Faculty Publications
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Item Durability studies on ferrochrome slag as coarse aggregate in sustainable alkali activated slag/fly ash based concretes(Elsevier B.V., 2020) Yaragal, S.C.; Kumar, B.; Jitin, C.Utilization of industrial byproducts in concrete reduces carbon footprint, associated with production of ordinary Portland cement (OPC), and also indirectly controls rapid depletion of natural resources in the form of natural coarse aggregate (NCA). This study reports the durability effect of alkali activated slag/fly ash concretes (AASFC) with ferrochrome slag (FCS) as coarse aggregate. Different AASFC mixtures were prepared with two control factors i.e., fly ash (FA) content (0, 25, and 50% by weight as a replacement to Ground granulated blast furnace slag (GGBS)), and FCS content (0, 50, and 100% by volume as a replacement to NCA). Total nine mixtures were examined for three different durability tests i.e., volume of permeable voids (VPV), acid resistant test, and sulphate resistant test. Further, embodied energy (EE), and Embodied carbon dioxide emission (ECO2e) were also utilized to optimize the AASFC mixtures by grey relational analysis (GRA). Analysis of variance (ANOVA) is used as a statistical tool to investigate the effect of FA, and FCS content on the overall durability and ecological performance of AASFC mixtures. Results show that, addition of FA increases the durability performance (in % age), and addition of FCS decreases the durability performance (in % age) in AASFC mixtures. AASFC mixture with composition of 50% GGBS, 50% FA, and 100% FCS is considered as most suitable mixture. © 2019 Elsevier B.V.Item Ferrochrome ash – Its usage potential in alkali activated slag mortars(Elsevier Ltd, 2020) Kumar, K.B.; Yaragal, S.C.; Das, B.B.This study is an attempt to develop a sustainable construction material, i.e., alkali activated slag (AAS) in combination with ferrochrome ash (FCA) as a replacement to ordinary Portland cement (OPC). The effect of the various levels of FCA (0, 25, and 50%) replacing ground granulated blast furnace slag (GGBS) in AAS mortars with 4% of Na2O dosage is studied. Further, five levels of the modulus of silica (Ms = 0.75, 1.00, 1.25, 1.5, and 1.75) are chosen to achieve targeted compressive strength at 28 days under ambient temperature curing conditions. The compressive strength decreases with the increase in level of the FCA replacement. The targeted design compressive strength is achieved with 25% FCA replacement to GGBS in the AAS mortar system with Ms = 1.25. In addition, microstructure and mineralogical studies are undertaken to ascertain the formation of different hydration products with the aid of the scanning electron microscope (SEM) and the X-ray diffractometer (XRD). Gismondine and calcium aluminate silicate hydrate (C-A-S-H) are the major hydration products in the AAS mortar mixes. Sodium aluminate silicate hydrate phases (N-A-S-H) are also observed prominently as the FCA replacement level increases in the AAS mortar mixes. The Fourier-transform infrared spectroscopy (FTIR) confirms the presence of the Si–O-(Si or Al) functional group. The addition of FCA in the AAS system is of vital significance in the reduction of the embodied carbon dioxide (ECO2eq), embodied energy (EEeq) and cost. © 2020 Elsevier LtdItem Microstructural and optimization studies on novel one-part geopolymer pastes by Box-Behnken response surface design method(Elsevier Ltd, 2023) Srinivasa, A.S.; Swaminathan, K.; Yaragal, S.C.This paper reports the work on developing an optimized mix proportion of novel one-part geopolymer (OPG) binder produced by dry blending the solid aluminosilicate precursor and solid alkali source and then adding free water to the blended mix similar to the preparation of Ordinary Portland Cement (OPC). A three-level Box-Behnken Response Surface Method (RSM) design was used to study the properties of OPG mixes at fresh and hardened state and to test and develop the regression models. The Ground Granulated Blast Furnace Slag (GGBS) substitution, water to geopolymer solids (w/s) ratio, and the activator dosage were considered as the independent variables. The response target values were the flow value, initial and final setting time, and compressive strength. The multiple regression analysis with the quadratic polynomial model was used to fit the data, which offered an accurate and reliable match to the actual data. Scanning Electron Microscope (SEM), X-ray Diffraction (XRD), and Fourier Transform Infrared Spectroscopy (FTIR) were used to study changes in microstructure, mineral phase, and molecular bonding of OPG mixes, respectively. Based on the material characterization observation, the change in GGBS addition, w/s ratio, and activator dosage were discovered to have a considerable impact on both the fresh and hardened properties. The optimum mix proportion obtained was 51.39% GGBS substitution, 0.32 w/s, and 12.35% activator content, with 191 mm flow, 68.56 MPa of compressive strength, 59 and 191 mins of initial and final setting time, respectively. The target values obtained using the one-part geopolymer mix with 50% GGBS substitution, 0.3 w/s, and 12% activator content were in close agreement with the target values predicted by the optimized mix, confirming the efficiency of RSM in obtaining the optimum one-part geopolymer mix proportion. © 2023 The AuthorsItem Performance and microstructural investigations of processed lateritic fine aggregates in blended cement mortars exposed to elevated temperatures(Emerald Publishing, 2023) Basavana Gowda, S.N.; Yaragal, S.C.; C, C.; Goudar, S.K.Purpose: In recent years, fire accidents in engineering structures have often been reported worldwide, leading to a severe risk to life and property safety. The present study is carried out to evaluate the performance of Ground Granulated Blast Furnace Slag (GGBS) and fly ash–blended laterized mortars at elevated temperatures. Design/methodology/approach: This test program includes the replacement of natural river sand with lateritic fine aggregates (lateritic FA) in terms of 0, 50 and 100%. Also, the ordinary Portland cement (OPC) was replaced with fly ash and GGBS in terms of 10, 20, 30% and 20, 40 and 60%, respectively, for producing blended mortars. Findings: This paper presents results related to the determination of residual compressive strengths of lateritic fine aggregates-based cement mortars with part replacement of cement by fly ash and GGBS exposed to elevated temperatures. The effect of elevated temperatures on the physical and mechanical properties was evaluated with the help of microstructure studies and the quantification of hydration products. Originality/value: A sustainable cement mortar was produced by replacing natural river sand with lateritic fine aggregates. The thermal strength deterioration features were assessed by exposing the control specimens and lateritic fine aggregates-based cement mortars to elevated temperatures. Changes in the mechanical properties were evaluated through a quantitative microstructure study using scanning electron microscopy (SEM) images. The phase change of hydration products after exposure to elevated temperatures was qualitatively analyzed by greyscale thresholding of SEM images using Image J software. © 2023, Emerald Publishing Limited.Item One-part eco-friendly alkali-activated concrete – An innovative sustainable alternative(Elsevier Ltd, 2023) Rakesh Kumar Reddy, R.; Yaragal, S.C.; Srinivasa, A.S.The primary objective of this study is to develop an eco-friendly one-part alkali-activated concrete (OPAAC) by incorporating a combination of fly ash (FA), ground granulated blast furnace slag (GGBS), and micro silica (MS). In this investigation, the proportion of MS is maintained at 20% of FA, while the maximum replacement of FA with GGBS is set to 60%, varying in 20% intervals (i.e., 0%, 20%, 40%, and 60%). Further, the natural aggregates (NA) are substituted with recycled coarse aggregates (RCAs), ferrochrome slag aggregates (FCSAs), or a combination of both. The influence of GGBS and alternative aggregates (RCAs, FCSAs) on the mechanical properties of OPAAC is thoroughly examined. To provide a comprehensive assessment, the properties of OPAAC are compared against Ordinary Portland Cement (OPC) concrete (CC) of equivalent grades. Additionally, microstructural and mineralogical investigations are conducted to determine the formation of distinct hydration products, utilizing scanning electron microscopy (SEM) and X-ray diffractometry (XRD) techniques. In OPAAC containing FA, the primary hydration products identified are alkaline alumino silicate hydrates (CASH and NASH). As the GGBS content increases, calcium silicate hydrate (CSH) becomes the predominant hydration product. Furthermore, in order to assess the sustainability of OPAAC, an analysis of embodied CO2 emissions is performed, and the results are compared with CC and alkali-activated concrete. Notably, OPAAC comprising 40% FA replaced with GGBS, 50% RCAs, and 50% FCSAs demonstrates the most favourable mechanical properties and exhibits lower CO2 emissions. © 2023 Elsevier Ltd
