Faculty Publications
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Item Cadmium (II) and nickel (II) biosorption by Bacillus laterosporus (MTCC 1628)(Taiwan Institute of Chemical Engineers, 2014) Kulkarni, R.; Shetty K, V.; Srinikethan, G.Biosorption of heavy metals is a promising technology that involves removal of toxic metals from industrial waste streams and natural waters. The study describes the sorption of cadmium (II) [Cd (II)] and nickel (II) [Ni (II)] by dead biomass of Bacillus laterosporus, MTCC 1628. The biosorption conditions for the removal of Cd (II) and Ni (II) were examined by studying the effect of pH, contact time, biosorbent dosage and initial metal ion concentration. Shake flask studies yielded adsorption equilibrium in almost 120. min, for both the metals. It was found from Langmuir model that the maximum adsorption capacity for Cd (II) and Ni (II) ions was 85.47. mg/g and 44.44. mg/g respectively. Kinetic evaluation of the experimental data showed that the biosorption process followed pseudo-second order kinetics. Thermodynamic analysis showed that biosorption is an endothermic process with ?. H° of 5.45. kJ/mol for Cd (II) biosorption and 24.33. kJ/mol for Ni (II) biosorption. The surface characteristics of B. laterosporus biomass before and after metal biosorption were analyzed by using scanning electron microscope (SEM) with energy dispersive X-ray spectroscopy (EDAX) to study the changes in surface morphology and elemental constitution of the adsorbent. B. laterosporus exhibited a higher and better potential biosorbent for the removal of Cd (II) as compared to Ni (II) from aqueous solution. © 2013 Taiwan Institute of Chemical Engineers.Item Kinetic and equilibrium modeling of biosorption of nickel (II) and cadmium (II) on brewery sludge(IWA Publishing 12 Caxton Street London SW1H 0QS, 2019) Kulkarni, R.M.; Shetty K, K.; Srinikethan, G.In the current study, utilization of industrial waste brewery sludge for the biosorption of nickel (II) and cadmium (II) has been explored. The suitable conditions for the effective removal of Ni (II) and Cd (II) from aqueous solutions were examined. The kinetic evaluation showed that the biosorption process using the sludge followed pseudo-second order kinetics. In the presence of a metal co-ion, competitive and preferential biosorption was observed. The Langmuir model and Freundlich model were able to describe the sorption equilibrium for biosorption of Ni (II) and Cd (II) ions in single and dual metal systems. The effects of co-ion concentrations onto mono-component isotherm parameters (Langmuir and Freundlich) were studied and the inhibitory effect of co-ion concentration was observed. The effective reusability of biomass was assessed by three cycles of sorption-desorption. The sludge, owing to its high biosorption intensity and large availability from the local supply, is a better biosorbent for the treatment of Ni (II) and Cd (II) contaminated water. © IWA Publishing 2019 Water Science & Technology.Item Pelletization of pristine Pteris vittata L. pinnae powder and its application as a biosorbent of Cd(II) and Cr(VI)(Springer Nature, 2020) Prabhu, S.G.; Srinikethan, G.; Hegde, S.Mobility of toxic metals, originating from natural or anthropogenic sources, from soil to groundwater is a matter of utmost concern to human health. Remediation of the contaminated groundwater is of the highest priority as groundwater is an alternate source of freshwater that is used all over the world for drinking purpose. Hence, in the present study, Pteris vittata L. is used as a simple, biodegradable and efficient biosorbent of toxic metals in its non-living and pelletized form by employing organic binders and a simple manual pellet press. The capacity of the pelletized Pteris vittata L. to sequester the metals Cd(II) and Cr(VI) from an aqueous solution is determined through the study on the effect of operating conditions, isotherm and kinetic models. The metal removal capacity of the biosorbent pelletized using corn starch as the binder is 13.51 mg/g for Cd(II) at pH 6 and 1.66 mg/g for Cr(VI) at pH 2 as obtained from the Langmuir isotherm model. The diffusion of the metal ions into the micropores of the pellets aids its biosorption. Physical adsorption, ion exchange, covalent bonding and complexation are deduced to be few of the biosorption mechanisms involved. The findings contribute to the existing data in the biosorption technology. The novelty lies in the use of a weedy fern, Pteris vittata L., pelletized with desired structural characteristics as a potential low-cost biosorbent of toxic metals from groundwater. © 2019, Springer Nature Switzerland AG.Item Biosorption study on Ni(II) and Cd(II) removal in a packed bed column using brewery sludge pellets(Springer Science and Business Media Deutschland GmbH, 2024) Kulkarni, R.M.; Shetty K, V.; Srinikethan, G.The study covers the results of investigations on performance of packed bed column as a continuous contactor for nickel [Ni(II)] and cadmium [Cd(II)] biosorption on pellets of brewery sludge. Experiments were conducted to assess influence of design variables such as bed height (2.5 to 10 cm) and flow rate (2.5 to 10 mL/min). By fitting the column data into the model equations, the parameters of the Thomas and bed depth service time (BDST) models, which are utilized in the design of packed column adsorbers, were determined. For Ni(II) biosorption, the computed values of N0 and KA obtained using the BDST model were 1833 mg/L and 0.022 L/mg.h, respectively, whereas for Cd(II) biosorption, the values were 5424 mg/L and 0.005 L/mg.h, respectively. Predicted Ni(II) and Cd(II) uptake using the Thomas model were 7.33 mg/g and 14.79 mg/g at 2.5 mL/min flow rate. Optimal biosorption conditions for Ni(II) and Cd(II) were observed at 2.5 mL/min flow rate and 10 cm bed height. Critical design factors such as length of the unused bed (LUB), stoichiometric time (t*), and mass transfer zone (Δt) needed for scaling up the biosorption process were also determined. The present study has demonstrated that the biosorption of Ni(II) and Cd(II) onto pellets of brewery sludge in packed bed column is intraparticle mass transfer controlled process. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022.