Faculty Publications
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Item Assessment of mixture boiling heat transfer correlations for ammonia/water mixture(2009) Sathyabhama, A.; Ashok Babu, T.P.The aim of this work is to present a critical examination of both the available experimental data and the performance of the available mixture boiling heat transfer correlations for ammonia/water mixture. First, a selection and comparison of the experimental database found in the open literature at the mentioned working conditions is presented. Subsequently, after a short description of the most relevant heat transfer correlations, and in accordance with the selected data, a detailed analysis of the performance of each correlation is carried out. Results show a small divergence between the experimental data sets and conclude that the presently available correlations show considerable discrepancies in heat transfer coefficients within the selected conditions. © 2009 Wiley Periodicals, Inc.Item Acoustical and compressibility parameters of glycylglycine-FeCl3 in aqueous ethanol mixture at T = (293.15, 303.15, and 313.15) K(2010) Santosh, M.S.; Bhat, D.K.Ultrasonic velocity measurement is a reliable procedure that allows quick and easy determination of solvent concentrations in mixtures. This paper presents data of ultrasonic velocities and isentropic compressibilities of (glycylglcyine-FeCl3) in aqueous ethanol mixture at T = (293.15, 303.15, and 313.15) K. Various acoustical parameters were calculated, because of their importance in the study of specific molecular interactions. A less-compressible phase of the fluid and a closer packing of molecules is observed with changes in the intermolecular free length. Quantitative investigation suggests that the mixing of ethanol with an aqueous glycylglycine-FeCl3 solution causes the rupture of hydrogen bonds, with increasing S and Lf values (where the former represents the change in isentropic compressibility and the latter represents the intermolecular free length). Theoretically computed values of isentropic compressibility in the studied mixture using different models indicate the superiority of the very complex procedure. © 2010 American Chemical Society.Item Corrosion inhibition of 6061 Al-15 vol. pct. SiC(p) composite and its base alloy in a mixture of sulphuric acid and hydrochloric acid by 4-(N,N-dimethyl amino) benzaldehyde thiosemicarbazone(2011) Geetha, G.M.; Nayak, J.; Nityananda Shetty, A.N.The corrosion inhibition characteristics of 4-(N,N-dimethylamino) benzaldehyde thiosemicarbazone (DMABT) on the corrosion behavior of 6061 Al-15 vol. pct. SiC(p) composite and its base alloy were studied at different temperatures in acid mixture medium containing varying concentrations of hydrochloric acid and sulphuric acid using Tafel extrapolation technique and ac impedance spectroscopy (EIS). The effect of inhibitor concentration, temperature and concentration of the acid mixture media on the inhibitor action was investigated. It was found that inhibition efficiencies increase with the increase in inhibitor concentration, but decrease with the increase in temperature and with the increase in concentration of the acid media. Thermodynamic parameters for dissolution process were determined. The adsorption of DMABT on both the composite and base alloy was found to be through physisorption obeying Freundlich adsorption isotherm. © 2010 Elsevier B.V. All rights reserved.Item Excess and deviation properties of {(glycylglycine + ZnCl2) in aqueous methanol} mixtures(2011) Santosh, M.S.; Bhat, D.K.The excess molar volumes (VE), viscosity deviations (??), deviations in isentropic compressibility (?? S) and excess molar refractivity (?RmE) for {(glycylglycine + ZnCl2) in aqueous methanol} mixture have been calculated from the experimental values. The bridging water molecules bend the chains into stable open ring structures together with intermolecular hydrogen bonding and interstitial accommodation leading to negative VE values. The positive ?? values indicate a structure breaking effect of aqueous glycylglycine-ZnCl2 upon contact with methanol molecules. It is also noted that chelation of zinc to glycylglycinate is through carboxylic group and not the amino group. The negative ??S values suggest the formation of an open ring structure lowering the entropy of the solution. Due to weak interaction between solute and solvent, the molecular structure of individual molecule does not change significantly and leads to negative ?RmE values. Finally, the results have lead to a good understanding of the thermodynamics properties of the studied liquid mixture. © 2010 Elsevier Ltd. All rights reserved.Item Experimental investigation in pool boiling heat transfer of ammonia/water mixture and heat transfer correlations(2011) Sathyabhama, A.; Ashok Babu, T.P.A.The nucleate pool boiling heat transfer coefficient of ammonia/water mixture was investigated on a cylindrical heated surface at low pressure of 4-8bar and at low mass fraction of 0NH3<0.3 and at different heat flux. The effect of mass fraction, heat flux and pressure on boiling heat transfer coefficient was studied. The results indicate that the heat transfer coefficient in the mixture decreases with increase in ammonia mass fraction, increases with increase in heat flux and pressure in the investigated range. The measured heat transfer coefficient was compared with existing correlations. The experimental data were predicted with an accuracy of ±20% by the correlation of Calus&Rice, correlation of Stephan-Koorner and Inoue-Monde correlation for ammonia/water mixture in the investigated range of low ammonia mass fraction. The empirical constant of the first two correlations is modified by fitting the correlation to the present experimental data. The modified Calus&Rice correlation predicts the present experimental data with an accuracy of ±18% and the modified Stephan-Koorner correlation with an accuracy of ±16%. © 2011 Elsevier Inc.Item Experimental study of nucleate pool boiling heat transfer to ammonia-water-lithium bromide solution(2011) Sathyabhama, A.; Ashok Babu, T.P.Visualization of bubble nucleation during nucleate pool boiling outside a vertical cylindrical heated surface was done for ammonia-water binary and ammonia-water-lithium bromide ternary mixture in order to obtain a descriptive behavior of the boiling which was directly compared with the measured heat transfer coefficient at low pressure of 4-8. bar and at low ammonia mass fraction of 0Item Effect of preheated mixture on heat transfer characteristics of impinging methane-air premixed flame jet(Elsevier Ltd, 2015) Tajik, A.R.; Kuntikana, P.; Prabhu, S.V.; Hindasageri, V.Energy from spent flame or other low grade energy can be used to increase the temperature of the air before mixing with fuel. This would improve the heat transfer characteristics of the impinging flame jet. The studies on impinging flame jets reported in the literature are based on the fuel-air mixture at ambient temperature. In the present work, the inlet air for mixture is heated by an electrical heater. The heat flux distribution is estimated using an inverse heat conduction (IHCP) technique. The Nusselt number (Nu) and effectiveness (?) distributions are obtained by estimating the adiabatic wall temperature (Taw) by the analytical-numerical method. A circular burner of 13.5 mm is used for impingement on quartz plate of 3 mm thickness. Reynolds number (Re) varying from 500 to 2000 for the non-dimensional burner tip to impingement plate spacing (Z/d) of 2-6 and stoichiometric condition (Ø = 1.0) is considered for varying preheated condition. The effect of equivalence ratio is studied for Ø = 0.75 to 1.5 for Re = 1000 and Z/d = 4. By increase in preheat temperature, the stagnation point heat flux increases from 20% to 50% unless the inner premixed zone touches the impingement plate. CFD simulations are carried out in FLUENT software to explain the distribution of heat flux. © 2015 Elsevier Ltd. All rights reserved.Item Comparison of Stone Matrix Asphalt mixtures with polymer-modified bitumen and shredded waste plastics(Taylor and Francis Ltd. michael.wagreich@univie.ac.at, 2016) Goutham, G.; Lekha, B.M.; Krishna, G.; Ravi Shankar, A.U.Stone Matrix Asphalt (SMA) is a gap-graded bituminous mixture characterised with its improved rut resistance and durability. It has comparatively higher proportion of coarse aggregates and binder mastic with bituminous binder and mineral filler. Drain down of mastic content at various stages of construction is a common issue with SMA, and generally, some fibre additives are used to stabilise the mixture or a modified bitumen is used as the binder material. In this study, shredded waste plastics (SWP) are used instead of other stabilising additives, to prepare SMA mixtures with conventional viscosity graded (VG) 30 bitumen. Mixtures were prepared with four different levels of SWP content, and another mixture without any stabilisers was also prepared using polymer-modified bitumen (PMB). Specimens were prepared in superpave gyratory compactor (SGC) for all mixtures at different bitumen contents to determine volumetric and Marshall properties, and optimum bitumen content (OBC) was calculated for each mixture. Tensile strength, moisture susceptibility, rutting resistance and fatigue behaviour were also determined for all mixtures at corresponding OBC. From the available results, the optimum level of SWP in SMA mixture was determined as 8% by weight of bitumen. The study showed that even though mixture with PMB performed the best, SMA with 8% SWP provided comparable results. Based on the present investigation, waste plastic in suitable dosage can be recommended in SMA, instead of a stabilising additive. © 2015 Informa UK Limited, trading as Taylor & Francis Group.Item Numerical Analyses of Single-Phase Pressure Drop and Forced Convective Heat Transfer Coefficient of Water–Ethanol Mixture: An Application in Cooling of HEV Battery Module(John Wiley and Sons Inc. P.O.Box 18667 Newark NJ 07191-8667, 2016) Suhas, B.G.; Sathyabhama, A.The present numerical analyses are related to the cooling of a hybrid electric vehicle (HEV) battery module by water–ethanol mixture. The fluid is passed through a cold plate consisting of two rectangular channels of 0.01 m depth, 0.015 m width, and 0.15 m length. The battery module is represented by a heater placed below the cold plate. The single-phase pressure drop and single-phase heat transfer coefficient for water, water–ethanol mixture of mass fraction of 25%, 50%, and 75%, and ethanol are determined numerically for different heat fluxes of 10, 15, 20, and 25 kW/m2 and different Reynolds numbers 500, 1000, 1500, 2000, and 2500. To solve the Navier–Stokes equation, the pressure correction method was used and to solve the energy equation, the Lax–Wendroff explicit method is used. Numerical results obtained for water are compared with the literature correlations. The friction factor for water deviated by an average of 8.02% from the Lewis and Robertson equation. The Nusselt number for water deviated by 7.35% from the Churchill and Ozoe equation at lower Reynolds number 500 and at higher Reynolds number 2500, Nusselt number deviated by 13.68% from the Stephan equation. The results showed that the heat transfer coefficient increased with an increase in Reynolds number and heat flux. The effect of the increase in Reynolds number is more significant than the increase in heat flux. At higher ethanol mass fraction and higher Reynolds number the heat transfer coefficient increased with heat flux when compared to water. There is no significant decrease in heat transfer coefficient with an increase in ethanol mass fraction. The pressure drop increased and the heat transfer coefficient decreased with an increase in ethanol mass fraction. © 2015 Wiley Periodicals, Inc.Item Development of a Spectrophotometric Biphasic Assay for the Estimation of mPEG-maleimide in Thiol PEGylation Reaction Mixtures(Taylor and Francis Ltd. michael.wagreich@univie.ac.at, 2016) Nanda, P.; JagadeeshBabu, P.E.; Gupta, P.; Prasad, A.G.Methoxy(polyethylene glycol)-maleimide (mPEG-mal) is a PEG derivative used for thiol PEGylation of protein molecules and finds application in drug delivery studies. The maleimide group undergoes degradation in aqueous media, resulting in the difficult quantitative analysis of mPEG-mal. Routinely employed methods for separation and estimation of mPEG-mal include tedious chromatographic methods like ion exchange, high-performance liquid chromatography with refractive index detector and techniques like mass spectrometry and proton nuclear magnetic resonance. We present a direct and reproducible spectrophotometric method to quantify free and protein bound mPEG-mal in thiol PEGylation reaction mixtures. This method is based on the partitioning of a PEG bound chromophore between an aqueous ammonium isoferrothiocyanate phase to a chloroform phase in the presence of mPEG-mal. Several important parameters influencing the partitioning and stability of the chromophore, volume ratios of liquid phases, ethylenediaminetetraacetic acid concentration in the reaction mixture, mixing time, and chlorinated solvents used for partitioning have been studied. © 2016, Copyright © Taylor & Francis Group, LLC.