Faculty Publications
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Item Extruded poly(ethylene-co-octene)/fly ash composites - Value added products from an environmental pollutant(Kluwer Academic Publishers, 2012) Anandhan, S.; Sundar, S.M.; Senthil, T.; Mahendran, A.R.; Shibulal, G.S.Fly ash (FA) is a by-product generated during combustion of coal and has caused serious environmental concerns. In an effort to utilize FA beneficially, we developed composites from an ethylene-octene random copolymer (EOC) and unmodified as well as surfacemodified class-F fly ash (MFA) by twin screw extrusion. Addition of 20 wt% of MFA to EOC improves its tensile strength by 150%; also, MFA improves stress at 100% and 300% strains (M100 and M300) of EOC. Thermal stability of EOC matrix is appreciably improved by the addition of either FA or MFA, while the melting behavior is not appreciably influenced by either. Fractography study reveals an improved adhesion between the EOC and MFA particles up to a filler loading of 20%, beyond which the adhesion between EOC and MFA is weakened causing a reduction in mechanical properties. The 'flammable' nature of EOC changes to 'self extinguishing' on addition of even 10 wt% of FA or MFA, as found out from LOI study. © Springer Science+Business Media B.V. 2012.Item Optical and mechanical properties of calcium phosphate glasses(Maik Nauka Publishing / Springer SBM compmg@maik.ru, 2014) Venkateswara Rao, G.V.; Shashikala, H.D.Binary calcium phosphate glasses in the system, xCaO-(100 - x) P 2O5 with x = 30, 35, 40, 45, and 50 mol % were prepared by conventional melt quenching technique. The density, molar volume and refractive index of the glasses were found to increase with the increase in CaO content. Structural investigation by FTIR spectroscopy revealed that the substitution of P2O5 by CaO depolymerizes the phosphate glass network by systematic conversion of Q3 structural units to Q2 structural units by breaking the P-O-P links. From the optical absorption studies, the optical band gap values were found to decrease with increasing CaO content which can be due to increase in the concentration of non-bridging oxygens in the glass network. Vickers hardness increased with the calcium oxide content due to densification. The fracture toughness decreases with the increase in CaO content due to the increase in the bond density between the modifying cations and the non-bridging oxygens in the glass network. It was observed that brittleness increases with the addition of CaO content which can be mainly attributed to the decrease in the molar volume. © 2014 Pleiades Publishing, Ltd.Item Structural, optical and mechanical properties of ternary CaO-CaF2-P2O5 glasses(Tsinghua University, 2014) Venkateswara Rao, G.V.; Shashikala, H.D.The ternary phosphate glass series (50?x)CaO-xCaF2-50P2O5 (x = 0–20 mol%) were synthesized using melt quench technique. Structural, optical and mechanical properties were investigated with increase in CaF2 content. Using X-ray diffraction (XRD), synthesized glasses were confirmed to be amorphous in nature. Replacement of oxygen ions by fluorine ions increased the values of density. Decrease in refractive index due to the low polarizability of fluorine ions in the glass matrix was observed. In Fourier transform infrared (FTIR) spectra, the slight variation in ?as (PO2) band position and intensity could be attributed to replacement of fluorine ions for oxygen ions in phosphate glass structure. These data were well supported by Raman spectra. Optical band gap energy increased from 3.44 eV to 3.64 eV with increase in CaF2 content, and Urbach energy decreased suggesting that the fluorine ions reduced the tail energy states in the band gap compared to the oxygen ions. Mechanical parameters such as Vickers hardness, fracture toughness and brittleness were evaluated from the Vickers micro indentation measurements. Increase in Vickers hardness, decrease in fracture toughness and increase in brittleness were observed with increase in CaF2 content. © 2014, The Author(s).Item Optical, dielectric and mechanical properties of silver nanoparticle embedded calcium phosphate glass(Elsevier, 2014) Venkateswara Rao, G.V.; Shashikala, H.D.Silver nanoparticles have been embedded in 50 mol% CaO-50 mol% P 2O5 glass using melt quenching technique. The quenched glasses were heat treated at 550 °C for different durations between 10 and 50 h. The growth of silver nanoparticles in glass matrix appeared to be time dependent. FTIR spectra revealed that silver nanocluster formation had not affected the position of vibration bands of basic phosphate tetrahedral network. The Ag nanoparticle embedded glass matrix showed the red shift and broadening of the surface plasmon resonance (SPR) peak in the visible region with the increase in the duration of the heat treatment. Results showed the increase in size of the nanoparticles in glass matrix with heat treatment which was further confirmed using transmission electron microscopy and XRD. X-ray diffraction studies indicated the presence of Ag crystalline peaks along with amorphous structure on heat treatment at 550 °C for 50 h. The dielectric constant of these glasses increased as the duration of the heat treatment increased. Increase in both Vickers hardness and fracture toughness, and decrease in brittleness were observed which can be attributed to the increase in size of the nanoparticles in glass matrix. © 2014 Elsevier B.V.Item Effect of heat treatment on optical, dielectric and mechanical properties of silver nanoparticle embedded CaOCaF2P2O5 glass(Elsevier Ltd, 2015) Venkateswara Rao, G.; Shashikala, H.D.Silver nanoparticle have been embedded in CaOCaF2P2O5 glass using melt quenching technique. The quenched glasses were heat treated at 550 °C for 10, 20, 30, 40 and 50 h. The growth of silver nanoparticle in the glass matrix appeared to be time dependent. FTIR spectra show that silver nanoparticle formation has not affected the vibration bands of basic phosphate tetrahedral network. The increase in compactness of the glass structure is confirmed by increase in measured density of the glasses with increase in the duration of the heat treatment. Glass containing spherical silver nanoparticle shows the red shift and increase in the full width half maxima (FWHM) of the surface plasmon resonance (SPR) in the visible region with increase in the duration of the heat treatment. X-ray diffraction pattern indicated the presence of Ag crystalline peaks along with amorphous structure on heat treating at 550°C for 50 h. For the glass samples, the increase in dielectric constant and low dielectric loss around 0.005 were observed with increase in duration of the heat treatment. Both Vickers hardness and fracture toughness increased while the brittleness decreased which can be attributed to the increase in size of the nanoparticles in glass matrix. © 2014 Elsevier B.V. All rights reserved.Item Joining of Inconel-625 alloy through microwave hybrid heating and its characterization(Elsevier Ltd, 2015) Badiger, R.I.; Narendranath, S.; Srinath, M.S.Joining of bulk metals using microwave energy is being explored as a new processing method in the era of high technology applications. The present work investigates the results of on-going project in which joining of Inconel-625 alloy has been effectively carried out through microwave hybrid heating. Characterization of the microwave developed joints is done through SEM, XRD, UTM and Vicker's microhardness tester. The microstructural analysis through scanning electron microscope exhibits a fully fused weld interface free from interfacial cracks. XRD study reveals the formation of carbides of Ni, Cr and Mo in the joint interface. The average Vicker's microhardness in the joint region observed was 360 ± 20 Hv. Assessment of tensile strength shows an ultimate tensile strength of 328 MPa with 9.04% elongation. Further the fractured joints are subjected to fractography study which possibly reveals a mixed mode fracture. © 2015 The Society of Manufacturing Engineers. Published by Elsevier Ltd. All rights reserved.Item Mechanical properties of Nd3+-doped phosphate laser glasses(Society of Glass Technology christine@glass.demon.co.uk, 2015) Venkateswara Rao, G.; Vijaya, N.; Joshi, A.S.; Shashikala, H.D.; Jayasankar, C.K.The mechanical properties of P2O5+K2O+BaO+Al2O3+Nd2O3 (PKBANd) glasses were studied using the Vickers indentation technique. The values of Vickers hardness, fracture toughness and brittleness of the glass samples were evaluated. The surface morphology of the indentations were analyzed using scanning electron microscopy. An increase in Vickers hardness, fracture toughness and decrease in brittleness were observed with an increase in Nd2O3 concentration in the phosphate glass matrix. A decrease in the brittleness of the synthesized glass samples was confirmed by scanning electron microscopy of median/radial cracks generated due to Vickers indentation pattern with increase in Nd2O3 concentration.Item Dielectric and piezoelectric properties of PVDF/PZT composites: A review(John Wiley and Sons Inc, 2015) Jain, A.; Prashanth, K.J.; Sharma, A.K.; Jain, A.; P.n, R.Smart materials, which exhibit piezoelectricity, find an eclectic range of applications in the industry. The direct piezoelectric effect has been widely used in sensor design, and the inverse piezoelectric effect has been applied in actuator design. Ever since 1954, PZT and BaTiO3 were widely used for sensor and actuator applications despite their toxicity, brittleness, inflexibility, etc. With the discovery of PVDF in 1969, followed by development of copolymers, a flexible, easy to process, nontoxic, high density alternate with high piezoelectric voltage coefficient was available. In the past 20 years, heterostructural materials like polymer ceramic composites, have received lot of attention, since these materials combine the excellent pyroelectric and piezoelectric properties of ceramics with the flexibility, processing facility, and strength of the polymers resulting in relatively high dielectric permittivity and breakdown strength, which are not attainable in a single phase piezoelectric material. The current review article is an attempt to provide a compendium of all the work carried out with reference to PVDF-PZT composites. The review article evaluates the effect of grain size, content and other factors under the purview of dielectric and piezoelectric properties while evaluating the sensitivity of the material for sensor application.Item Determination of fracture toughness and fatigue crack growth rate using circumferentially cracked round bar specimens of Al2014T651(Elsevier Masson SAS infos@masson.fr 62 rue Camille Desmoulins Issy les Moulineaux Cedex 92442, 2015) Neelakantha, V.L.; Jayaraju, T.; Naik, P.; Kumar K, D.; Rajashekhar, C.R.; Kumar, M.Fracture toughness (KIC) and fatigue crack growth rate (FCGR) are the important material properties in fracture mechanics. ASTM-E399 and ASTM-E647 are the standards for determination of KIC and FCGR of metallic materials. These standards recommend the use of compact tension (CT) or single edge notched bend (SENB) test specimens. Literature review indicates that CT or SENB specimens are complex in nature, difficult to manufacture, require typical fixtures for loading during experimentation and the test procedures using CT or SENB are time consuming and cumbersome. An alternate specimen geometry which can overcome the above said drawbacks is needed by the industry which can be used as standard test specimen geometry. This research work explains use of circumferentially cracked round bar (CCRB) specimens of high strength Al2014T651 alloy for determination of KIC and FCGR.The pre-cracked round bar specimen was loaded in tensile in a universal testing machine and pulled till failure. Using suitable stress intensity factor equations the fracture toughness can be calculated. In case of crack growth test, the pre-cracked round bar specimen is allowed to rotate under fatigue load. The ratio of length of crack propagated to the number of cycles to failure was the crack growth rate. The SEM analysis of fractured surfaces was also done.The results are comparable with the values reported in the literature obtained by using standard test specimens. There are numerous advantages of using round bar specimen in KIC and FCGR tests. It is concluded that, the methodology of determination of fracture toughness and fatigue crack growth rate using CCRB specimens is relatively simple, reliable, fast and economical. CCRB specimen may be recommended as a standard test specimen for fracture toughness as well as crack growth tests. © 2015 Elsevier Masson SAS. All rights reserved.Item Physical, mechanical and structural properties of BaO-CaF2-P2O5 glasses(Elsevier, 2015) Narayanan, M.K.; Shashikala, H.D.Mechanical properties and structure of melt-quenched ternary barium phosphate glasses belonging to the composition (50 - X)BaO-XCaF2-50P2O5 (X = 0 to 10 mol%) were studied using Vickers indentation and vibrational spectroscopy. Elastic moduli of prepared samples were calculated using the Makishima and Mackenzie (M-M) model. Density of glasses was measured using the Archimedes method, while molar volume and atomic packing density were calculated from measured density to study structural changes in the glass matrix. Vickers hardness and brittleness increased and fracture toughness decreased with increase in CaF2 content. This can be attributed to increase in the compactness of phosphate bonds and reduction in the molar volume of glasses with partial substitution of Ba2 + with Ca2 +. Infrared and Raman spectroscopies revealed that the glass network mainly consisted of metaphosphate units arranged in chain and ring structures together with small amounts of ultraphosphate and pyrophosphate units. © 2015 Elsevier B.V. All rights reserved.