Faculty Publications

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Author: search.filters.author.Srinikethan, G.Subject: search.filters.subject.concentration (composition)

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    Natural and anthropogenic factors controlling the dissolved organic carbon concentrations and fluxes in a large tropical river, India
    (2006) Balakrishna, K.; Kumar, I.A.; Srinikethan, G.; Mugeraya, G.
    Carbon studies in tropical rivers have gained significance since it was realized that a significant chunk of anthropogenic CO2 emitted into the atmosphere returns to the biosphere, that is eventually transported by the river and locked up in coastal sediments for a few thousand years. Carbon studies are also significant because dissolved organic carbon (DOC) is known to complex the toxic trace metals in the river and carry them in the dissolved form. For the first time, this work has made an attempt to study the variations in DOC concentrations in space and time for a period of 19 months, and estimate their fluxes in the largest peninsular Indian river, the Godavari at Rajahmundry. Anthropogenic influence on DOC concentrations possibly from the number of bathing ghats along the banks and domestic sewage discharge into the river are evident during the pre-monsoon of 2004 and 2005. The rise in DOC concentrations at the onset of monsoon could be due to the contributions from flood plains and soils from the river catchment. Spatial variations highlighted that the DOC concentrations in the river are affected more by the anthropogenic discharges in the downstream than in the upstream. The discharge weighted DOC concentrations in the Godavari river is 3-12 times lower than Ganga-Brahmaputra, Indus and major Chinese rivers. The total carbon fluxes from the Godavari into the Bay of Bengal is insignificant (0.5%) compared to the total carbon discharges by major rivers of the world into oceans. © Springer Science+Business Media, Inc. 2006.
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    Performance of pulsed plate bioreactor for biodegradation of phenol
    (2007) Shetty K, K.V.; Kalifathulla, I.; Srinikethan, G.
    Biodegradation of phenol was carried out using Nocardia hydrocarbonoxydans immobilised on glass beads, in a pulsed plate bioreactor. The effect of operating parameters like frequency of pulsation and amplitude of pulsation on the performance of pulsed plate bioreactor for biodegradation of phenol in a synthetic wastewater containing 500 ppm phenol was studied. Axial concentration profile measurements revealed that the pulsed plate bioreactor shows continuous stirred tank behaviour. As the amplitude was increased, percentage degradation increased, reaching 100% at amplitude of 4.7 cm and higher. Introduction of pulsation is found to increase the percentage degradation. Percentage degradation has increased with increase in frequency and 100% degradation was achieved at 0.5 s-1 and above. Biofilms developed in a non-pulsed bioreactor were thicker than those in the pulsed plate bioreactor. But biofilm thickness remained almost constant with increasing frequency. Biofilm density was found to be influenced by pulsation. The time required to reach steady state was more for pulsed reactor than the non-pulsed reactor and this start-up time had increased with increase in frequency of pulsation. The performance studies reveal that the pulsed plate bioreactor with immobilized cells has the potential to be an efficient bioreactor for wastewater treatment. © 2006 Elsevier B.V. All rights reserved.
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    Removal of remazol brilliant blue dye from dye-contaminated water by adsorption using red mud: Equilibrium, kinetic, and thermodynamic studies
    (2012) Ratnamala, G.M.; Shetty K, K.V.; Srinikethan, G.
    Utilization of industrial solid wastes for the treatment of wastewater from another industry could help environmental pollution abatement, in solving both solid waste disposal as well as liquid waste problems. Red mud (RM) is a waste product in the production of alumina and it poses serious pollution hazard. The present paper focuses on the possibility of utilization of RM as an adsorbent for removal of Remazol Brilliant Blue dye (RBB), a reactive dye from dye-contaminated water. Adsorption of RBB, from dye-contaminated water was studied by adsorption on powdered sulfuric acid-treated RM. The effect of initial dye concentration, contact time, initial pH, and adsorbent dosage were studied. Langmuir isotherm model has been found to represent the equilibrium data for RBB-RM adsorption system better than Freundlich model. The adsorption capacity of RM was found to be 27.8 mg dye/g of adsorbent at 40 °C. Thermodynamic analysis showed that adsorption of RBB on acid-treated RM is an endothermic reaction with ?H0 of 28.38 kJ/mol. The adsorption kinetics is represented by second-order kinetic model and the kinetic constant was estimated to be 0.0105 ± 0.005 g/mgmin. Validity of intra-particle diffusion kinetic model suggested that among the mass transfer processes during the dye adsorption process, pore diffusion is the controlling step and not the film diffusion. The process can serve dual purposes of utilization of an industrial solid waste and the treatment of liquid waste. © Springer Science+Business Media Dordrecht 2012.
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    Source apportionment of lead and cadmium by chemical characterization of PM2.5
    (Enviro Media rktem@pn3.vsnl.net.in, 2016) Srinikethan, G.; Ayare, A.
    Particulate matter below 2.5 micron (PM2.5) and its existence in atmosphere is observed in most of major cities in India and abroad. Health impacts of such pollutant on human being leading asthma and chronic bronchitis in India in last decade. Pune city in Maharashtra state of India is rapidly emerging as mega city in India due to its urbanization and modernization. Particulate matter and trace elements in it are causing severe effects on people of Pune. In present study, trace elements like lead (Pb) and cadmium (Cd) in PM2.5 at Pune city in Maharashtra, India were measured with the help of PM2.5 sampler and chemical characterization of Pb and Cd was done to determine the concentrations in the ambient air. The source apportionment of Pb and Cd was done by applying US EPA positive matrix factorization model to identify the sources and quantitative distribution of these elements at receptor location of Katraj in Pune city. The main objective was to identify and determine health impacts of Pb and Cd as well as PM2.5. The results of the study shall help urban planners, air quality planners and people of medicine to initiate urban air pollution management in Pune city.
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    Simultaneous adsorption of Remazol brilliant blue and Disperse orange dyes on red mud and isotherms for the mixed dye system
    (Springer Verlag service@springer.de, 2017) Ratnamala, R.; Shetty K, K.V.; Srinikethan, G.
    The paper presents the adsorption of Remazol brilliant blue (RBB) and Disperse orange 25 (DO25) dyes from aqueous solution of the mixture of dyes onto concentrated sulphuric acid-treated red mud (ATRM). First-order derivative spectrophotometric method was developed for the analysis of RBB and DO25 in mixed dye aqueous solution to overcome the limitations arising due to interference in the zero-order spectral method. The optimum conditions to maximize RBB adsorption favoured the adsorption of RBB, and those for DO25 favoured DO25 adsorption from the mixed dye aqueous solutions. Presence of a second dye always inhibited the adsorption of a target dye. The uptake and percentage adsorption of each of the dyes onto ATRM from the aqueous solution of the mixture of dyes decreased considerably with increasing concentrations of the other dye showing the antagonistic effect. Monocomponent Langmuir isotherm fitted the mixed dye adsorption equilibrium data better than the monocomponent Freundlich isotherm. However, monocomponent models are suitable for the fixed concentration of the other dye. Modified Langmuir isotherm model adequately predicted the multi-component adsorption equilibrium data for RBB-DO25-ATRM adsorption system with a good accuracy and is more generic from the application point of view. © 2017, Springer-Verlag Berlin Heidelberg.
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    Kinetic and equilibrium modeling of biosorption of nickel (II) and cadmium (II) on brewery sludge
    (IWA Publishing 12 Caxton Street London SW1H 0QS, 2019) Kulkarni, R.M.; Shetty K, K.; Srinikethan, G.
    In the current study, utilization of industrial waste brewery sludge for the biosorption of nickel (II) and cadmium (II) has been explored. The suitable conditions for the effective removal of Ni (II) and Cd (II) from aqueous solutions were examined. The kinetic evaluation showed that the biosorption process using the sludge followed pseudo-second order kinetics. In the presence of a metal co-ion, competitive and preferential biosorption was observed. The Langmuir model and Freundlich model were able to describe the sorption equilibrium for biosorption of Ni (II) and Cd (II) ions in single and dual metal systems. The effects of co-ion concentrations onto mono-component isotherm parameters (Langmuir and Freundlich) were studied and the inhibitory effect of co-ion concentration was observed. The effective reusability of biomass was assessed by three cycles of sorption-desorption. The sludge, owing to its high biosorption intensity and large availability from the local supply, is a better biosorbent for the treatment of Ni (II) and Cd (II) contaminated water. © IWA Publishing 2019 Water Science & Technology.