Faculty Publications
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Item Characterization of poly(ethylene-co-vinyl acetate-co-carbon monoxide)/layered silicate clay hybrids obtained by melt mixing(2011) Anandhan, S.; Patil, H.G.; Babu, R.R.In recent times, polymer-layered silicate nanocomposites have drawn a great deal of attention because they often exhibit tremendous improvements in material properties compared with virgin polymers or conventional microor macro-composites. In the present study, nanocomposites were developed from organically modified clay and poly(ethylene-co-vinyl acetate-co-carbon monoxide) by melt mixing. FTIR spectroscopy reveals that the interaction between the organoclay and EVACO is thermodynamically favored. High resolution wide angle X-ray diffraction and transmission electron microscopy were used to study the morphology of the nanocomposites. Elemental mapping by scanning electron microscopy indicates good dispersion and distribution of the nanoclay in EVACO matrix. The mechanical properties of the nanocomposites are optimum at a clay loading of 3%. © Springer Science+Business Media, LLC 2011.Item Effects of smear layer removal agents on the physical properties and microstructure of mineral trioxide aggregate cement(Elsevier Ltd, 2017) Nidambur, N.V.; Sona, M.; Tay, F.R.Objective To compare the effect of QMix (Dentsply Sirona), 7% maleic acid (MA), and 17% ethylenediaminetetraacetic acid (EDTA) on the microhardness, flexural strength and microstructure of mineral trioxide aggregate (MTA; ProRoot MTA, Dentsply Sirona). Methods Forty MTA specimens were divided into four groups: [I] QMix [II] 7% MA [III] 17% EDTA and [IV] distilled water (control). After treatment with 5 mL of the respective solution for 1 min, the specimens were tested for microhardness using a Knoop hardness tester. Forty additional specimens were similarly treated and evaluated for the flexural strength using a universal testing machine. For microstructure evaluation, MTA specimens were treated in a similar manner and examined by X-ray diffractometry and scanning electron microscopy (SEM). Results For microhardness, there were no differences between distilled water, QMix and EDTA groups. However, MTA exposed to distilled water had higher microhardness than MA. When compared with QMix and EDTA, MA had lower microhardness; there was no difference between EDTA and QMix. For flexural strength, distilled water group had higher flexural strength than the other agents. There were no differences between EDTA vs MA and EDTA vs QMix. Specimens treated with QMix had higher flexural strength than MA. X-ray diffraction indicated that EDTA inhibited hydration of MTA. For SEM, all the tested agents altered the microstructure of MTA when compared to distilled water. Conclusion MA had more detrimental effect on the physical properties of MTA and EDTA was more detrimental to the hydration of MTA. Clinical significance The present study highlights the effect of newer chelating agents on the physical properties and microstructure of MTA. Preventing the deterioration of MTA is important for its long term success in endodontic procedures. © 2017Item Studies on development of high performance, self-compacting alkali activated slag concrete mixes using industrial wastes(Elsevier Ltd, 2019) Manjunath, R.; Narasimhan, M.C.; Umesh, K.M.; Kumar, S.; Bala Bharathi, U.K.In the present study, development of a class of High Performance Alkali Activated Slag Concrete mixes (hereafter referred to as HPAASC mixes) is discussed. These mixes are developed using three industrial wastes from Iron and Steel industry. While Ground granulated blast furnace slag (GGBFS) was used as the main binder, in the development of these HPAASC mixes, steel slag sand and Electric Arc Furnace slag (EAF slag) have been employed in the fine aggregate and coarse aggregate fractions of them. Higher flow characteristics, as those of self-compacting concrete mixes, as well as enhanced mechanical strength properties of these mixes are discussed in detail. The alkaline solutions used consist mixtures of sodium hydroxide and sodium silicate solutions, with a constant activator modulus (ratio of SiO2/Na2O) of one maintained in them. Taguchi’ design of experiments methodology was used to reduce the experimental efforts. The formulation of all the mixes developed herein was based on Taguchi's L-9 orthogonal array. Flow and strength properties of a set of nine mixes were used for performance evaluation purposes in an initial, calibration phase. Strength prediction equations were derived based on such results, the predictive capability of which were then assessed and ascertained with actual results of experiments on the next six new mixes, in the prediction phase. Test results indicated a higher flowability values for all the mixes (with slump flows greater than 700 mm), good filling and passing abilities, all satisfying the EFNARC (European Federation of Specialist Construction Chemicals and Concrete Systems) recommendations for SCC mixes. Higher compressive strengths (65–90 MPa), split-tensile strengths (4.8–5.3 MPa), flexural strengths (6.5–7 MPa), and Modulus of Elasticity (30.4–36.2 GPa) were observed along with lower water absorption values (2.1–2.7%) for all the HPAASC mixes tested herein. Microstructure studies were conducted on samples from the fractured surfaces of test specimens from different mixes, using advanced SEM, EDX and XRD analyses and the results are discussed. © 2018 Elsevier LtdItem A study on initial setting time and the mechanical properties of AASC using the PS ball as fine aggregate(Springer, 2019) Talkeri, A.H.; Ravi Shankar, A.U.India is the second largest producer of cement in the world with an annual production of 455 Million Tonnes (MT) which is expected to reach up to 550MT by 2020. In India, the increased demand for cement in the construction industry is required to meet the needs of infrastructure development. However, the production of Portland cement releases significant amounts of CO2 to the atmosphere. Therefore, it is necessary to look for sustainable solutions for concrete production by the use of supplementary cementitious materials. The alternative replacement for Ordinary Portland Cement (OPC) can be Ground Granulated Blast Furnace Slag (GGBS), Fly-ash, Silica fume, Rice-husk ash, which is the various industrial by-products. In this present work, an attempt was made to develop Alkali Activated Slag Concrete (AASC) using Precious Slag (PS) ball as fine aggregate. The development of AASC was made with GGBS as the principal binder. Mixes were developed with binder content 443 kg/m3, Sodium Silicate (SS)/Sodium Hydroxide (SH) ratio of 1 and their performance when exposed to ambient temperature were studied. Alkali binder ratio (0.3) with 8, 10, 12 and 14M NaOH was selected for all the AASC mixes. The test results showed that the slump values for the different mixes satisfying the MoRTH guidelines for concrete pavements. The AASC mixes have higher compressive strength ranging between 41–64 MPa. The fatigue life of the AASC mix was has improved by the addition of PS ball, at the higher concentration of NaOH. © 2019, Chinese Society of Pavement Engineering. Production and hosting by Springer Nature.Item Volume change characteristics of eco-friendly mortar mixes produced with geopolymeric binder and recycled fine aggregate(ASTM International, 2020) Saha, S.; Shaik, N.; C, C.The production of geopolymer mortar using recycled fine aggregate (RFA) generated from concrete waste has significant potential to be a sustainable construction material. In this article, the volume change properties of the produced geopolymer mortar mixes are studied in terms of drying shrinkage up to the age of 180 days and reported as the percentage increase with respect to the shrinkage value of 3 days. The influence of RFA content, alkaline liquid (AL) in terms of the concentration of sodium hydroxide (SH) solution, the ratio of sodium silicate (SS) solution to SH solution, and the ratio of AL to fly ash (FA) were investigated on the drying shrinkage properties of the geopolymer mortar mixes. All the cast specimens were cured at 80°C for 24 hours. Higher drying shrinkage values were observed for the mortar mixes produced with higher RFA content, AL/FA, SS/SH ratio, and lower concentration of SH solution. Scanning electron microscope images were studied for the samples taken from the geopolymer mixes showing lower drying shrinkage values to understand the microstructure. © 2019 by ASTM International.Item Bond strength characteristics of fly-ash admixed selfcompacting alkali activated concrete mixes(Associated Cement Companies Ltd. priti.saldanha@acclimited.com, 2020) Manjunath, R.; Narasimhan, M.C.; Suryanarayana, L.R.Bonding in any type of concrete plays a crucial role in the performance of reinforced concrete structures, which are profoundly determined by many factors such as concrete compressive strength, diameter, type and size of the bar along with length of embedment and confinement of concrete. Herein, an attempt has been made to develop fly-ash admixed self-compacting alkali activated slag concrete mixes cured under laboratory ambient conditions and to evaluate the bond strength characteristics using direct pull out test along with their bond stress-slip behaviour at the age of 28 and 56 days. These self-compacting alkali activated slag concrete mixes were developed using Fly-ash and GGBFS as the major principal binder. Naturally available river sand was used as the fine aggregate; 12.5 mm down size crushed granite chips (Jelly) constituted the coarse aggregate fractions in all these mixes. The alkaline solutions basically consisted of mixtures of sodium hydroxide flakes dissolved in the calculated quantity of water and mixed with the liquid sodium silicate solution. The experiments were planned based on Taguchi’s design of experiments methodology. A total of fifteen mixes were developed and evaluated for their flow ability characteristics as per the requirements of EFNARC guidelines along with compressive strength values at the age of 7, 14, 28 and 56 days. In an initial, calibration phase, bond strength characteristics of a set of nine mixes were utilized for performance evaluation purposes. Strength prediction equations were then derived on the basis of such results, whose predictive capacity was then evaluated and ascertained in the prediction phase with actual results of experiments on a set of three new mixes. Test results indicated higher flow ability characteristics for all the mixes satisfying the requirements as per the EFNARC guidelines. Higher compressive strengths values in the range of 46 – 85 MPa were obtained at the age of 56 days. Further acceptable bond strength values were obtained varying in the range of 8.0 – 14.5 MPa as compared to control OPC based reference concrete mix. © 2020, Associated Cement Companies Ltd.. All rights reserved.Item Replacement of Conventional Base Course with Stabilized Lateritic Soil Using Ground Granulated Blast Furnace Slag and Alkali Solution in the Flexible Pavement Construction(Springer, 2020) Amulya, S.; Ravi Shankar, A.U.The use of cement/chemical-treated base and sub-bases is widely recommended in the pavement construction. Therefore, this paper investigates the behaviour of stabilized lateritic soil as a base course in flexible pavement by replacing the granular base course. The lateritic soil was stabilized with 25% Ground Granulated Blast Furnace Slag (GGBFS) along with the alkali solutions such as sodium hydroxide and sodium silicate at a varying sodium oxide (Na2O) contents of 4, 5 and 6%, silica modulus (Ms, a ratio of silica to sodium oxide) of 0.5, 1.0 and 1.5 and a constant water binder ratio (w/b) of 0.25. The maximum compressive strengths of 5452 and 6593 kPa were achieved for a treated sample consisting of 6% Na2O and 1.0 Ms cured for 28 days at the light and heavy compactions, respectively, which is due to the formation of calcium silicate hydrates when calcium oxide-rich GGBFS reacts with water. Further with the curing period results in an increase in strength due to the formation of calcium alumino-silicate hydrates when GGBFS reacts with alkali solutions. The durability of the samples was evaluated by wetting–drying and freezing–thawing tests. The samples passing the required durability criteria were tested for flexural strength and fatigue life. Scanning electron microscope images showed closely packed crystal orientation indicating high strength. Low and high volume pavements were designed using stabilized soil as a base course, and the strains were evaluated using pavement analysis software. It is suggested that the conventional granular base layer can be replaced with the stabilized soil. © 2020, Indian Geotechnical Society.Item Ferrochrome ash – Its usage potential in alkali activated slag mortars(Elsevier Ltd, 2020) Kumar, K.B.; Yaragal, S.C.; Das, B.B.This study is an attempt to develop a sustainable construction material, i.e., alkali activated slag (AAS) in combination with ferrochrome ash (FCA) as a replacement to ordinary Portland cement (OPC). The effect of the various levels of FCA (0, 25, and 50%) replacing ground granulated blast furnace slag (GGBS) in AAS mortars with 4% of Na2O dosage is studied. Further, five levels of the modulus of silica (Ms = 0.75, 1.00, 1.25, 1.5, and 1.75) are chosen to achieve targeted compressive strength at 28 days under ambient temperature curing conditions. The compressive strength decreases with the increase in level of the FCA replacement. The targeted design compressive strength is achieved with 25% FCA replacement to GGBS in the AAS mortar system with Ms = 1.25. In addition, microstructure and mineralogical studies are undertaken to ascertain the formation of different hydration products with the aid of the scanning electron microscope (SEM) and the X-ray diffractometer (XRD). Gismondine and calcium aluminate silicate hydrate (C-A-S-H) are the major hydration products in the AAS mortar mixes. Sodium aluminate silicate hydrate phases (N-A-S-H) are also observed prominently as the FCA replacement level increases in the AAS mortar mixes. The Fourier-transform infrared spectroscopy (FTIR) confirms the presence of the Si–O-(Si or Al) functional group. The addition of FCA in the AAS system is of vital significance in the reduction of the embodied carbon dioxide (ECO2eq), embodied energy (EEeq) and cost. © 2020 Elsevier LtdItem Stabilisation of lithomargic clay using alkali activated fly ash and ground granulated blast furnace slag(Taylor and Francis Ltd. michael.wagreich@univie.ac.at, 2020) Amulya, A.; Ravi Shankar, A.U.; Praveen, M.A suitable ground improvement technique is essential in order to confront the problems associated with lithomargic clay for road construction. The efficacy of alkaline solutions such as sodium hydroxide and sodium silicate along with class F fly ash and Ground Granulated Blast Furnace Slag (GGBS) as additives to improve the properties of lithomargic clay is examined. The different mixes are prepared by replacing the soil with 20%, 30%, and 40% of GGBS and fly ash. The Maximum Dry Density (MDD) obtained from the soil replaced with 40% GGBS and for the soil replaced with 30% fly ash. An activator modulus of 1.25 is kept constant for the varying sodium oxide dosage at 2, 3 and 4 per cent. The Unconfined Compressive Strength (UCS) of the alkali-activated soil cured for 3, 7 and 28 days is determined and compared with the UCS of the soil replaced with fly ash and GGBS at both standard and modified proctor densities. The different mixes are tested for the durability, California Bearing Ratio (CBR). The soil is replaced with GGBS and fly ash does not pass the durability test while the alkali-activated mixes with 4% sodium oxide dosage is found to be durable. © 2018, © 2018 Informa UK Limited, trading as Taylor & Francis Group.Item Utilization of lateritic soil stabilized with alkali solution and ground granulated blast furnace slag as a base course in flexible pavement construction(Springer, 2020) Amulya, A.; Ravi Shankar, A.U.; Singh, A.; Pammar, K.H.The natural aggregates are depleting in developing countries due to the excessive usage in road and building construction. In the present study, the engineering properties of abundantly available lateritic soil stabilized with Ground Granulated Blast Furnace Slag (GGBS) and alkali solutions like Sodium hydroxide and Sodium silicate was evaluated. The suitability of stabilized soil as a base course in flexible pavements was investigated. The lateritic soil was treated with 15, 20, 25 and 30% of GGBS and alkali solutions consisting of 5% of Sodium oxide with Silica Modulus (Ms) of 0.5, 1.0 and 1.5 at a constant water binder ratio of 0.25. The improved unconfined compressive strength, flexural strength, and fatigue life were observed from the soil treated with 30% of GGBS and alkali solution having Ms 1.0 air-cured for 28 days at ambient temperature. The improvement is due to the formation of Calcium Silicate Hydrates and Calcium Alumino Silicate Hydrates from an exothermic reaction between Calcium ions and the dissolved silicates and aluminates present in GGBS and alkali solutions. The samples treated with 25, 30% of GGBS and alkali solution having 1.0 Ms cured for 28 days found to be durable in Wetting-Drying and Freezing-Thawing tests. The compact and densified crystal orientation of the treated soil samples was observed from the microstructure images obtained from the Scanning Electron Microscope technique. The design of low and high volume roads was suggested with stabilized soil and strains developed at different locations on the proposed pavement were analyzed using pavement analysis software. © 2020, Chinese Society of Pavement Engineering. Production and hosting by Springer Nature.