Faculty Publications
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Item Thermal and optical properties of BaO-CaF2-P2O5 glasses(Elsevier B.V., 2015) Narayanan, M.K.; Shashikala, H.D.Thermal and optical properties of ternary phosphate glasses prepared by conventional melt-quenching technique, belonging to the series (50 - X)BaO-XCaF2-50P2O5 (X = 0 to 10 mol%) were investigated with increase in CaF2 content. Thermal stability and glass forming ability studied using differential thermal analysis (DTA) were found to increase with the increase in CaF2 content. Powder X-ray diffraction (XRD) analysis of heat treated samples also revealed that CaF2 addition improves the thermal stability against crystallization. Increase in both glass transition temperature and onset crystallization temperature with the increase in CaF2 content can be attributed to the partial substitution of Ba2 + ion with Ca2 + ion, which is having larger field strength. The observed decrease in the melting temperature of glass batch with the increase in CaF2 content indicates that CaF2 acts as a flux and reduces the viscosity of the glass melt. The decrease in refractive index of the glasses with the increase in CaF2 content can be attributed to replacement of lower field strength Ba2 + by Ca2 + or the partial substitution of more polarizable oxygen ion by fluorine. Optical band gap energy slightly increased and Urbach energy marginally reduced with the increase in CaF2 content. Increase in optical band gap energy was further confirmed by calculating theoretical optical basicity of glasses. Average anion polarizability (?O/F) of (50 - X)BaO-XCaF2-50P2O5 glasses calculated from refractivity data using Lorentz-Lorentz relation was correlated with its theoretical optical basicity (?th) using the previously established correlation for oxyfluoro phosphate glasses. © 2015 Elsevier B.V. All rights reserved.Item Characterization of linear low-density polyethylene with graphene as thermal energy storage material(Institute of Physics Publishing helen.craven@iop.org, 2019) Chavan, S.; Gumtapure, V.; Arumuga Perumal, D.A.In this work authors reported the preparation and characterization of composite phase change material (CPCM) using the direct-synthesis method by blending the Linear low-density polyethylene (LLDPE) with Carboxyl Functionalized Graphene (f-Gr). LLDPE is selected as base material and f-Gr is dispersed into three different concentrations 1.0, 3.0, and 5.0 wt% and referred as CPCM-1, CPCM-2 and CPCM-3 respectively. Experimental analysis is carried out through Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM) and Differential scanning calorimeter (DSC). The preset study assesses the influences of nanoparticle concentration on thermophysical properties, thermal performance and thermal storage characteristics of CPCMs. Results show that addition of f-Gr improves the thermal conductivity and latent heat of fusion of LLDPE. However, f-Gr slightly reduces the melting temperature and decreased the crystallization temperature. Therefore, this study reveals that f-Gr, addition to LLDPE has substantial potential for improving the thermal energy storage performance. © 2019 IOP Publishing Ltd.Item Crystallization kinetics of Si20Te80?xBix (0???x???3) chalcogenide glasses(Elsevier Ltd, 2019) Fernandes, B.J.; Ramesh, K.; Udayashankar, N.K.In this report, we investigate the crystallization kinetics of Si20Te80?xBix (0 ? x ? 3) chalcogenide glassy systems using differential scanning calorimetry (DSC) technique. Systematic studies are carried out in order to understand the variation of thermal parameters such as glass transition temperature (Tg), onset crystallization temperature (Tc) and peak crystallization temperature (Tp) as a function of composition. Activation energy for glass transition (Eg) and crystallization (Ec) has been calculated based on the relevant statistical methods. Furthermore, thermal parameters such as change in specific heat (?Cp), fragility index (F), thermal stability (?T)& (S), enthalpy (?Hc), entropy (?S) are deduced to interpret distinct material behaviour as a function of composition. Structural evaluation like thermal devitrification studies elucidate the restricted glass formability of the studied glass system. Conclusively, a relationship has been established between the obtained thermal parameters and electrical switching characteristics. © 2019 Elsevier B.V.Item Eco-friendly lightweight filament synthesis and mechanical characterization of additively manufactured closed cell foams(Elsevier Ltd, 2019) Patil, B.; Bharath Kumar, B.R.; Bontha, S.; Balla, V.K.; Powar, S.; Hemanth Kumar, V.H.; Suresha, S.N.; Doddamani, M.Environmentally pollutant fly ash cenospheres (hollow microballoons) are utilized with most widely consumed, relatively expensive high density polyethylene (HDPE) for developing lightweight eco-friendly filament for 3D printing of closed cell foams. Cenospheres (20, 40 and 60 by volume %) are blended with HDPE and subsequently extruded in filament to be used for 3D printing. Cenosphere/HDPE blends are studied for melt flow index (MFI) and rheological properties. MFI decreases with cenospheres addition. Complex viscosity, storage and loss modulus increase with filler loading. DSC results on the filament and printed samples reveal increasing crystallization temperature and decreasing crystallinity % with no appreciable change in peak melting temperature. Cooling rate variations exhibit crystallinity differences between the filament and the prints. CTE decreases with increasing cenosphere content resulting in lower thermal stresses and under diffusion of raster leading to non-warped prints. Micrography on freeze fractured filament and prints show cenospheres uniform distribution in HDPE. Intact cenospheres lower the foam density making it lightweight. Tensile tests are carried out on filaments and printed samples while flexural properties are investigated for 3D prints. Cenospheres addition resulted in improved tensile modulus and decreased filament strength. Tensile and flexural modulus of printed foams increases with filler content. Results are also compared with injection molded samples. Printed foams registered comparable tensile strength. Specific tensile modulus is noted to be increased with cenospheres loading implying weight saving potential of 3D printed foams. Property map reveals printed foams advantage over other fillers and HDPE composites synthesized through injection and compression molding. © 2019 Elsevier LtdItem Mechanical behavior of additively manufactured nanoclay/HDPE nanocomposites(Elsevier Ltd, 2020) Beesetty, P.; Kale, A.; Patil, B.; Doddamani, M.Nanoclay (NC) has blended with relatively inexpensive, widely consumed HDPE (high density polyethylene) for the development of filament to be used in 3D printers. NC/HDPE blends are prepared by varying NC wt. % (0.5, 1, 2, and 5) and are subjected to melt flow index (MFI) measurements. MFI has noted to be decreasing with NC loadings. NC/HDPE nanocomposite blends are further extruded using a single screw extruder. Developed nanocomposites filaments are fed to the fused filament fabrication (FFF) based 3D printer for realizing NC/HDPE nanocomposite prints. The density of printed sample increases with filler content. Filament and printed samples thermal study is carried out using differential scanning calorimeter (DSC). NC addition increases crystallinity and crystallization temperature without significant change in melting peak temperature. Freeze fractured prints reveal the uniform distribution of NC in HDPE. The tensile test is conducted on the filaments and prints. Further printed nanocomposites are subjected to flexural investigations. Tensile modulus and strength of filament increase with NC additions in HDPE matrix. Tensile and flexural properties (modulus and strength) of the nanocomposite prints increases with NC content. Finally, results obtained from the tensile and flexural tests of prints are compared with different HDPE composites available in the literature. © 2020 Elsevier Ltd