Faculty Publications

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Publications by NITK Faculty

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    Development of anti-corrosive multi-layered coatings of zinc-nickel alloy
    (2011) Subbaiah, Y.; Kaje, V.; Hegde, A.C.
    Purpose: The purpose of this paper is to develop and optimize anti-corrosive multi-layered coatings of zinc-nickel alloy on carbon steel. Design/methodology/approach: A variety of composition-modulated multi-layer alloy (CMMA) coatings of zinc-nickel were developed on a carbon steel substrate by cyclic changes in cathode current during electrodeposition, coupled with variation of the thicknesses of the individual layers. The corrosion behavior of the coatings was studied in 5 percent NaCl solution by electrochemical methods. Cyclic cathode current densities (CCCDs) and the number of alloy layers were optimized for highest performance of the coatings against corrosion. The factors responsible for improved corrosion resistance were analyzed in terms of change in the intrinsic electrical properties of the capacitance value at the electrical double layer that was associated with micro/nanometric layering. The formation of the semi-conductive surface film, which was responsible for the improved corrosion resistance, was supported by a Mott-Schottky plot and the cyclic polarization study. The formation of multi-layered deposit and the mechanism of corrosion degradation of the coating were analyzed using scanning electron microscopy. Findings: CMMA coatings with an optimal configuration of (Zn-Ni)2.0/4.0/300 showed ~35 times better corrosion resistance compared to a monolithic (Zn-Ni)3.0 alloy coating of the same thickness. The peak performance was attributed to the change in intrinsic electrical properties of the coating and this conclusion was supported by dielectric spectroscopy. Originality/value: The paper describes the optimization of CCCD and the number of deposited layers by development of electrolytic deposition of anti-corrosive multi-layered zinc-nickel coatings from a single plating technique. © Emerald Group Publishing Limited.
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    Molecular surface-dependent light harvesting and photo charge separation in plant-derived carbon quantum dots for visible-light-driven OH radical generation for remediation of aromatic hydrocarbon pollutants and real wastewater
    (Academic Press Inc., 2024) Meena, S.; Sethi, M.; Saini, S.; Kumar, K.; Saini, P.; Meena, S.; Kashyap, S.; Yadav, M.; Meena, M.L.; Dandia, A.; Nirmal, N.K.; Parewa, V.
    Despite the growing emphasis on eco-friendly nanomaterials as energy harvesters, scientists are actively searching for metal-free photocatalysts to be used in environmental remediation strategies. Developing renewable resource-based carbon quantum dots (CQDs) as the sole photocatalyst to harvest visible light for efficient pollutant degradation is crucial yet challenging, particularly for addressing the escalating issue of water deterioration. Moreover, the photocatalytic decomposition of H2O2 under visible light irradiation remains an arduous task. Based on this, we designed two types of CQDs, C-CQDs (carboxylic-rich) and A-CQDs (amine-rich) with distinct molecular surfaces. Owing to the higher amount of upward band bending induced by amine-rich molecular surface, A-CQDs efficiently harvest the visible light and prevent recombination kinetics resulting in prolonged lifetimes (25 ps), and augmented charge carrier density (35.7 × 1018) of photoexcited charge carriers. A-CQDs enabled rapid visible-light-driven photolysis of H2O2 (k = 0.058 min−1) and produced higher quantity of •OH radicals (0.158 μmol/sec) for the mineralization of petroleum waste, BETX (i.e. Benzene, Ethylbenzene, Toluene and Xylene) (k = 0.017–0.026 min−1) and real textile wastewater (k = 0.026 min−1). To assess comparative toxicities of both remediated and non-remediated real wastewater samples in a time and dose depended manner, Drosophila melanogaster was used as a model organism. The findings unequivocally demonstrate the potential of remediated wastewater for watering urban forestry. © 2024 Elsevier Inc.
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    Effects of coconut shell charcoal powder combined with SBS on rheological properties of asphalt binder
    (Elsevier Ltd, 2025) Rahul, M.S.; Anjani, H.; T S, P.; Bhanu V, U.; Suresha, S.N.
    Conventional asphalt binders often suffer from inadequate stiffness, elasticity, and aging resistance under high temperatures and heavy traffic conditions. This study addresses these limitations by utilizing coconut shell charcoal powder (CSCP), a carbon-rich, porous biochar derived from agricultural waste, along with styrene-butadiene-styrene (SBS) polymer to enhance the rheological performance and sustainability of VG-30 asphalt binder. CSCP, incorporated at 2 %, 4 %, and 6 % by weight, provides high surface activity and thermal stability that improve binder stiffness and aging resistance, while 1 % SBS enhances elasticity and recovery through its elastomeric network. Rheological tests using the dynamic shear rheometer (DSR), multiple stress creep recovery (MSCR), and linear amplitude sweep (LAS) on unaged, rolling thin-film oven (RTFO)-aged, and pressure aging vessel (PAV)-aged samples, supported by field emission scanning electron microscopy (FESEM) and Fourier transform infrared spectroscopy (FTIR) analyses, revealed that the dual-modified binder (CSMB6S1) achieved an optimal balance of stiffness and elasticity, exhibiting superior rutting resistance, fatigue life, and high-temperature stability. The results highlight the synergistic reinforcement between CSCP and SBS and demonstrate the potential of coconut shell–derived carbon as a sustainable modifier for high-performance asphalt pavements. © 2025 Elsevier Ltd.