Faculty Publications
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Item Unprecedented Electroreduction of CO2over Metal Organic Framework-Derived Intermetallic Nano-Alloy Cu0.85Ni0.15/C(American Chemical Society, 2022) Payra, S.; Devaraj, N.; Tarafder, K.; Roy, S.Designing suitable catalysts for efficient and selective electrocatalytic reduction of CO2 is a need of the hour, and in this regard, the well-defined, highly dispersed active metal centers can be a trendsetting research endeavor toward CO2 electroreduction due to the maximum atom utilization and unique electronic structure. This study describes the synthesis and electrocatalytic CO2 reduction activity of atomistically dispersed Cu/C and Ni/C and the intermetallic nano-alloy Cu0.85 Ni0.15 /C. The catalysts were synthesized from the corresponding MOF precursors. The successful synthesis of the monometallic and intermetallic nano-alloys was established from structural, surface morphological, and electronic properties. Cu0.85 Ni0.15 /C exhibited an unprecedented electrocatalytic reduction of CO2 with a high selectivity and high faradaic efficiency toward CH3 OH. The kinetic studies and the first-principles calculations elucidated the intricate mechanism and the superior activity of electrocatalytic reduction of CO2 over the intermetallic Cu0.85 Ni0.15 /C catalyst. © 2022 American Chemical Society. All rights reserved.Item Effective photoelectrocatalytic reduction of CO2to formic acid using controllably annealed TiO2nanoparticles derived from porous structured Ti foil(Elsevier Ltd, 2022) Mubarak, S.; Dhamodharan, D.; Byun, H.-S.; Arya, S.B.; Pattanayak, D.K.The rate of global warming and unfavorable climate changes caused by the drastic upsurge of carbon dioxide (CO2) emission has necessitated the development of approaches to limit the significantly high concentration of CO2 in the atmosphere. The photoelectrochemical reduction of CO2 results in a reduction of the energy required to transform this greenhouse gas into valuable end products. In this study, we fabricated cost-effective and novel 3D nanoporous structured (3DNS) TiO2 nanoparticles (T-NPs) on the surface of a thin titanium foil (T-foil) by chemical treatment with hydrogen peroxide (H2O2) followed by calcination at high temperatures in the range of 400-800 °C. The as-proposed samples were analyzed by several characterizations such as XRD, XPS, TEM, and Raman spectroscopy. At 600 °C, the anatase-dominated mixed phases of calcinated T-foil (TO600) were seen, and a maximum photocurrent density of 71.5 μA/cm2 was obtained, in comparison to the T-foils treated at other temperatures (TO400, TO500, TO700, and TO800). Because of the better photocurrent density, TO600 was selected as the photocathode material for photoelectrochemical CO2 reduction performed with or without the presence of solar light. The lowest CO2 reduction onset potential (-1.191 V) was observed on the TO600 sample in the presence of light with Ag/AgCl as the reference electrode. 1H NMR analysis of the product solution revealed the formation of formic acid as the major product of the CO2 reduction reaction after the chronoamperometric electrolysis was performed for more than 25 h. The maximum faradaic efficiency (64%) and formic acid yield (165 μmol cm-2 h-1) were obtained at an applied potential of-1.3 V (vs. Ag/AgCl reference electrode) for TO600. © 2022 Elsevier Ltd.Item Efficient photoelectrocatalytic conversion of CO2 to formic acid using Ag-TiO2 nanoparticles formed on the surface of nanoporous structured Ti foil(Korean Society of Industrial Engineering Chemistry, 2022) Mubarak, S.; Dhamodharan, D.; Byun, H.-S.; Pattanayak, D.K.; Arya, S.B.Global warming and adverse climate change, which have been intensified by a strident increase in carbon dioxide (CO2) emissions, have necessitated the development of alternative techniques to reduce the disproportionate concentration of CO2 in the atmosphere. The photoelectrochemical reduction of CO2 is a technique of lowering the energy required to convert greenhouse gases into useful end products. Herein, we have manufactured an innovative, cost-effective silver (Ag) decorated anatase TiO2 (TO-Agx; ‘x’ stands for different concentration of Ag) nanoparticles which created on the 3D nanoporous structured surface of a thin titanium foil (Ti-foil) by the assist of chemical treatment with hydrogen peroxide (H2O2) and different concentrations (1, 5, 10, 20 mM) of silver nitrate (AgNO3) solution and followed by calcination at 500 °C. As-prepared samples were analyzed by several characterization techniques such as XRD, XPS, TEM and Raman spectroscopy. Among various samples (TO, TO-Ag1, TO-Ag5, TO-Ag20), the TO-Ag10 sample were exposed a supreme photocurrent density of 83.2 µA/cm−2 (86.1% higher than TO sample which is untreated with AgNO3 solution). Because of its high photocurrent density, the sample TO-Ag10 were selected as the electrode material for photoelectrochemical CO2 reduction reaction and a lowest reduction onset potential (−1.018 V) was observed on linear sweep voltammetry analysis in the presence of light with Ag/AgCl reference electrode. 1H NMR analysis of the product solution exposed the production of formic acid as a single product of CO2 reduction reaction after the chronoamperometric electrolysis were carried out more than 6 h. The maximum faradaic efficiency (73%) and formic acid yield (193 µmol cm−2 h−1) were found at an applied potential of −1.2 V (vs. Ag/AgCl reference electrode) for TO-Ag10 photocathode. © 2022 The Korean Society of Industrial and Engineering ChemistryItem Achieving elevated thermal performance with novel ‘O’ rings eccentric spine as turbulators in solar parabolic trough collector(Springer Science and Business Media B.V., 2025) Ahmed, K.R.A.; Shyam, A.; Prasanna Naveen Kumar, J.P.N.; Arumuga Perumal, D.A.The present study integrates the eccentric inserts in the absorber section of a parabolic trough collector to augment the thermal behaviour. To produce significant effect on the thermal performance, the effect of ‘O’ rings with the eccentric spine as turbulator and insert in the receiver tube with thickness of 4 mm and pitch length of 2d are experimentally analysed. The effects of parameters like thermal efficiency, heat transfer coefficient, and heat flow are evaluated, illustrated, and compared with those of a smooth tube. Empirical relations were used to validate and compare the performance parameters. The modified receiver tube with the eccentric insert exhibited improvement in the overall thermal efficiency and heat transfer coefficient to 10.93 and 28.08%, respectively. In addition, the proposed system with inserts exhibited maximum thermal enhancement index and efficiency of 1.078 and 72%, respectively, with 24.02% reduction in cost of heat gain produced and the carbon credits earned for the present system is seen to be 2.89, which is 11% more in comparison with a smooth absorber tube. © Akadémiai Kiadó Zrt 2025.