Faculty Publications
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Item A comprehensive review on integrating sustainable practices and circular economy principles in concrete industry(Academic Press, 2024) Barbhuiya, S.; Das, B.B.; Adak, D.This comprehensive review explores the integration of circular economy principles into the concrete industry, emphasizing their role in enhancing sustainability and resource efficiency. It covers the fundamental concepts of circular economy and examines the application of Life Cycle Assessment (LCA) in evaluating the environmental impacts of concrete production. The review highlights innovative strategies for recycling, reuse, waste reduction, and resource optimisation, showcasing how these approaches can transform concrete production practices. It also addresses the policy considerations, economic implications, and societal impacts associated with adopting circular economy practices. Furthermore, the review investigates recent technological advancements in circular concrete production, including self-healing concrete and 3D printing. By summarizing these findings and offering practical recommendations, the review aims to support the industry in transitioning towards more sustainable practices. This detailed analysis provides valuable insights into the benefits and challenges of circular economy adoption, helping stakeholders make informed decisions for a greener concrete sector. © 2024 The AuthorsItem Thermoplastic vulcanizates from post consumer computer plastics/nitrile rubber blends by dynamic vulcanization(Springer Japan, 2013) Anandhan, S.; Bhowmick, A.K.Due to depletion of natural resources and increasing greenhouse emissions, new technologies for the transformation of waste polymers into valuable materials represent one of our greatest current needs. Acrylonitrile-butadiene-styrene terpolymer (ABS) is one of the most widely used engineering plastics and is used as outer casing for electronic equipment. Nitrile rubber (NBR) is used in many applications that demand oil resistance. In an attempt to explore whether these materials can be successfully recycled, we prepared blends of scrap computer plastics (SCP) based on ABS with NBR and waste NBR powder (w-NBR), and investigated their mechanical properties and recyclability. Specifically, we assessed the effect of dynamic vulcanization and replacement of virgin NBR with w-NBR on the properties of 60/40, 70/30, and 80/20 NBR/SCP blends. These blends exhibited thermoplastic elastomeric behavior. The thermoplastic elastomeric blends showed excellent swelling resistance to standard lubricant oil (namely, IRM 903 oil). © 2013 Springer Japan.Item Sustainable approaches for utilizing waste in building construction: Two case studies in India(CAFET INNOVA Technical Society cafetinnova@gmail.com 1-2-18/103, Mohini Mansion, Gagan Mahal Road, Domalguda, Hyderabad 500029, 2014) Kasthurba, A.K.; Reddy, K.R.; Venkat Reddy, D.V.Problems associated with increasing waste due to rising urban developments and its environmental concerns are reviewed. The challenges and standards for sustainable construction are outlined. This study explores potential utilization of different types of waste materials in building construction for its efficient and sustainable management. The benefits and challenges in utilization of waste for building applications are reviewed. Two case studies which demonstrate effective utilization of waste in construction projects carried out in India are outlined. These sustainable approaches of managing waste in building construction shall help private and governmental agencies to incorporate effective waste management strategies in future. This study will offer a background and useful guide for engineers and material scientists to develop standards and specifications for cost effective alternate building materials and techniques for economy, energy, and environmental benefits. © 2014 CAFET-INNOVA TECHNICAL SOCIETY. All rights reserved.Item Preparation and evaluation of heavy metal rejection properties of polysulfone/chitosan, polysulfone/N-succinyl chitosan and polysulfone/N-propylphosphonyl chitosan blend ultrafiltration membranes(Elsevier, 2014) Kumar, R.; Isloor, A.M.; A.F., A.F.Heavy metal rejection properties of chitosan based polysulfone/chitosan (PSf/CS), polysulfonef/N-succinyl chitosan (PSf/NSCS) and polysulfone/N-propylphosphonyl chitosan (PSf/NPPCS) ultrfiltration (UF) membranes were evaluated. The rejection of membranes towards the copper, cadmium and nickel ions was studied during ultrafiltration (UF) by polymer enhanced ultrafiltration (PEUF) processes. The flux change during the UF process and the effect of pH on the rejection were determined. The membrane recycling property was studied during PEUF process by filtering chelated CuSO4 solution. A maximum of 78% of Cu, 73% of Ni and 68% of Cd rejection for M-5 membrane, 75% of Cu, 71% of Ni and 66% of Cd rejection for M-8 membrane and 76% of Cu, 69% of Ni and 66% of Cd rejection for M-2 membrane with reasonably good flux was observed. Further improvement in heavy metal ion rejection was achieved by PEUF process. Membrane M-5 showed a maximum of 98%, 95% and 92% rejection for Cu, Ni and Cd respectively with steady state flux of 117L/m2h. An increase in membrane recycling property after the metal ion rejection was mainly attributed to the hydrophilicity of CS, NSCS and NPPCS. © 2014 Elsevier B.V.Item Additive Manufacturing of Syntactic Foams: Part 1: Development, Properties, and Recycling Potential of Filaments(Minerals, Metals and Materials Society 184 Thorn Hill Road Warrendale PA 15086, 2018) Singh, A.K.; Patil, B.; Hoffmann, N.; Saltonstall, B.; Doddamani, M.; Gupta, N.This work focuses on developing filaments of high-density polyethylene (HDPE) and their hollow particle-filled syntactic foams for commercial three-dimensional (3D) printers based on fused filament fabrication technology. Hollow fly-ash cenospheres were blended by 40 wt.% in a HDPE matrix to produce syntactic foam (HDPE40) filaments. Further, the recycling potential was studied by pelletizing the filaments again to extrude twice (2×) and three times (3×). The filaments were tensile tested at 10?4 s?1, 10?3 s?1, and 10?2 s?1 strain rates. HDPE40 filaments show an increasing trend in modulus and strength with the strain rate. Higher density and modulus were noticed for 2× filaments compared to 1× filaments because of the crushing of some cenospheres in the extrusion cycle. However, 2× and 3× filament densities are nearly the same, showing potential for recycling them. The filaments show better properties than the same materials processed by conventional injection molding. Micro-CT scans show a uniform dispersion of cenospheres in all filaments. © 2018, The Minerals, Metals & Materials Society.Item Investigation on the potential use of recycled fine aggregate to produce geopolymer mortar mix(ASTM International, 2019) Saha, S.; C, C.The utilization of construction and demolition waste (C&DW) partially or fully for various purposes in construction industries is one of the most significant solutions to overcome the scarcity of raw materials and disturbances of the environmental system. On the other hand, geopolymer is being tried to be established as an alternative sustainable binder material for ordinary portland cement. In the present study, with the thought of promoting of sustainability, an attempt has been made to use concrete wastes as recycled fine aggregate (RFA) partially to produce fly ash (FA)-based geopolymer mortar. The workability, water absorption, compressive strength at 3, 7, 28, and 56 days, volume change behavior, and chloride permeability of the produced FA-based geopolymer mortar were determined. The effects of RFA, the ratio of alkali liquid (AL) to FA, and different curing regimes on these properties of mortar mix also discussed. The morphology and microstructures of the samples taken from the mortar mix, which were observed having the highest strength under different curing regimes, were studied using scanning electron microscopy (SEM). The experimental results indicate lower workability, higher water absorption capacity, and higher drying shrinkage of geopolymer mortar mix that has more RFA content in the mix, but the compressive strength of the geopolymer mortar mix started decreasing after a certain percentage of RFA content in the mix. Utilization of that certain percentage of RFA will help us to minimize the consumption of natural fine aggregates and reduce the disturbances generated by unorganized dumping of C&DW. © 2019 by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959.Item Life cycle assessment of municipal solid waste management options for India(Elsevier Ltd, 2019) Khandelwal, H.; Thalla, A.K.; Kumar, S.; Kumar, R.Life Cycle Assessment (LCA) tool can be used for environmental assessment of Municipal Solid Waste Management (MSWM) system. The present study aims to evaluate the impact of MSWM system in Nagpur city, India under four different scenarios. i.e., composting combined with landfilling (S1), material recovery facility (MRF) & composting combined with landfilling (S2), MRF & anaerobic digestion (AD) combined with landfilling (S3) and MRF, AD & composting combined with landfilling (S4) using LCA tool. The sensitivity analysis was also performed for evaluating the influence of recycling rate of valuable resources in all the considered scenarios. The scenarios were compared using Gabi 8.5.0.79 model and CML-1A impact characterization method. S2 was found to have the least environmental impacts on global warming, human toxicity, eutrophication, and photochemical ozone creation potential categories. The sensitivity analysis indicated an inversely proportional relation between change in recycling rate and total environmental burdens. © 2019 Elsevier LtdItem Volume change characteristics of eco-friendly mortar mixes produced with geopolymeric binder and recycled fine aggregate(ASTM International, 2020) Saha, S.; Shaik, N.; C, C.The production of geopolymer mortar using recycled fine aggregate (RFA) generated from concrete waste has significant potential to be a sustainable construction material. In this article, the volume change properties of the produced geopolymer mortar mixes are studied in terms of drying shrinkage up to the age of 180 days and reported as the percentage increase with respect to the shrinkage value of 3 days. The influence of RFA content, alkaline liquid (AL) in terms of the concentration of sodium hydroxide (SH) solution, the ratio of sodium silicate (SS) solution to SH solution, and the ratio of AL to fly ash (FA) were investigated on the drying shrinkage properties of the geopolymer mortar mixes. All the cast specimens were cured at 80°C for 24 hours. Higher drying shrinkage values were observed for the mortar mixes produced with higher RFA content, AL/FA, SS/SH ratio, and lower concentration of SH solution. Scanning electron microscope images were studied for the samples taken from the geopolymer mixes showing lower drying shrinkage values to understand the microstructure. © 2019 by ASTM International.Item Residence Time Distribution Studies in a Modified Rotating Packed Disc Contactor: Mathematical Modeling and Validation(De Gruyter Open Ltd, 2020) Kalnake, R.P.; Murthy, D.V.R.; Achar, A.; Raval, K.A modified rotating packed disc contactor (RPDC) with the maximum working volume of 65 liter is designed for biological waste water treatment. A hollow disc with radial vanes mounted on the disc was a modified design of this contactor. Stimulus-response experiments were conducted in the contactor to understand liquid mixing behavior under different operating conditions. The recycle stream was also used in the operation of the contactor. Experiments were conducted for different number of discs, rotational speeds and recycle ratios. The disc design and recycle ratio had marked influence on the mixing behavior. An increase in disc rotation and recycle ratio produced a well-mixed flow behavior. Moreover, the surface area available in the RPDC was about 4 times more than the surface area available in a standard rotating biological contactor (RBC) operating at similar conditions. A mathematical model was developed for the flow behavior under recycle and a good agreement was found between the model and experimental results. © 2020 Walter de Gruyter GmbH, Berlin/Boston 2020.Item Strength and shrinkage properties of heat-cured fly ash-based geopolymer mortars containing fine recycled concrete aggregate(ASTM International, 2020) Saha, S.; C, C.Geopolymer has obtained significant importance as an alternative eco-friendly binder material for ordinary portland cement (OPC) as it can be produced from the reaction between the industrial by-product materials rich in alumina, silica, and alkaline solutions. Therefore, usage of geopolymer effectively in the construction industry will help to reduce the consumption of a huge quantity of natural resources for the energy processes required for the production of OPC. It is also one of important solution to control carbon dioxides emission by the usage of OPC. On the other hand, using construction and demolition waste (C&DW) as the source of recycled aggregates in construction industry helps to reduce the huge consumption of natural aggregates and protect the environment from the disturbances caused by the unorganized dumping of C&DW. In this study, an attempt has been madeto produce fly ash (FA)-based geopolymer mortar mixes using C&DW effectively as fine aggregates partially. The effects of recycled fine aggregates (RFA), the ratio of alkaline liquid (AL) to FA, and duration of heat curing on the properties of the produced geo-polymer mortar mixes have been discussed in this article. To determine the influence of RFA on the strength and volume change behavior of mixes, natural fine aggregates were replaced by RFA at 0, 10, 20, 30, 40, and 50 % by mass. The AL/FA ratio was adopted as 0.4 and 0.6. Higher compressive strength was observed for most of the mortar mixes having RFA up to 20 %, and higher drying shrinkage value was found for the mixes with higher RFA content. Scanning electron microscopy (SEM) images were also studied for knowledge about the signature of the formed structures in the mortar mixes, which were observed having higher strength. © © 2019 by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959.