Faculty Publications

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    Equilibrium and kinetic study for the removal of malachite green using activated carbon prepared from Borassus flabellofer male flower
    (2010) JagadeeshBabu, P.E.; Kumar, V.; Visvanathan, R.
    Activated carbon was prepared from dried Borassus flabellofer male flower and batch adsorption experiments were conducted to study its potential to remove malachite green (MG) dye. The process was further optimized by studying the operating variables like initial pH of the stock solution, activation temperature, initial dye concentration, adsorbent loading and contact time. The optimized pH and activation temperatures were found to be 7.55 and 450.C respectively, where further analysis was made using these optimal variables. Linear, Freundlich and Langmuir isotherms were studied and it was found that the Langmuir isotherms have the highest correlation coefficients compared to the others. Further, the sorption kinetics were analysed using pseudo-first-order and pseudo-second-order kinetic models. The data showed that the second-order equation was the more appropriate, which indicate that the intra-particle diffusion is the rate limiting factor. © 2009 Curtin University of Technology and John Wiley & Sons, Ltd.
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    Removal of remazol brilliant blue dye from dye-contaminated water by adsorption using red mud: Equilibrium, kinetic, and thermodynamic studies
    (2012) Ratnamala, G.M.; Shetty K, K.V.; Srinikethan, G.
    Utilization of industrial solid wastes for the treatment of wastewater from another industry could help environmental pollution abatement, in solving both solid waste disposal as well as liquid waste problems. Red mud (RM) is a waste product in the production of alumina and it poses serious pollution hazard. The present paper focuses on the possibility of utilization of RM as an adsorbent for removal of Remazol Brilliant Blue dye (RBB), a reactive dye from dye-contaminated water. Adsorption of RBB, from dye-contaminated water was studied by adsorption on powdered sulfuric acid-treated RM. The effect of initial dye concentration, contact time, initial pH, and adsorbent dosage were studied. Langmuir isotherm model has been found to represent the equilibrium data for RBB-RM adsorption system better than Freundlich model. The adsorption capacity of RM was found to be 27.8 mg dye/g of adsorbent at 40 °C. Thermodynamic analysis showed that adsorption of RBB on acid-treated RM is an endothermic reaction with ?H0 of 28.38 kJ/mol. The adsorption kinetics is represented by second-order kinetic model and the kinetic constant was estimated to be 0.0105 ± 0.005 g/mgmin. Validity of intra-particle diffusion kinetic model suggested that among the mass transfer processes during the dye adsorption process, pore diffusion is the controlling step and not the film diffusion. The process can serve dual purposes of utilization of an industrial solid waste and the treatment of liquid waste. © Springer Science+Business Media Dordrecht 2012.
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    Role of N-vinyl-2-pyrrolidinone on the thermoresponsive behavior of PNIPAm hydrogel and its release kinetics using dye and vitamin-B12 as model drug
    (2014) Maheswari, B.; JagadeeshBabu, P.E.; Agarwal, M.
    Temperature-sensitive hydrogels hold great promise in biological applications as they can respond to changes in physiological temperature to produce a desired effect like controlled drug delivery. In this study, a series of poly(N-isopropylacrylamide-co-N-vinyl-2-pyrrolidinone) thermosensitive hydrogels were synthesized by radical copolymerization of NIPAm with 1-vinyl-2-pyrrolidinone (NVP). By altering the initial NIPAm/NVP mole ratios, copolymers were synthesized to have their own distinctive lower critical solution temperature which was established using differential scanning calorimetry. The swelling behavior of the hydrogel was analyzed gravimetrically and it was observed that reswelling rate increases with increasing NVP mole ratio. Further characterizations of the hydrogels were performed using Fourier transform infrared spectroscopy and scanning electron microscopy. Release kinetics with respect to temperature was studied using methylene blue dye solution and vitamin B12. Kinetic modeling of the release profile revealed that the release mechanism is a non-Fickian diffusion mechanism. These results suggested that this material has potential application as intelligent drug carriers. The quantities of residual monomers in the PIV4 hydrogel were determined by HPLC method, and the results show almost complete conversion. © 2013 Taylor & Francis.
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    Hydrous Cerium Oxide Nanoparticles Impregnated Enteromorpha sp. for the Removal of Hexavalent Chromium from Aqueous Solutions
    (American Society of Civil Engineers (ASCE) onlinejls@asce.org, 2016) Selvasembian, S.; Selvaraju, N.; Raj Mohan, B.; Muhammed Anzil, P.K.; Amith, K.D.; Ushakumary, E.R.
    A novel nanobiocomposite, hydrous cerium oxide nanoparticles impregnated Enteromorpha sp. (HCONIE) was used effectively for the adsorption of Cr(VI) from aqueous solutions. The chemical and structural characteristics of the nanobiocomposite were investigated using Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) analysis. Adsorption studies were determined as a function of pH, contact time, initial concentration of Cr(VI), HCONIE dose, and temperature. The equilibrium adsorption data were modeled using two parameter isotherms, including Langmuir, Freundlich, Dubinin-Radushkevich (D-R), Temkin, Jovanovic, Halsey, and Harkin-Jura. Adsorption data were well described by the Freundlich and Halsey isotherm. The kinetics data were analyzed using adsorption kinetic models like the pseudo-first-order, pseudo-second-order and intraparticle diffusion equation. Kinetic data showed good agreement with the pseudo-second-order kinetic model. The obtained thermodynamic parameters showed that the adsorption of Cr(VI) onto the HCONIE was exothermic in nature. The presence of foreign ions showed a decreased effect on the adsorption capacity of HCONIE towards Cr(VI) removal. The desorption study was carried out with 0.1 and 0.5 M of three different desorbing agents. The study suggests that HCONIE nanobiocomposite could be used for the removal of Cr(VI) from aqueous solution. © 2015 American Society of Civil Engineers.
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    Computation of fluid flow in double sided cross-shaped lid-driven cavities using Lattice Boltzmann method
    (Elsevier Ltd, 2018) Bhopalam, S.B.; Arumuga Perumal, D.A.; Yadav, A.K.
    This work implements Lattice Boltzmann method to compute flows in double-sided cross-shaped lid-driven cavities. Firstly, a complicated geometry which is a symmetrized version of the staggered lid-driven cavity namely, the double-sided cross-shaped lid-driven cavity with antiparallel uniform wall motion is studied employing Single as well as Two Relaxation time models. The streamline patterns and vorticity contours obtained for low to moderate Reynolds numbers (150–1000) are compared with published results and found to be in good accordance. Next, this code is extended to simulate flows in a double-sided cross-shaped lid-driven cavity with parallel uniform wall motion. The effect of three dimensionality is also studied for low Reynolds numbers. Lattice Boltzmann method is then used to investigate the oscillating double-sided cross-shaped lid-driven cavity with antiparallel and parallel wall motions. The movement and formation of primary and secondary vortices have been well captured with the variation of Reynolds numbers and oscillating frequencies for uniform and oscillating wall motions. Reasonable agreements with the established results have been observed for the double-sided cross-shaped cavity with uniform wall motions, while new results have been obtained in the case of oscillating wall motions. © 2018 Elsevier Masson SAS
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    Fluid flow characteristics in double-sided lid-driven microcavity using lattice boltzmann method
    (Begell House Inc. orders@begellhouse.com, 2019) Rajan, I.; Arumuga Perumal, D.A.; Yadav, A.K.
    In this study, we analyze the fluid flow characteristic of rarefied gas flows in double-sided lid-driven microcavity subjected to various combinations of boundary conditions that simulate the slip at the walls using lattice Boltzmann method (LBM) constituting a single relaxation time (SRT) model. The fluid motion inside a closed square container with two rigid walls and two moving walls constitutes an exemplar for internal vortex flows. First, a complicated geometry, namely, the single-sided lid-driven microcavity is studied using the LBM-SRT model. Next, this code is extended to simulate flows in a double-sided microcavity flow. Numerical computation of fluid flow incorporating various slip boundary conditions as bounce-back and specular boundary condition (BSBC) for different values of tangential accommodation momentum coefficient (TMAC) has been investigated. Various values of Knudsen number in the slip and transition regime (Kn = 0.01, 0.05, 0.10, 0.135, and 0.15) along with different aspect ratios of 0.33, 0.50, 1.0, 2.0, and 3.0 have been considered in this study. The streamline patterns and velocity profiles were obtained for different Knudsen numbers. The formation and movement of primary vortices have been well captured with the variation of Knudsen numbers for different aspect ratios of microcavity. © 2019 by Begell House, Inc.
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    Study of adiabatic obstacles on natural convection in a square cavity using lattice boltzmann method
    (American Society of Mechanical Engineers (ASME) infocentral@asme.org, 2019) Karki, P.; Yadav, A.K.; Arumuga Perumal, D.A.
    This study involves the effect of adiabatic obstacles on twodimensional natural convection in a square enclosure using lattice Boltzmann method (LBM). The enclosure embodies squareshaped adiabatic obstacles with one, two, and four in number. The single obstacle in cavity is centrally placed, whereas for other two configurations, a different arrangement has been made such that the core fluid zone is not hampered. The four boundaries of the cavity considered here consist of two adiabatic horizontal walls and two differentially heated vertical walls. The current study covers the range of Rayleigh number (10 3 ? Ra ? 10 6 ) and a fixed Prandtl number of 0.71 for all cases. The effect of size of obstacle is studied in detail for single obstacle. It is found that the average heat transfer along the hot wall increases with the increase in size of obstacle until it reaches an optimum value and then with further increase in size, the heat transfer rate deteriorates. Study is carried out to delineate the comparison between the presences of obstacle in and out of the conduction dominant zone in the cavity. The number of obstacles (two and four) outside of this core zone shows that heat transfer decreases despite the obstacle being adiabatic in nature. © 2019 by ASME.
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    A review of lattice boltzmann method computational domains for micro-and nanoregime applications
    (Begell House Inc., 2020) Narendran, G.; Arumuga Perumal, A.P.; Gnanasekaran, N.
    In the last two decades, microscale and nanoscale devices have received much interest due to the inevitable performance and their numerous applications not only in the field of fluid flow and heat transfer but also in bio-technology, bio-medical engineering, etc. In many situations, besides the conventional experiments and theoretical analysis, computations have emerged as a valuable tool for investigating the fluid transport and heat transfer phenomena. The lattice Boltzmann method (LBM) has emerged as an important option for micro-and nanoscale devices due to the fact that the LBM is well established for the range of Knudsen number. A comparative study on several working fluids used in the field of micro-and nanodevices such as microchannel, micro-cavity, microboiling, and nanochannel is categorized. Various aspects of nanofluids used in natural convection with different cavity configurations, flow boiling, immiscible fluids, liquid–vapor phase change are also critically reviewed. Different remarks and findings of available numerical results with several investigated parameters were summarized. © 2020 Begell House, Inc.
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    Kinetics and regression analysis of phenanthrene adsorption on the nanocomposite of CaO and activated carbon: Characterization, regeneration, and mechanistic approach
    (Elsevier B.V., 2021) Aravind Kumar, J.; Krithiga, T.; Vijai Anand, K.; Sundararaman, S.; Karthick Raja Namasivamyam, S.; Annam Renita, A.A.; Hosseini-Bandegharaei, A.; Praveenkumar, T.R.; Manivasagan, M.; Bhat, N.S.; Dutta, S.
    In the present study, calcium oxide supported on activated carbon (CaO@AC) nanocomposite was synthesized using Basil leaf extract as a promoter and used to remove phenanthrene, an environmental pollutant, from aqueous solution. The activated carbon (AC) was prepared by the carbonization of Palm shells under pyrolytic conditions. The CaO@AC nanocomposite was characterized by FTIR, SEM-EDX, BET, and PXRD. The characterized CaO@AC nanocomposite was employed as an adsorbent for selective removal of phenanthrene from wastewater, maintaining the optimized conditions at initial phenanthrene concentration (5 mg/L), catalyst dosage (1 g), temperature (30 °C), and pH (7.6) for all batches. The adsorption isotherm and the kinetic studies for regression analysis were well fitted for the Freundlich model (R2 = 0.9956) and non-linear Pseudo (II order) mechanism (R2 = 0.9942). The results showed that the type IV linear form of pseudo-II order kinetic expression was inadequate for the kinetic rate parameters compared to the type I - III models. The CaO@AC was demonstrated as an inexpensive, scalable, recyclable, and eco-friendly adsorbent material for removing phenanthrene from wastewater. © 2021 Elsevier B.V.
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    Synthesis and characterisation of an ultra-light, hydrophobic and flame-retardant robust lignin-carbon foam for oil-water separation
    (Elsevier Ltd, 2021) Vannarath, A.; Thalla, A.K.
    The lignin extracted from Arecanut husk (Areca catechu) was used as an additive in lignin-carbon foam synthesis to enhance oil uptake in oil-water separation. The lignin yield from the arecanut husk increased as the husk fibre size reduced. The extracted lignin and lignin-carbon foam were characterised for morphology, structural, compositional and thermal degradation properties. The synthesised lignin-carbon foam appears to be ultralight (density = 0.0294 g/cm3), excellent hydrophobic (water contact angle was 124°), mesoporous (3D cell-like structure), fire-retardant and thermally stable. The foam showed an excellent sorption capacity for different oils, and the highest sorption was observed for diesel oil (7842.71 mg/g). The optimisation of contact time (30 min), lignin-carbon foam dosage (0.5 g), and initial oil concentration (30 g/L) were done for the diesel oil sorption. The isotherm study and kinetic model evaluation were done for the diesel adsorption on the lignin-carbon foam. The Temkin model was found the best fit for the adsorption isotherm. The adsorption kinetics of the lignin-carbon foam for diesel oil was best described by pseudo-second-order kinetics. The thermodynamic parameters showed that the adsorption was endothermic and spontaneous (standard enthalpy change, ?H° = +4926.46 J/mol and standard entropy change, ?S° = 25.249 J/mol/K). The proposed mechanism depicts that the adsorption primarily influenced hydrogen bonding (H-bonding) and n-? interactions. The enduring adsorption of oil into the lignin-carbon foam within few seconds shows the material oleophilicity and confirms their application prospect in oil spill cleanup. © 2021