Faculty Publications
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Item Facile hydrothermal synthesis of vanadium disulfide nanomaterial for supercapacitor application(SPIE, 2023) Mandal, A.; Pandey, N.; Pandey, S.K.; Yadav, A.K.; Chakrabarti, S.Vanadium disulfide (VS2) is a prominent metallic member of transition metal dichalcogenides (TMDs) family and has already demonstrated its flair in energy storage device applications such as supercapacitors and batteries. In this work, we have synthesized hexagonal shape VS2 nanomaterial using a facile one step hydrothermal route and investigated the phase, morphology and structural properties of the material. The formation of phase has been confirmed from the X-ray diffraction (XRD) plot by correlating with the database of Joint Committee on Powder Diffraction Standards (JCPDS) 00-036-1139 of 1T VS2. Further, the crystalline behavior of VS2 nanomaterial can be seen from the high resolution transmission electron microscopy (HRTEM) measurement. Moreover, the morphology of the synthesized material is obtained from the field emission gun-scanning electron microscopy (FEG-SEM). Also, the characteristic Raman peaks of 1T VS2 at 140.3 cm-1 and 192.3 cm-1 have been observed from the Raman spectrum indicating the metallic behavior of synthesized material. The peak at 281.8 cm-1 is attributed to the in-plane vibrational mode (E2g1) while the peak at 404.5 cm-1 represents the out-of-plane vibrational mode (A1g) of V-S bond. The Fourier transform infrared (FTIR) spectrum shows the V-S-V and V=S vibrational modes around 534 cm-1 and 982 cm-1 respectively. The study introduces a low cost, large scale, highly crystalline, and metallic VS2 nanomaterial with potential application for next generation supercapacitors and other energy storage devices. © 2023 SPIE.Item Electroslag remelting experiments have been carried out on En 24 steel using two slag compositions in indigeneously constructed 350 KVA DC and 50 KVA AC ESR units. Detailed quantitative characterisation of the inclusions of different types has been carried out using Quantimet Image Analyser. The inclusion content in terms of volume fraction and density (No/mm2) and their size distribution in the refined ingot and the unrefined steel have been assessed. The chemical composition of selected inclusions has been established by electron probe microanalyser (EPMA). These studies are supplemented by scanning electron microscopy on typical fractured specimens. The present study shows that the DC reverse polarity mode of melting using a slag with higher silica content (10 wt%) offers the best conditions with particular reference to removal of inclusions and modification of inclusion morphology as compared to the ingots produced by DC straight polarity and AC modes of melting.(Studies on inclusion characterization in electroslag refined En24 steel) Udupa, K.R.; Subramanian, S.; Sastry, D.H.; Iyengar, G.N.K.1994Item Unintentionally doped homoepitaxial InSb films have been grown by liquid phase epitaxy employing ramp cooling and step cooling growth modes. The effect of growth temperature, degree of supercooling and growth duration on the surface morphology and crystallinity were investigated. The major surface features of the grown film like terracing, inclusions, meniscus lines, etc are presented step-by-step and a variety of methods devised to overcome such undesirable features are described in sufficient detail. The optimization of growth parameters have led to the growth of smooth and continuous films. From the detailed morphological, X-ray diffraction, scanning electron microscopic and Raman studies, a correlation between the surface morphology and crystallinity has been established.(Indian Academy of Sciences, Influence of growth parameters on the surface morphology and crystallinity of InSb epilayers grown by liquid phase epitaxy) Udayashankar, N.K.; Bhat, H.L.2003Item The effect of the inclusion of ceramic particles in polythene material on the response to erosion due to impingement by sand particles at three angles is investigated. It is seen that erosion resistance varies with ceramic inclusions. The work also considers the limitations posed by the system in adopting weight change measurements as a measure to follow erosive wear owing to the softer nature of the matrix material. Consequently, the investigation looks at two other experimental parameters that can readily be measured to quantify erosion. Of the two approaches, the advantages of following wear through measuring linear dimension of the resulting crater is stressed in this work. The study also highlights the problems associated in assessing the depth of the crater as a parameter to express the extent of erosion owing to the phenomenon of material flow suggested and schematically illustrated in the work. Corroborative evidence for this flow behaviour through scanning electron microscopic studies is presented. © 2002 Elsevier Science Ltd. All rights reserved.(Elsevier Ltd, On evaluating erosion by sand particles in polythene system without and with ceramic particles) Kishore; Sridhar, G.B.2002Item Ductile cast iron was austenitized at four different temperatures and subsequently austempered at six different temperatures. Plane strain fracture toughness was evaluated under all the heat treatment conditions and correlated with the microstructural features such as the austenite content and the carbon content of the austenite. Fracture mechanism was studied by scanning electron microscopy. It was found that the optimum austempering temperature for maximum fracture toughness decreased with increasing austenitizing temperature. This could be interpreted in terms of the microstructural features. A study of the fracture mechanism revealed that good fracture toughness is unlikely to be obtained when austempering temperature is less than half of the austenitizing temperature on the absolute scale. © 2002 Elsevier Science B.V. All rights reserved.(Elsevier BV, Investigations on the fracture toughness of austempered ductile irons austenitized at different temperatures) Prasad Rao, R.; Putatunda, S.K.2003Item SiC particulate reinforced A356 Al metal matrix composites were laser treated using pulsed Nd-YAG laser beam. The processing was carried out in air atmosphere at varying pulse energy (5 to 20 J) and scan rates (30 to 150 mm/sec). The samples were cut perpendicular to the track and they were characterized using optical microscopy, scanning electron microscopy and X-ray diffraction. Microstructure of laser treated region consists of regular succession of coarse and fine microstructure signifying the presence of low velocity bands. Transition from cellular/columnar dendritic to equiaxed dendritic structure has been observed. Microstructure of samples laser treated with specific energy greater than 13 kJ/cm2 show presence of Al 4C3 platelets. © 2004 Kluwer Academic Publishers.(Microstructural studies in low specific energy laser surface treated Al(A356)-SiCp composites) Bhat, K.U.; Surappa, M.K.2004Item Methanol selective oxidation to formaldehyde over a modified Fe-Mo catalyst with two different stoichiometric (Mo/Fe atomic ratio = 1.5 and 3.0) was studied experimentally in a fixed bed reactor over a wide range of reaction conditions. The physicochemical characterization of the prepared catalysts provides evidence that Fe2(MoO4)3 is in fact the active phase of the catalyst. The experimental results of conversion of methanol and selectivity towards formaldehyde for various residence times were studied. The results showed that as the residence time increases the yield of formaldehyde decreases. Selectivity of formaldehyde decreases with increase in residence time. This result is attributable to subsequent oxidation of formaldehyde to carbon monoxide due to longer residence time.(Selective oxidation of methanol to formaldehyde using modified iron-molybdate catalysts) Kim, T.-H.; Badekai Ramachandra, B.; Choi, J.-S.; Saidutta, M.B.; Choo, K.-Y.; Song, S.-D.; Rhee, Y.-W.2004Item Epoxy systems with and without different volume fractions of fly ash particulate fillers are made and their absorption due to immersion in saline water maintained at room temperature are established through weight measurements recorded up to 100h. The 100-h exposed samples are additionally subjected to compression tests to evaluate the strength. The results show that both neat epoxy and fly ash-bearing composites exhibit differing levels of aqueous medium absorption - it being less in ash-free samples. When the ash content in the system is large, the absorption levels are high. The data further revealed that the unexposed samples generally record an increasing strength value with ash content. However, for the exposed cases, a reversal in trend with the ash content is noticed. Attempts to explain these differing trends are made in this work by analyzing the features observed on the surface of compression-failed samples using fractography employing scanning electron microscopy (SEM). © 2005 Sage Publications.(Compression strength of saline water-exposed epoxy system containing fly ash particles) Kishore; Barpanda, P.; Kulkarni, S.M.2005Item Molybdenum based mixed oxide containing Mo0.65V 0.25W0.10 was investigated for the partial oxidation of methanol. The structural property and catalytic activity of the mixed oxide catalyst was studied by surface area (BET), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), Fourier transform infra-red spectroscopy (FTIR) and X-ray diffraction (XRD). The thermal activation of the catalyst resulted increase in the conversion of methanol and the selectivity to formaldehyde. The thermal activation of the MoVW mixed oxide in nitrogen atmospheres induces partial crystallization of a Mo5O14-type oxide at 813 K. The SEM images of the thermally activated catalyst show needle like particles. These particles were agglomerates of platelet-like crystallites of a few hundreds of nanometers in size. SEM and EDX techniques show that the mixed oxide is characterized by an inhomogeneous elemental distribution on the length scale of a few microns. XRD of the thermally activated catalyst showed a nanocrystalline material identified as a mixture of Mo5O 14, MoO3 and MoO2-type MoVW oxides. The catalytic activity of the MoVW mixed oxide show a good conversion of methanol and selectivity to formaldehyde. © 2005 Springer Science+Business Media, Inc.(Partial oxidation of methanol to formaldehyde on molybdenum based mixed oxide catalyst) Badekai Ramachandra, B.; Choi, J.-S.; Choo, K.-Y.; Sung, J.-S.; Song, S.-D.; Kim, T.-H.2005