Faculty Publications
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Item Synthesis, characterization and applications of metal complexes of 5-nitrosalicylidene 4-amino 3-mercapto-1, 2, 4-triazine- 5-one(2010) Ramasubramanian, A.S.; Badekai Ramachandra, B.; Ramakrishna, R.Transition metal complexes of Cu(II), Ni(II), Co(II) with 5- Nitro salicylidene 4- amino 3 -mercapto 1,2,4 triazine-5-one have been synthesized and characterized by analytical and spectral techniques. All metal complexes form ML type of complexes. Based on analytical data, IR spectra and magnetic moments Co (II), Ni (II) are assigned octahedral geometries while Cu (II) a square planar geometry. In all these complexes azomethine nitrogen, carbonyl oxygen and phenolic oxygen are involved in bond formation.Item Transition metal complexes of 5-bromosalicylidene-4-amino-3-mercapto-1,2,4- triazine-5-one: Synthesis, characterization, catalytic and antibacterial studies(Serbian Chemical Society, 2011) Ramasubramanian, A.S.; Badekai Ramachandra, B.; Dileep, R.; Rani, S.Transition metal complexes of 5-bromosalicylidene-4-amino-3-mercapto-1,2,4- triazine-5-one with metal precursors, such as Cu(II), Ni(II), Co(II) and Pd(II), were synthesized and characterized by physico-chemical and spectroscopic techniques. All the complexes are of the ML type. Based on analytical, spectral data and magnetic moments, the Co(II) and Ni(II) complexes were assigned octahedral geometries, while the Cu (II) and Pd(II) complexes square planar. A study on the catalytic oxidation of benzyl alcohol, cyclohexanol, cinnamyl alcohol, 2-propanol and 2-methyl-1-propanol was performed with N-methylmorpholine-N-oxide (NMO) as co-oxidant. All the complexes and their parent organic moiety were screened for their biological activity on several pathogenic bacteria and were found to possess appreciable bactericidal properties. © 2011 Copyright (CC) SCS.
