Faculty Publications

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Shear strength characteristics and chemical characteristics of leachate-contaminated lateritic soil
(2009) Sunil, B.M.; Shrihari, S.; Nayak, S.
Leachate is a hazardous liquid and is a major cause of concern in landfills. Numerous environmental problems such as soil and groundwater contamination occur in unlined landfills due to free flow of leachate. Large quantities of leachate-contaminated soils result from open dumping in the study area. These dump yards receive large quantities of municipal solid waste which includes chemical and industrial wastes. Large areas of land are currently being used for this purpose. An extensive laboratory testing program was carried out to determine the properties of clean and contaminated lateritic soils. Laboratory prepared municipal solid waste leachate was used in this study. Contaminated specimens were prepared by mixing the soils with MSW leachate in the increments of 0%, 5%, 10% and 20% by weight to vary the degree of contamination. The results showed that the MSW leachate affects the Atterberg limits, shear strength and chemical characteristics of the lateritic soils. The liquid limit and the plasticity index of the lateritic soils increases with MSW leachate concentration. For specimens tested at the Proctor density, effective cohesion increases and effective friction angle decreases due to increase in leachate concentration. This is attributed due to the increase in clay content of lateritic soil after interaction with the leachate. This led to increase in cohesion parameter and the friction angle decreases. The pH measurements of lateritic soil contaminated with MSW leachate indicated an increase in pH values. This is also accompanied by slight increase in the cation exchange capacity of the soil. The change in chemical characteristics of lateritic soil contributed due to addition of leachate may be detrimental to foundation concrete in real field conditions. The present work deals with an attempt to study the effect of leachate on the Atterberg limits, shear strength properties and chemical characteristics of lateritic soil. © 2009 Elsevier B.V. All rights reserved.
Effect of ammonia on the hydraulic conductivity and adsorption characteristics of lithomargic clay - Bentonite barrier in landfills
(Elsevier Ltd, 2022) Aswathy, C.M.; Sunil, B.M.
Alteration of characteristic properties of the liner material occurs mainly due to interaction with contaminants present in the landfill leachate. The present study deals with the effect of inorganic contaminants on the behaviour of bentonite-based landfill liner material. Saturated hydraulic conductivity, unconfined compressive strength and compaction characteristics of the lithomargic clay and its blends permeated with an inorganic contaminant (ammonia) were evaluated. Experiments were conducted by blending lithomargic clay with 5%, 7.5% and 10% bentonite. The results showed that hydraulic conductivity decreased from an initial value of 3 × 10-8 m/s to 6.83 × 10-11 m/s. Unconfined compressive strength at wet of optimum and maximum dry density of blended lithomargic clay also reduced slightly. Adsorption studies were conducted, and the coefficient of distribution (Kd) for blended lithomargic clay with 5% and 10% was found to be 60.46 L/kg and 94.74 L/kg, respectively. The Kd values indicate good adsorption characteristics of bentonite-based material. Overall, the results showed that lithomargic clay blended with bentonite is a suitable alternative barrier for constructing engineered landfills to prevent environmental degradation and other health effects. © 2022 Elsevier Ltd.
Improving landfill liner performance with bentonite-slag blend permeated with ammonia for a Municipal solid waste landfill
(Academic Press, 2024) Aswathy, A.; Sunil, B.M.
Leachate emanating from landfills contains ammonia which may cause serious health effects on living things. An effectively designed clay barrier should not allow the contaminant to infiltrate the soil and groundwater systems. The utilization of certain industrial by-products in engineered landfill barriers, not only reduces the need for conventional liner materials but also helps in sustainable waste management. This study investigated the hydraulic conductivity, unconfined compressive strength, compaction, and adsorption characteristics of lithomargic clay blended with an optimum percentage of bentonite (10%) and granulated blast furnace slag (15%) permeated with ammonia. The results revealed that increasing the content of granulated blast furnace slag decreased the maximum dry density while increasing the optimum moisture content. In comparison to lithomargic clay, the hydraulic conductivity of the amended soil liner permeated with ammonia decreased from a value of 3 × 10−8 m/s to 5 × 10−10 m/s. The unconfined compressive strength of the amended soil specimens showed an increasing trend with curing times (i.e., 0, 14, 28, and 56 days). The batch adsorption results revealed that Freundlich and Langmuir's isotherm fits the equilibrium adsorption data and the adsorption of ammonia on clay liner follows non-linear behaviour. Overall, the experimental results implied that lithomargic clay blended with 10% bentonite and 15% granulated blast furnace slag can be used as an impermeable soil reactive barrier in engineered landfills. © 2024 Elsevier Ltd

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