Faculty Publications

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    Thermoplastic vulcanizates from post consumer computer plastics/nitrile rubber blends by dynamic vulcanization
    (Springer Japan, 2013) Anandhan, S.; Bhowmick, A.K.
    Due to depletion of natural resources and increasing greenhouse emissions, new technologies for the transformation of waste polymers into valuable materials represent one of our greatest current needs. Acrylonitrile-butadiene-styrene terpolymer (ABS) is one of the most widely used engineering plastics and is used as outer casing for electronic equipment. Nitrile rubber (NBR) is used in many applications that demand oil resistance. In an attempt to explore whether these materials can be successfully recycled, we prepared blends of scrap computer plastics (SCP) based on ABS with NBR and waste NBR powder (w-NBR), and investigated their mechanical properties and recyclability. Specifically, we assessed the effect of dynamic vulcanization and replacement of virgin NBR with w-NBR on the properties of 60/40, 70/30, and 80/20 NBR/SCP blends. These blends exhibited thermoplastic elastomeric behavior. The thermoplastic elastomeric blends showed excellent swelling resistance to standard lubricant oil (namely, IRM 903 oil). © 2013 Springer Japan.
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    Conversion of waste polypropylene to liquid fuel using acid-activated kaolin
    (SAGE Publications Ltd, 2014) Panda, A.K.; Singh, R.K.
    Waste polypropylene was subjected to thermal degradation in the presence of kaolin and acid-treated kaolin, with different catalyst-to-plastics ratios, in a semi-batch reactor at a temperature range of 400-550°C to obtain optimized process conditions for the production of liquid fuels. The effects of process temperature, catalyst and feed composition on yield and quality of the oil were determined. For a thermal decomposition reaction at up to 450°C, the major product is volatile oil; and the major products at a higher temperature (475-550°C) are either viscous liquid or wax. The highest yield of condensed fraction in the thermal reaction is 82.85% by weight at 500°C. Use of kaolin and acid-treated kaolin as a catalyst decreased the reaction time and increased the yield of liquid fraction. The major product of catalysed degradation at all temperatures is highly volatile liquid oil. The maximum oil yield using kaolin and acidtreated kaolin is 87.5% and 92%, respectively, at 500°C. The oil obtained was characterized using GC-MS for its composition and different fuel properties by IS methods. © The Author(s) 2014.
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    A novel approach to investigate effect of magnetic field on dynamic properties of natural rubber based isotropic thick magnetorheological elastomers in shear mode
    (Central South University of Technology f-ysxb@mail.csut.edu.cn, 2015) Hegde, S.; Kiran, K.; Gangadharan, K.V.
    The preparation of natural rubber based isotropic thick magnetorheological elastomers (MRE) was focused on by varying the percentage volume concentration of carbonyl iron powder and developing a test set up to test the dynamic properties. Effect of magnetic field on the damping ratio was studied on the amplification region of the transmissibility curve. The viscoelastic dynamic damping nature of the elastomer was also studied by analyzing the force-displacement hysteresis graphs. The results show that MR effect increases with the increase in magnetic field as well as carbonyl iron powder particle concentration. It is observed that softer matrix material produces more MR effect. A maximum of 125% improvement in the loss factor is observed for the MRE with 25% carbonyl iron volume concentration. FEMM simulation shows that as carbonyl iron particle distribution becomes denser, MR effect is improved. FEMM analysis also reveals that if the distance between the adjacent iron particles are reduced from 20 ?m to 10 ?m, a 40% increase in stored energy is observed. © 2014, Central South University Press and Springer-Verlag Berlin Heidelberg.
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    Comparison of Stone Matrix Asphalt mixtures with polymer-modified bitumen and shredded waste plastics
    (Taylor and Francis Ltd. michael.wagreich@univie.ac.at, 2016) Goutham, G.; Lekha, B.M.; Krishna, G.; Ravi Shankar, A.U.
    Stone Matrix Asphalt (SMA) is a gap-graded bituminous mixture characterised with its improved rut resistance and durability. It has comparatively higher proportion of coarse aggregates and binder mastic with bituminous binder and mineral filler. Drain down of mastic content at various stages of construction is a common issue with SMA, and generally, some fibre additives are used to stabilise the mixture or a modified bitumen is used as the binder material. In this study, shredded waste plastics (SWP) are used instead of other stabilising additives, to prepare SMA mixtures with conventional viscosity graded (VG) 30 bitumen. Mixtures were prepared with four different levels of SWP content, and another mixture without any stabilisers was also prepared using polymer-modified bitumen (PMB). Specimens were prepared in superpave gyratory compactor (SGC) for all mixtures at different bitumen contents to determine volumetric and Marshall properties, and optimum bitumen content (OBC) was calculated for each mixture. Tensile strength, moisture susceptibility, rutting resistance and fatigue behaviour were also determined for all mixtures at corresponding OBC. From the available results, the optimum level of SWP in SMA mixture was determined as 8% by weight of bitumen. The study showed that even though mixture with PMB performed the best, SMA with 8% SWP provided comparable results. Based on the present investigation, waste plastic in suitable dosage can be recommended in SMA, instead of a stabilising additive. © 2015 Informa UK Limited, trading as Taylor & Francis Group.
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    Magnetic field and frequency dependent LVE limit characterization of magnetorheological elastomer
    (Springer Verlag service@springer.de, 2017) Poojary, U.R.; Gangadharan, K.V.
    Magnetorheological elastomer (MRE) based semi-active isolators have the potential to replace conventional passive isolators to achieve wide frequency range isolation. The effectiveness of MRE isolator depends on the control strategies developed based on viscoelastic constitutive relations. The theory of linear viscoelasticity is the basis for viscoelastic constitutive relations which can predict the material behavior within a certain strain limit referred as linear viscoelastic (LVE) limit. Beyond the LVE limit, the performance of MRE semi-active isolator exacerbates as the control strategies turns out to be ineffective. In the present study, variation in LVE limit of MRE with the magnetic field and frequency is investigated through forced vibration tests. To exclude the effect of terminal non-linearity on the measurement, the blocked transfer stiffness method described in the ISO 10846-2 is adopted. The results revealed that the LVE limit of MRE is strongly dependant on the magnetic field and exhibited a weak dependency on the operating frequency. Under magnetized state, the transition from linear to non-linear behavior of MRE is at lower strain levels indicating the increased friction energy dissipation at particle–matrix interface. © 2016, The Brazilian Society of Mechanical Sciences and Engineering.
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    Dynamic deformation–dependent magnetic field–induced force transmissibility characteristics of magnetorheological elastomer
    (SAGE Publications Ltd info@sagepub.co.uk, 2017) Poojary, U.R.; Hegde, S.; Gangadharan, K.V.
    The need for broad-band vibration isolation performance of the structures is fulfilled by magnetorheological elastomer–based smart vibration isolation system. The smart isolation capabilities of magnetorheological elastomer isolator vary with the input dynamic deformation levels. In this study, force transmissibility measurement approach is adapted to evaluate the influence of dynamic deformation on the field-induced isolation capabilities of magnetorheological elastomer. The variation in isolation capabilities of magnetorheological elastomer is assessed in terms of isolation effect. Isolation performance of magnetorheological elastomer is enhanced with the increase in the magnetic field. Under increased dynamic deformation levels, the isolation characteristics of magnetorheological elastomer are influenced by the Payne effect. Dominance of the Payne effect under non-magnetized state of magnetorheological elastomer has enhanced the isolation effect at larger strain levels. The influence of strain on isolation characteristics of magnetorheological elastomer is verified from the magnetic force simulation between a pair of dipoles performed in ANSYS (version 14). © 2016, © The Author(s) 2016.
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    Experimental investigation on the effect of carbon nanotube additive on the field-induced viscoelastic properties of magnetorheological elastomer
    (Springer New York LLC barbara.b.bertram@gsk.com, 2018) Poojary, U.R.; Hegde, S.; Gangadharan, K.V.
    The additives improve the properties of magnetorheological elastomer by modifying the surface of ferromagnetic filler particles or by varying the properties of a host polymer matrix. In this study, effect of carbon nanotube additive on the viscoelastic properties of magnetorheological elastomer reinforced with optimum quantity of ferromagnetic filler is studied. Room temperature vulcanizing silicone elastomer-based test samples are prepared by mixing the elastomer with the carbon nanotube and carbonyl iron powder blend obtained from ultrasonication. Viscoelastic properties are measured by adopting the dynamic blocked transfer stiffness method. The results revealed that the properties of magnetorheological elastomer vary significantly with the inclusion of carbon nanotube. With the addition of 0.5 wt% carbon nanotube, the zero field dynamic stiffness of magnetorheological elastomer is enhanced by 36.7% and the loss factor is increased by 17.2%. The enhancement in zero field properties led to the least field-induced enhancement for magnetorheological elastomer doped with 0.5 wt% carbon nanotube. A relatively larger flexibility of pure magnetorheological elastomer samples had resulted in the maximum field-induced enhancement of 48.04%. Among the prepared test samples with carbon nanotube addition, the sample loaded with 0.25 wt% carbon nanotube exhibited a pronounced stiffness enhancement and lower loss factor. This substantiated the existence of an optimum limit for carbon nanotube additive. The present study also confirmed the feasibility of developing MRE tailor-made to suit the particular application by selecting a proper composition of matrix, filler and the additives. © 2017, Springer Science+Business Media, LLC, part of Springer Nature.
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    Integer and fractional order-based viscoelastic constitutive modeling to predict the frequency and magnetic field-induced properties of magnetorheological elastomer
    (American Society of Mechanical Engineers (ASME), 2018) Poojary, U.R.; Gangadharan, K.V.
    Magnetorheological elastomer (MRE)-based semi-active vibration mitigation device demands a mathematical representation of its smart characteristics. To model the material behavior over broadband frequency, the simplicity of the mathematical formulation is very important. Material modeling of MRE involves the theory of viscoelasticity, which describes the properties intermediate between the solid and the liquid. In the present study, viscoelastic property of MRE is modeled by an integer and fractional order derivative approaches. Integer order-based model comprises of six parameters, and the fraction order model is represented by five parameters. The parameters of the model are identified by minimizing the error between the response from the model and the dynamic compression test data. Performance of the model is evaluated with respect to the optimized parameters estimated at different sets of regularly spaced arbitrary input frequencies. A linear and quadratic interpolation function is chosen to generalize the variation of parameters with respect to the magnetic field and frequency. The predicted response from the model revealed that the fractional order model describes the properties of MRE in a simplest form with reduced number of parameters. This model has a greater control over the real and imaginary part of the complex stiffness, which facilitates in choosing a better interpolating function to improve the accuracy. Furthermore, it is confirmed that the realistic assessment on the performance of a model is based on its ability to reproduce the results obtained from optimized parameters. © © 2018 by ASME.
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    A study on the effect of rejuvenators in reclaimed asphalt pavement based stone mastic asphalt mixes
    (Springer, 2019) Durga Prashanth, L.; Palankar, N.; Ravi Shankar, A.U.
    The present paper focuses on the behavior of Stone Mastic Asphalt (SMA) mixes incorporating rejuvenated Reclaimed Asphalt Pavement (RAP) materials. The RAP materials were tested for its physical properties and later were rejuvenated using various rejuvenators such as waste cooking oil, waste engine oil and shredded plastics. The rejuvenated RAP materials were incorporated in the SMA mixes at various replacement levels i.e. 0%, 30%, 50% and 70% (by weight). Various binder properties such as viscosity, rheological properties and chemical composition were evaluated for the aged and rejuvenated material. The rejuvenators were incorporated at different dosage levels i.e. 2%, 4% and 6% (by weight of binder). The optimal rejuvenation dosage for each type of rejuvenator was identified and mix design for the SMA was optimized for evaluating its physical and mechanical properties. Based on the results, the optimum rejuvenator dosage was identified at 6% for waste cooking oil and waste engine oil, while 2% for shredded plastics. It was observed that the addition of rejuvenators improved the performance of RAP based SMA mixes. © 2019, Chinese Society of Pavement Engineering. Production and hosting by Springer Nature.
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    NOx reduction studies on a diesel engine operating on waste plastic oil blend using selective catalytic reduction technique
    (Elsevier B.V., 2019) Ayodhya, A.S.; Lamani, V.T.; Thirumoorthy, M.; Kumar, G.N.
    The constant escalation in the consumption of petroleum products has compelled researchers to discover for new alternative fuels which can be successfully incorporated in the existing automotive engines. Oil derived from waste plastics is one such alternative, which not only ensures longevity of fossil fuels but also assists in bringing down the hazardous impacts caused by the improper disposal of plastic wastes. This work focuses on the utilization of valuable energy of toxic non-biodegradable waste plastics to lucratively be used as an alternative fuel. An attempt was further made to reduce the NO X emissions which increased with the use of waste plastic oil blend. The main objective of this experimental investigation is to study the performance & emission characteristics of a twin cylinder CRDI engine subjected to selective catalytic reduction (SCR) after-treatment technique. Different flow rates of ammonia as a reducing agent were tested and concluded that a flow rate of 0.5 kg/hr furnishes optimum results. A comparison of NO X reduction efficiency was also made between SCR and EGR techniques. The comparison eventually indicated that SCR gives better NO X conversion efficiency at higher loads without any adverse effect on the engine performance while operating on Waste Plastic Oil blend (P30). © 2018 Energy Institute