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    The hydrogen peroxide-mediated oxidation of biorenewable furfural to 2(5H)-furanone using heteropolyacids supported on ammonium y zeolite as the catalyst
    (Elsevier Ltd, 2020) Tiwari, R.; Bhat, N.S.; Mal, S.S.; Dutta, S.
    A series of heteropolyacid supported on ammonium Y zeolite (HPA-NH4YZ) catalysts were prepared and used for the catalytic oxidation of furfural to 2(5H)-furanone in aqueous hydrogen peroxide. The catalysts were characterized by PXRD, FTIR, TGA, and SEM analyses. The organic-solvent-free reaction was optimized on temperature, duration, loading of catalyst, and the equivalent of H2O2. The 20%PTA-NH4YZ catalyst showed the best catalytic activity giving 2(5H)-furanone in 40% isolated yield by solvent extraction under optimized conditions (20wt% cat., 100°C, 90min, 7.5eq. 30%H2O2). In addition, around 20% of succinic acid was recovered from the aqueous layer. © 2020 Elsevier Ltd. All rights reserved.
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    Selective oxidation of biomass-derived furfural to 2(5H)-furanone using trifluoroacetic acid as the catalyst and hydrogen peroxide as a green oxidant
    (Springer Science and Business Media Deutschland GmbH, 2023) Bhat, N.S.; Kumar, R.; Jana, A.; Mal, S.S.; Dutta, S.
    In this work, biomass-derived furfural has been selectively oxidized to 2(5H)-furanone using aqueous hydrogen peroxide as the green oxidant. Among various homogeneous acid catalysts screened for the transformation, trifluoroacetic acid (TFA) was found to be the most suitable candidate that afforded up to 52% isolated yield of 2(5H)-furanone under mild conditions (RT, 1 h). In addition, succinic acid was recovered in nearly 20% yield from the aqueous layer. The organic solvent-free, gram-scale reaction was optimized on temperature, the molar ratio of H2O2 and furfural, and the amount of TFA used. [Figure not available: see fulltext.]. © 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature.