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Quantification and morphology studies of nanoporous alumina membranes: A new algorithm for digital image processing
(2013) Choudhari, K.S.; Jidesh, P.; Sudheendra, P.; Kulkarni, S.D.
A new mathematical algorithm is reported for the accurate and efficient analysis of pore properties of nanoporous anodic alumina (NAA) membranes using scanning electron microscope (SEM) images. NAA membranes of the desired pore size were fabricated using a two-step anodic oxidation process. Surface morphology of the NAA membranes with different pore properties was studied using SEM images along with computerized image processing and analysis. The main objective was to analyze the SEM images of NAA membranes quantitatively, systematically, and quickly. The method uses a regularized shock filter for contrast enhancement, mathematical morphological operators, and a segmentation process for efficient determination of pore properties. The algorithm is executed using MATLAB, which generates a statistical report on the morphology of NAA membrane surfaces and performs accurate quantification of the parameters such as average pore-size distribution, porous area fraction, and average interpore distances. A good comparison between the pore property measurements was obtained using our algorithm and ImageJ software. This algorithm, with little manual intervention, is useful for optimizing the experimental process parameters during the fabrication of such nanostructures. Further, the algorithm is capable of analyzing SEM images of similar or asymmetrically porous nanostructures where sample and background have distinguishable contrast. Copyright Â© Microscopy Society of America 2013.
Multilayer Zn-Ni-Al2O3 coatings for corrosion protection
(Inderscience Publishers, 2014) Ullal, Y.; Hegde, A.C.
The paper reports the development of composite coatings of Zn-Ni-Al2O3 by composition modulated multilayer (CMM) technique using m-aminophenol and gelatin as additives. The bath constituents and deposition parameters were optimised by conventional method. The role of gelatin and m-aminophenol in the bath was analysed by cyclic voltammetry (CV) study. Corrosion performance of the monolayer coatings was enhanced further by multilayer technique. The modulation in composition was effected by pulsing the DC in square-wave patterns. The coatings configurations were optimised for peak performance of the coatings against corrosion. It was found that corrosion resistance of CMM coatings increased with number of layers up to certain optimal numbers, and then decreased. Incorporation of Al2O3 particles into metal matrix was confirmed by EDAX. Formation of layered coating and their phase structures were analysed by scanning electron microscopy (SEM) and X-ray diffraction (XRD) study. Reasons responsible for better corrosion resistance of CMM composite coatings are analysed and results are discussed. Copyright Â© 2014 Inderscience Enterprises Ltd.
Hot-dip Aluminizing of Low Carbon Steel in Al & Al-5wt % Cr Baths
(Elsevier Ltd, 2018) Huilgol, P.; Bhat, K.U.; Udupa, K.R.
Hot dip aluminizing of low carbon steel is carried out in pure aluminium bath and Al-5wt% Cr bath. The coating is characterized by scanning electron microscopy and chemical composition of the coating is analysed by EDS (energy dispersive spectroscopy) attached to SEM. The coating consists of three regions, viz., outer aluminium topcoat, intermediate Fe-Al intermetallics layer and the base alloy. The intermetallics layer consists of FeAl3 and Fe2Al5 phases. Fe2Al5 is the major phase in the intermetallics layer. The growth kinetics of intermetallics layer is parabolic in nature implying that it is diffusion controlled. Addition of chromium forms Al7Cr dispersed intermetallics phases in the aluminium topcoat. Addition of chromium has no influence on the morphology of the intermetallics layer. Scratch resistance of the coating is carried out to evaluate the scratch hardness of the coating. Chromium addition improves scratch resistance of the coating. Â© 2018 Elsevier Ltd.
Facile hydrothermal synthesis of vanadium disulfide nanomaterial for supercapacitor application
(SPIE, 2023) Mandal, A.; Pandey, N.; Pandey, S.K.; Yadav, A.K.; Chakrabarti, S.
Vanadium disulfide (VS2) is a prominent metallic member of transition metal dichalcogenides (TMDs) family and has already demonstrated its flair in energy storage device applications such as supercapacitors and batteries. In this work, we have synthesized hexagonal shape VS2 nanomaterial using a facile one step hydrothermal route and investigated the phase, morphology and structural properties of the material. The formation of phase has been confirmed from the X-ray diffraction (XRD) plot by correlating with the database of Joint Committee on Powder Diffraction Standards (JCPDS) 00-036-1139 of 1T VS2. Further, the crystalline behavior of VS2 nanomaterial can be seen from the high resolution transmission electron microscopy (HRTEM) measurement. Moreover, the morphology of the synthesized material is obtained from the field emission gun-scanning electron microscopy (FEG-SEM). Also, the characteristic Raman peaks of 1T VS2 at 140.3 cm-1 and 192.3 cm-1 have been observed from the Raman spectrum indicating the metallic behavior of synthesized material. The peak at 281.8 cm-1 is attributed to the in-plane vibrational mode (E2g1) while the peak at 404.5 cm-1 represents the out-of-plane vibrational mode (A1g) of V-S bond. The Fourier transform infrared (FTIR) spectrum shows the V-S-V and V=S vibrational modes around 534 cm-1 and 982 cm-1 respectively. The study introduces a low cost, large scale, highly crystalline, and metallic VS2 nanomaterial with potential application for next generation supercapacitors and other energy storage devices. Â© 2023 SPIE.
Electroslag remelting experiments have been carried out on En 24 steel using two slag compositions in indigeneously constructed 350 KVA DC and 50 KVA AC ESR units. Detailed quantitative characterisation of the inclusions of different types has been carried out using Quantimet Image Analyser. The inclusion content in terms of volume fraction and density (No/mm2) and their size distribution in the refined ingot and the unrefined steel have been assessed. The chemical composition of selected inclusions has been established by electron probe microanalyser (EPMA). These studies are supplemented by scanning electron microscopy on typical fractured specimens. The present study shows that the DC reverse polarity mode of melting using a slag with higher silica content (10 wt%) offers the best conditions with particular reference to removal of inclusions and modification of inclusion morphology as compared to the ingots produced by DC straight polarity and AC modes of melting.
(Studies on inclusion characterization in electroslag refined En24 steel) Udupa, K.R.; Subramanian, S.; Sastry, D.H.; Iyengar, G.N.K.
1994
Unintentionally doped homoepitaxial InSb films have been grown by liquid phase epitaxy employing ramp cooling and step cooling growth modes. The effect of growth temperature, degree of supercooling and growth duration on the surface morphology and crystallinity were investigated. The major surface features of the grown film like terracing, inclusions, meniscus lines, etc are presented step-by-step and a variety of methods devised to overcome such undesirable features are described in sufficient detail. The optimization of growth parameters have led to the growth of smooth and continuous films. From the detailed morphological, X-ray diffraction, scanning electron microscopic and Raman studies, a correlation between the surface morphology and crystallinity has been established.
(Indian Academy of Sciences, Influence of growth parameters on the surface morphology and crystallinity of InSb epilayers grown by liquid phase epitaxy) Udayashankar, N.K.; Bhat, H.L.
2003
The effect of the inclusion of ceramic particles in polythene material on the response to erosion due to impingement by sand particles at three angles is investigated. It is seen that erosion resistance varies with ceramic inclusions. The work also considers the limitations posed by the system in adopting weight change measurements as a measure to follow erosive wear owing to the softer nature of the matrix material. Consequently, the investigation looks at two other experimental parameters that can readily be measured to quantify erosion. Of the two approaches, the advantages of following wear through measuring linear dimension of the resulting crater is stressed in this work. The study also highlights the problems associated in assessing the depth of the crater as a parameter to express the extent of erosion owing to the phenomenon of material flow suggested and schematically illustrated in the work. Corroborative evidence for this flow behaviour through scanning electron microscopic studies is presented. © 2002 Elsevier Science Ltd. All rights reserved.
(Elsevier Ltd, On evaluating erosion by sand particles in polythene system without and with ceramic particles) Kishore; Sridhar, G.B.
2002
Ductile cast iron was austenitized at four different temperatures and subsequently austempered at six different temperatures. Plane strain fracture toughness was evaluated under all the heat treatment conditions and correlated with the microstructural features such as the austenite content and the carbon content of the austenite. Fracture mechanism was studied by scanning electron microscopy. It was found that the optimum austempering temperature for maximum fracture toughness decreased with increasing austenitizing temperature. This could be interpreted in terms of the microstructural features. A study of the fracture mechanism revealed that good fracture toughness is unlikely to be obtained when austempering temperature is less than half of the austenitizing temperature on the absolute scale. © 2002 Elsevier Science B.V. All rights reserved.
(Elsevier BV, Investigations on the fracture toughness of austempered ductile irons austenitized at different temperatures) Prasad Rao, R.; Putatunda, S.K.
2003
SiC particulate reinforced A356 Al metal matrix composites were laser treated using pulsed Nd-YAG laser beam. The processing was carried out in air atmosphere at varying pulse energy (5 to 20 J) and scan rates (30 to 150 mm/sec). The samples were cut perpendicular to the track and they were characterized using optical microscopy, scanning electron microscopy and X-ray diffraction. Microstructure of laser treated region consists of regular succession of coarse and fine microstructure signifying the presence of low velocity bands. Transition from cellular/columnar dendritic to equiaxed dendritic structure has been observed. Microstructure of samples laser treated with specific energy greater than 13 kJ/cm2 show presence of Al 4C3 platelets. © 2004 Kluwer Academic Publishers.
(Microstructural studies in low specific energy laser surface treated Al(A356)-SiCp composites) Bhat, K.U.; Surappa, M.K.
2004
Neat epoxy (NE) and epoxy system with different volume fractions of fly ash fillers with their surfaces treated by silane bearing material were made and the responses to exposure by immersion in varying aqueous media, such as plain water (PW), seawater (SW) and seawater containing small amount of dilute hydrochloric acid (SWA) maintained at 80°C, established through weight measurements recorded up to 100 h on the test coupons. Further on, the 100 h exposed samples were subjected to compression tests to evaluate the strength. The results showed that both NE and the silane treated ash bearing composites generally exhibited the highest water absorption in SWA case and the lowest in SW media, with the water absorption level for PW case falling in between. When the ash content in the composite is very large, the water absorption levels tend to be lower for both SW and SWA. The data further showed that unexposed samples recorded less strength compared to the exposed ones. In the case of exposed samples, in all the media employed, as the ash content increases the strength also increases. Further, it was noticed that the samples exposed to SW showed higher strength than the corresponding values noticed with SWA case. Lower strength was found in samples immersed in PW case. Attempts to explain these differing trends are made in this effort by analyzing the features observed on the surface of compression failed samples using fractography technique employing scanning electron microscope (SEM).
(Compression strength of aqueous media exposed epoxy system containing silane surface bearing fly ash particles) Kishore; Ravikumar, N.L.; Kulkarni, S.M.
2004

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