Faculty Publications
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Publications by NITK Faculty
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Item Steam as coolant and lubricant in turning of metal matrix composites(2008) Shetty, R.; Pai B, R.B.; Kamath, V.; Rao, S.S.Green cutting has become focus of attention in ecological and environmental protection. Steam is cheap, pollution-free and eco-friendly, and then is a good and economical coolant and lubricant. Steam generator and steam feeding system were developed to generate and feed steam. Comparative experiments were carried out in cutting AA6061-15 vol.% SiC (25 ?m particle size), with cubic boron nitride (CBN) insert KB-90 grade under the conditions of compressed air, oil water emulsion, steam as coolant and lubricant, and dry cutting, respectively. The experimental results show that, with steam as coolant and lubricant, gradual reduction in the cutting force, friction coefficient, surface roughness and cutting temperature values were observed. Further, there was reduction in built up edge formation. It is proved that use of water steam as coolant and lubricant is environmentally friendly. © 2008 Zhejiang University and Springer-Verlag GmbH.Item Bio-fuel variants for use in CI engine at design and off-design regimes: An experimental analysis(2008) Bekal, S.; Ashok Babu, T.P.A.In this work an attempt has been made to study the ester based fuel variants derived from edible and inedible oil sources for identifying the most appropriate fuel variant and operating mode for running a CI engine based on performance and emission parameters. The twenty four fuel variants tested included esters obtained from the edible sunflower oil, inedible pongamia oil, and their higher and lower proportional blends with diesel. Besides, several other fuel variants obtained from the emulsification of water-in-ester (W/E) with different water proportions have been tested. Basing upon three operational variables, namely, injection timing, injection pressure, and load, comparisons are made in aspects of smoke emissions, NOX emissions, BSEC, and exhaust gas temperatures at the best injection timing. 21.5°, 23°, 24.5° and 27.5° bTDC as the four injection timings and 190, 220 and 250 bar as three injection pressures are considered for the overall study. The 264 sets of experiments conducted with these combinations, focussing on the full and partial load characteristics of the engine, show that both sunflower and pongamia oil esters exhibited similar characteristics in their engine performance, and in both the cases the best BSEC occurred with 220 bar injection pressure for most of the fuel variants, and for straight fuels the ideal injection timing found to be slightly retarded (1.5° crank angle) compared to diesel. However, 24.5° bTDC, normal for the engine, was found to be the most appropriate for the lower blends like B2 (2% ester by volume), B5 and emulsion with 10% water proportion. © 2008 Elsevier Ltd. All rights reserved.Item Experimental studies on turning of discontinuously reinforced aluminium composites under dry, oil water emulsion and steam lubricated conditions using TAGUCHI's technique(Gazi University Eti Mahallesi, 2009) Shetty, R.; Pai B, R.B.; Rao, S.S.This paper reports on the experimental investigations carried out under dry, oil water emulsion and steam lubricated conditions in turning of DRACs. The measured results were then collected and analyzed with the help of the commercial software package MINITAB15. The experiments were planned on orthogonal arrays, made with prefixed cutting parameters and different lubricated conditions. An analysis of variance (ANOVA) was carried out to check tho validity of the proposed parameters and also their percentage contributions. The results of the tests show that with proper selection of the range of cutting parameters, it is possible to obtain better performance under steam lubricated condition.Item An analysis of cycle-by-cycle fluctuation in combustion parameter in CI engine operation for various bio-fuels(2011) Bekal, S.; Ashok Babu, T.P.A.The cycle-by-cycle fluctuations in peak pressure of combustion in a CI engine were studied for lower and higher blends of diesel and ester, and water-in-ester emulsions, at four injection timings and three injection pressures using coefficient of variation. The sunflower ester-diesel blends are found to have lower cycle-by-cycle fluctuations than pongemia ester-diesel blends. The fluctuations are found to be higher than that of diesel for higher blend proportions of ester. The water-in-ester emulsion show higher cycle-by-cycle fluctuations than that of ester-diesel blends. In most cases, the Brake specific energy consumption is also found to be higher where the coefficient of variation has higher values. Copyright © Taylor & Francis Group, LLC.Item Synthesis and characterization of temperature sensitive P-NIPAM macro/micro hydrogels(Elsevier B.V., 2011) JagadeeshBabu, P.E.; Suresh Kumar, R.; Maheswari, B.A thermo responsive macro porous poly(N-isopropylacrylamide) hydrogel was synthesized using free radical polymerization. The reaction was optimized by varying the reaction temperature, monomer, cross-linker and initiator based on the strength and swelling characteristics of the hydrogel. The morphology of the macro hydrogel was observed using scanning electron microscope (SEM). The swelling behavior of the macro hydrogel was performed gravimetrically and found that the gel synthesized at 36 °C had maximum deswelling ratio of 34.5 (-). These optimized values were further used to synthesis micro hydrogels using water-oil (w/o) emulsion technique. The morphology of the micro hydrogels were observed through SEM. Effect of water-oil ratio and stirrer speed on the mean particle size of the micro hydrogels were studied. Micro hydrogels synthesized at 1:1.5. w/o ratio and at 800. rpm had perfect spherical shape and had least particle mean diameter of 0.74 ?m, with SD of 0.5. Dye release kinetics with respect to temperature and time were studied using methylene blue solution. The release kinetic studies of micro hydrogel showed higher sustained release for 56. h compared to the macro hydrogel. © 2011 Elsevier B.V.Item Production and characterization of biosurfactant produced by a novel Pseudomonas sp. 2B(2012) Aparna, A.; Srinikethan, G.; Smitha, H.Biosurfactant-producing bacteria were isolated from terrestrial samples collected in areas contaminated with petroleum compounds. Isolates were screened for biosurfactant production using Cetyl Tri Ammonium Bromide (CTAB)-Methylene blue agar selection medium and the qualitative drop-collapse test. An efficient bacterial strain was selected based on rapid drop collapse activity and highest biosurfactant production. The biochemical characteristics and partial sequenced 16S rRNA gene of isolate, 2B, identified the bacterium as Pseudomonas sp. Five different low cost carbon substrates were evaluated for their effect on biosurfactant production. The maximum biosurfactant synthesis (4.97g/L) occurred at 96h when the cells were grown on modified PPGAS medium containing 1% (v/v) molasses at 30°C and 150rpm. The cell free broth containing the biosurfactant could reduce the surface tension to 30.14mN/m. The surface active compound showed emulsifying activity against a variety of hydrocarbons and achieved a maximum emulsion index of 84% for sunflower oil. Compositional analysis of the biosurfactant reveals that the extracted biosurfactant was a glycolipid type, which was composed of high percentages of lipid (~65%, w/w) and carbohydrate (~32%, w/w). Fourier transform infrared (FT-IR) spectrum of extracted biosurfactant indicates the presence of carboxyl, hydroxyl and methoxyl functional groups. The mass spectra (MS) shows that dirhamnolipid (l-rhamnopyranosyl-l-rhamnopyranosyl-3-hydroxydecanoyl-3-hydroxydecanoate, Rha-Rha-C 10-C 10) was detected in abundance with the predominant congener monorhamnolipid (l-rhamnopyranosyl-?-hydroxydecanoyl-?-hydroxydecanoate, Rha-C 10-C 10). The crude oil recovery studies using the biosurfactant produced by Pseudomonas sp. 2B suggested its potential application in microbial enhanced oil recovery and bioremediation. © 2012 Elsevier B.V..Item Novel organogel based lyotropic liquid crystal physical gels for controlled delivery applications(Elsevier Ltd, 2015) Singh, V.K.; Pal, K.; Banerjee, I.; Pramanik, K.; Anis, A.; Al-Zahrani, S.M.In this study, novel organogel based lyotropic liquid crystals (LLC) were prepared and investigated as controlled release matrices. The LLC gels were prepared using mixtures of Span 80-Tween 80 (1:2 w/w), aqueous solution of polyvinyl alcohol (10% w/w) and sesame oil. The prepared gels were characterized by microscopy, mechanical testing and thermal studies. The biocompatibility of the gels was tested against human keratinocytes. Metronidazole loaded gels were used for in vitro drug release and antimicrobial tests. The formation of water-in-oil emulsion gels was confirmed by fluorescent microscopy. Polarized micrographs showed the formation of lamellar structures within the aqueous phase of the matrices. Mechanical studies confirmed the viscoelastic nature of the gels with solid like consistency. The melting points of the gels were in the range of 44-51°C. The gels did not elicit any cytotoxic effect on the human keratinocytes. The release of metronidazole from the gels was diffusion mediated. The drug loaded gels showed good antimicrobial efficacy against Escherichia coli. ©2015 Published by Elsevier Ltd.Item Synthesis of poly(styrene-co-methyl methacrylate) nanospheres by ultrasound-mediated Pickering nanoemulsion polymerization(Springer Netherlands rbk@louisiana.edu, 2019) Buruga, K.; Kalathi, J.T.Poly (styrene-co-methyl methacrylate) (PS-co-PMMA) nanospheres were synthesized by ultrasound-mediated Pickering nanoemulsion polymerization using halloysite nanotubes (HNTs) as a stabilizer. A relatively high conversion (? 99%) was obtained in a short span of time (60 min) relative to (?97%) for that obtained by conventional emulsion polymerization performed without ultrasound. The initial rate of polymerization and the conversion were found to be increasing with the acoustic intensity in the range of 12.5–25 W/cm2). The synthesized copolymer nanosphere particles exhibited a perfect spherical shape (from TEM analysis), good stability (from zeta-potential analysis), high molecular weight (Mw? 311 kDa from Gel permeation chromatography), and excellent thermal properties (Tg? 120°C from DSC and TGA) as a result of the combined physicochemical effects of acoustic cavitation. The formation of nanosized emulsion droplets stabilized by HNTs ultimately yielded nanospheres of PS-co-PMMA with an average size of ? 82.8 nm. The PS-co-PMMA nanospheres can have potential applications in medicine, dentistry, paper, paint, and automotive industries. © 2019, The Polymer Society, Taipei.Item Interface Dominated Dielectric Response of PS-Fe3O4 Patchy Microspheres(American Chemical Society service@acs.org, 2019) Kishor Kumar, M.J.; Kalathi, J.T.Polymeric-inorganic interface plays a vital role in enhancing dielectric properties of patchy microspheres, Janus particles, and nanocomposites. We performed the computational modeling and simulations along with experiments to understand the phenomena behind the improved dielectric permittivity of polystyrene-iron oxide (PS-Fe3O4) patchy microspheres. We addressed the fundamental insights into the role of the interfacial region on the dielectric properties. Based on the experimental outcomes and computational simulations on dielectric behavior including polarization and electric field formation, we propose a new mechanism of charge buildup at the interface. Computational results reveal that the creation of interface bound-charges at the inorganic-polymeric interface is responsible for the improved dielectric properties. We also fabricated PS-Fe3O4 patchy microspheres by Pickering emulsion polymerization using Fe3O4 particles as a solid stabilizer. The microstructure, composition, morphology, dielectric, and thermal properties of the synthesized patchy PS-Fe3O4 particles were investigated. The dielectric permittivity (k) of the neat PS increased from ?2.9 to ?14.8 after decorating with Fe3O4 particles. Impedance response of the patchy microspheres shows that the interface of PS-Fe3O4 stores more charges than bulk PS-Fe3O4. The dielectric behavior of patchy microspheres can be engineered by tuning the shape and position of the patches. The present studies on polymer-inorganic interface provide some insights into the mechanisms that control dielectric permittivity and nonlinear conduction in an applied electric field. © © 2019 American Chemical Society.Item Poly(N,N-diethyl acrylamide)/functionalized graphene quantum dots hydrogels loaded with doxorubicin as a nano-drug carrier for metastatic lung cancer in mice(Elsevier Ltd, 2019) Havanur, S.; Batish, I.; Cheruku, S.P.; Gourishetti, K.; JagadeeshBabu, J.; Kumar, N.Cancer has emanated as a daunting menace to human-kind even though medicine, science, and technology has reached its zenith. Subsequent scarcity in the revelation of new drugs, the exigency of salvaging formerly discovered toxic drugs such as doxorubicin has emerged. The invention of drug carrier has made drug delivery imminent which is ascribable to its characteristic traits of specific targeting, effective response to stimuli and biocompatibility. In this paper, the nanoscale polymeric drug carrier poly(N,N-diethyl acrylamide) nanohydrogel has been synthesized by inverse emulsion polymerization. Lower critical solution temperature of the polymeric carrier has been modified using graphene quantum. The particle size of pure nanohydrogel was in the range of 47 to 59.5 nm, and graphene quantum dots incorporated nanohydrogels was in the range of 68.1 to 87.5 nm. Doxorubicin (hydroxyl derivative of anthracycline) release behavior as a function of time and temperature was analyzed, and the Lower critical solution temperature of the synthesized nanohydrogels has been found to be in the range of 28–42 °C. Doxorubicin release characteristics have improved significantly as the surrounding temperature of the release media was increased near to physiological temperature. Further, the cumulative release profile was fitted in the different kinetic model and found to follow a Fickian diffusion release mechanism. The hydrogel was assessed for its cytotoxicity in B16F10 cells by MTT assay. In-vivo studies were done to study the lung metastasis by melanoma cancer and the results showed a rational favorable prognosis which was confirmed by evaluating hematological parameters and the non-immunogenic nature of nanohydrogel by cytokine assay. Comprehensively, the results suggested that poly(N,N-diethyl acrylamide) nanohydrogels have potential application as an intelligent drug carrier for melanoma cancer. © 2019 Elsevier B.V.