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Author: search.filters.author.Vijayan, V.Subject: search.filters.subject.Modification

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    The effect of strontium modification on casting/chill interfacial heat flux and casting surface profile during solidification of Al-7Si alloy
    (Institution of Engineering and Technology jbristow@theiet.org, 2013) Vijayan, V.; Prabhu, K.N.
    The effect of Sr modification of Al-7%Si alloy on casting/chill interfacial heat flux transients was investigated. The alloy was solidified against polished surfaces of copper, brass and cast iron chills. The heat flux across the casting/chill interface was estimated using inverse modeling technique. On modification melt treatment, the peak heat flux increased by about 70%, 24% and 22% for copper, brass and cast iron chills respectively. The effect of Sr modification on casting surface texture was analyzed using a surface profilometer. The surface profile of the casting and the chill surfaces clearly indicated the formation of anair gap at the periphery of the casting. The arithmetic average value of the profile departure from the mean line, within a sampling length(Ra) and arithmetical mean of the absolute departures of the waviness profile from the centre line within a sampling length(W a) were reduced by 50% on modification. The enhancement in heat transfer achieved due to modification was attributed to the decrease in gap width formed at the interface. The width of the gap formed for the unmodified and modified casting surfaces at the periphery were found to be about 35μm and 19μm respectively. The gap width was used to determine the variation of heat transfer coefficient (HTC) acrossthe chill surface after the formation of stable solid shell.It was found that the HTC decreased along the radial direction.
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    Effect of Ni and Sr additions on the microstructure, mechanical properties, and coefficient of thermal expansion of Al-23%Si alloy
    (Elsevier Ltd, 2021) Vijayan, V.; Ravi, M.; Prabhu, K.N.
    In this paper, the combined and individual effect of strontium (Sr) and nickel (Ni) additions on the microstructure and mechanical properties of hypereutectic Al-23Si alloy was studied using an optical microscopy, universal tensile testing machine and Brinell hardness tester. The wear properties and coefficient of thermal expansion of the melt treated samples were determined using pin on disc wear testing machine and linear expansion measurement unit respectively. The results indicate that the Ni additions significantly enhanced the mechanical properties of the alloy, whereas, presence of Sr was detrimental. It was observed that the improvement in mechanical properties due to Ni was primarily due to refinement and transformation of the star shaped primary silicon into polyhedral crystals. However, the addition of Sr, both as separate and when combined with Ni, transformed the primary silicon into a faceted crystal and hence decreased the mechanical property. Among all, the Ni melt treated alloy samples showed lowest wear rate and coefficient of thermal expansion. © 2021 Elsevier Ltd. All rights reserved.
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    Effect of chilling and cerium addition on microstructure and cooling curve parameters of Al-14%Si alloy
    (Maney Publishing maney@maney.co.uk, 2015) Vijayan, V.; Prabhu, K.
    Al-14%Si alloys, with and without cerium, were cast at varying cooling rates by solidifying them in a crucible and against chills. The effect of melt treatment and chilling on microstructure and cooling curve parameters of the alloy was assessed. Ce treated alloys solidified in clay graphite crucible at a slow cooling rate showed refinement of primary silicon and the formation of Al-Si-Ce ternary intermetallic compound. The addition of Ce to the alloy solidified against chills resulted in simultaneous refinement and modification of primary and eutectic silicon. Nucleation temperatures of both primary and eutectic silicon decreased on addition of cerium. The formation of the intermetallic compound decreased with increase in cooling rate, leading to the modification of the eutectic silicon. The increase in the degree of modification of the eutectic Si was associated with the decrease in the volume fraction of the intermetallic compound formed. © 2015 Canadian Institute of Mining, Metallurgy and Petroleum Published by Maney on behalf of the Institute.
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    The Effect of Addition of Ce and Sr on the Solidification Path of Al–8Si–2Cu Alloy
    (Springer India sanjiv.goswami@springer.co.in, 2015) Vijayan, V.; Prabhu, K.
    Thermal analysis of Al–Si alloys is very useful for the non-destructive evaluation of the melt quality. The present work aimed at the study of the effect of addition of Ce and Sr on cooling curve parameters, microstructure and mechanical properties of Al–8Si–2Cu alloy. The thermal analysis parameters of melt treated alloys were determined. The addition of Ce influenced both primary and eutectic phase nucleation temperatures, whereas, Sr affected only the eutectic nucleation temperature. The depression in the eutectic arrest temperature was higher with Sr addition when compared to Ce. Consequently, a high degree of modification was achieved with Sr. The addition of Ce yielded fine equiaxed ?-aluminium grains and Sr treatment resulted in columnar grains. The mechanical properties of the alloy significantly improved on simultaneous addition of Ce and Sr. The individual addition of Sr, Ce and combined addition of Ce + Sr to base alloy increased the tensile strength by about 40, 52 and 83 % respectively. © 2015, The Indian Institute of Metals - IIM.
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    The effect of simultaneous refinement and modification by cerium on microstructure and mechanical properties of Al-8% Si alloy
    (Taylor and Francis Ltd. maney@maney.co.uk, 2016) Vijayan, V.; Prabhu, K.N.
    The effect of cerium melt treatment on microstructure and mechanical properties of gravity die cast Al-8% Si alloy was studied. The addition of Ce transformed the large columnar ?-Al grains into fine equiaxed grains and modified the acicular eutectic Si into fine fibrous form. The addition of Ce resulted in the formation of needle-shaped complex Ce intermetallic along the grain boundaries. Electrical conductivity measurements are used for the first time to reveal the effect of Ce addition on modification of the eutectic Si. The electrical conductivity of the alloy increased with Ce melt treatment. Scanning Electron Microscopy results suggests that the Ce particles did not heterogeneously nucleate the ?-Al grains, instead the fine equiaxed grains were formed through an invariant reaction between the liquid melt and Ce phase. The ultimate tensile strength, % elongation and hardness of the alloy significantly improved due to simultaneous modification and refinement. © 2016 Informa UK Limited, trading as Taylor & Francis Group.