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Item A comparative analysis of crustacean exoskeletons: structural, microstructural, morphological, and UV absorption studies(Institute of Physics, 2024) Nowl, M.S.; Praveen, L.L.; Ambili, V.; Singh, S.; Samad, U.; Seikh, A.H.; Dutta, S.; Mandal, S.This study aims to investigate the structural, thermal, and spectral characteristics, along with the ultra-violet (UV) absorption of various marine benthos exoskeletons, such as various species of crabs (Portunus sanguinolentus, Portunus pelagicus, Charybdis feriata) and mantis shrimp (Oratosquilla oratoria). Their unique properties and ability to survive in harsh oceanic environments make them interesting research subjects. This research utilized powder x-ray diffraction (XRD) analysis to determine the crystal structure of the benthic varieties. The sample surface was analyzed using high-resolution micrographs obtained from field-emission scanning electron microscopy (FESEM), which identified the presence of chitin and calcite in the marine benthos. This was further confirmed by differential scanning calorimetry (DSC), and Fourier transform infrared spectroscopy (FTIR). The optical characteristics were investigated using UV-visible spectroscopy. The proximate analysis revealed high protein content in the mantis shrimp exoskeleton compared to other crab species, highlighting its excellent UV absorption characteristics. Overall, this research has the potential to broaden our understanding of marine organisms, which can have potential applications in biotechnology and materials science to develop nature-inspired innovative materials sustainably. © 2024 The Author(s). Published by IOP Publishing Ltd.Item Comparative analysis of flipped and overlapped microwave sintered plus friction stir processed in-situ Al-Cu composites(Springer Nature, 2024) Vinayak, V.R.; Bajakke, P.A.; Jambagi, S.C.; Bhajantri, V.; Deshpande, A.S.The in-situ Al-Cu composites were fabricated with Cu content more than the solubility limit (5.65%) and the critical composition of an Al-Cu alloy (4.6%). A powder metallurgy route with state-of-the-art microwave sintering and friction stir process with overlapped and flipped conditions was attempted. The overlapped friction stir resulted in a minimum area of nugget region, unidirectional material mixing, high heat input in successive passes, and brittleness in the material. This accounted for the material to exhibit high strength with low ductility. Whereas flipped friction stir leads to a maximum area of stir zone, bidirectional material mixing, and similar thermal cycles in individual passes and avoids excessive heating. This facilitated the material to possess maximum strength by retaining ductility. The newly developed in-situ Al-Cu composite material (with Cu wt% in ranges of 8–12) possesses equivalent strength, ductility, electrical conductivity, and rate of corrosion compared to copper. Notably, these attributes, combined with its cost-effectiveness, position this material as a promising alternative to copper conductors in electrical applications. From the present investigation, it is strongly recommended to choose a flipped friction stir for better properties. © Qatar University and Springer Nature Switzerland AG 2024.
