Faculty Publications
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Item Influence of Incorporating Phase Change Materials on Cementitious System—A Review(Springer Science and Business Media Deutschland GmbH, 2021) Snehal, K.; Das, B.B.Phase change materials (PCMs) are gaining more attention in achieving the sustainability and are being widely adopted as a green building material because of their exclusive ability to store latent heat of thermal energy. PCMs have a capacity to minimize the energy loads and to provide thermal comforts in building infrastructures by its iterative cycle of absorbing and releasing the heat energy. The potential need for manipulating the heating and cooling effect in buildings is significantly increasing especially in temperature fluctuating and varied climatic regions. It is for this one of the significant reasons, PCMs are getting pronounced interest by the research fraternity in the development of a thermally effective PCM-based construction material. In this paper, attempts were made to compile the data reported by the previous researchers on the influence of incorporating PCMs in the engineering properties of cementitious system such as slump, compressive strength, flexural strength, density, porosity, water absorption, shrinkage, durability, heat of hydration, specific heat capacity and thermal conductivity. This paper also discusses the most favorable content of PCM addition and effective methods of incorporating PCMs in the cementitious system. © 2021, Springer Nature Singapore Pte Ltd.Item Impact of Phase Change Materials on the Durability Properties of Cementitious Composites—A Review(Springer Science and Business Media Deutschland GmbH, 2023) Vismaya, K.; Snehal, K.; Das, B.B.Phase change materials (PCMs) are the novel thermal storage materials which have an ability to engross and dispel heat during the process of phase transition from solid to liquid and vice versa. Utilization of PCMs in cementitious composites has gained a lot of attention from the research fraternity to minimize the energy loadings used for space conditioning and heating in building. Impact of PCM’s presence in cementitious composites on the durability parameters is the need for its better usage. This paper gives the state of review on the influence of inclusion of phase change materials in the cementitious system on its various durability aspects. Durability properties such as porosity, water absorption, shrinkage, chloride ingression, and chemical attacks are compiled in this article. It is stated that the integration of PCM in cement composites enhances the porosity of cementitious system. Major hindrance described by the researchers is the interruption of hydration activity of cementitious system by the addition of PCM. Literature also signified that the micro/nano encapsulates PCMs and the use of highly reactive Pozzolans such as silica fume or nano-silica in conjunction with PCMs has the ability to lock up the limitations of PCMs. © 2023, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.Item Valorization of Incinerated Biomedical Waste Ash in Cementitious System: A Comprehensive Review(Springer Science and Business Media Deutschland GmbH, 2025) Joshi, S.; Snehal, K.; Das, B.B.; Barbhuiya, S.Disposing of incinerated biomedical waste ash (IBWA) contaminated with heavy metals (e.g., Cr, Zn, Pb) poses significant environmental and public health concerns, necessitating innovative and sustainable management strategies. Cement-based solidification emerges as a promising approach to repurpose IBWA by effectively immobilizing heavy metals and mitigating their ecological footprint. However, broader industrial and societal acceptance of IBWA as a substitute for cement and sand remains constrained owing to limited quantification of IBWA availability and safety concerns. In this perspective, the current paper presents a global database on IBWA availability and maps the geographic distribution of biomedical waste incinerators in India. It also comprehensively reviews IBWA’s potential in mortar/concrete, focusing on its physico-chemical, leachability, hydration, mechanical, durability, and microstructural properties. The study further highlights the importance of a cradle-to-gate and gate-to-gate Life Cycle Assessment (LCA) to holistically assess the environmental performance of IBWA-incorporated mortar systems, promoting circular economy principles and resource efficiency in the construction sector. IBWA, with its high SiO₂ and CaO content (> 50%), exhibits latent hydraulic properties suitable for construction applications. The porous cellular structure of IBWA can lead to increased porosity and water absorption in concrete. Leachate analysis demonstrated the effective stabilization of heavy elements within the cement hydration matrix (C-S-H, C-A-S-H, etc.), meeting US EPA regulatory standards. LCA interprets that IBWA utilization of up to 10% cement replacement material and 30% sand replacement material could curtail the carbon footprint and energy demand by ~ 25–35% and 15–25%, respectively, compared to conventional cement-based mortar systems. These findings highlight IBWA’s potential to transform the construction sector, aligning it with global sustainability goals and reducing its dependence on non-renewable resources. © The Author(s), under exclusive licence to Shiraz University 2025.Item Influence of Integration of Phase Change Materials on Hydration and Microstructure Properties of Nanosilica Admixed Cementitious Mortar(American Society of Civil Engineers (ASCE) onlinejls@asce.org 1801 Alexander Bell DriveGEO Reston VA 20191 Alabama, 2020) Snehal, K.; Das, B.B.; Kumar, S.The present study demonstrates the influence of integrating phase change materials (PCMs) on hydration and microstructure properties of nanosilica admixed cementitious mortar. First, the optimized dosage of nanosilica in correspondence to compressive strength was determined. Subsequently, the desired proportion of PCMs was identified pertaining to a designated compressive strength of 35 MPa at the curing age of 28 days. The hydration and microstructure studies were carried out through thermo gravimetric analysis (TGA), X-ray diffraction (XRD), and scanning electron microscopy (SEM), respectively. Further, thermal properties were determined by means of differential scanning calorimetry (DSC). Incorporation of nanosilica into the cementitious mortar was found to have a positive influence on early strength development and durability, however, there was found to be an increase in chemical shrinkage as compared to the control mixture. PCMs integrated cementitious mortar improved the thermal efficiency as well as reduced the chemical shrinkage, but adversely affected the mechanical, hydration, and durability properties. With respect to development of compressive strength of the cementitious mortar, it is found that n-octadecane PCMs performed better amidst other PCMs, such as paraffin and sodium carbonate hydrates. Further, studies were carried out on cementitious mortar having both nanosilica (optimized proportion) and PCMs (the best performing). From the results, it is found that cementitious mortar comprising of both nanosilica and PCMs have compensated the drawbacks of one another. Blended mortar (having both nanosilica and PCMs) showed superior strength gain at early age, better durability resistance, low chemical shrinkage, and superior thermal performance. © 2020 American Society of Civil Engineers.Item Effect of phase-change materials on the hydration and mineralogy of cement mortar(ICE Publishing, 2020) Snehal, K.; Das, B.B.The influence of direct incorporation of thermally efficient phase-change materials (PCMs) on the hydration and mineralogical properties of cement mortar was investigated. To assess the viability of bulk addition of PCMs to a cementitious system, tests of the early age, hydration, mechanical, durability and mineralogical properties were carried out. Organic PCMs showed an increase in setting time, while inorganic materials exhibited fast setting characteristics. Surface temperature was also found to be lower for cement paste with incremental dosages of PCM. However, chemical shrinkage was found to be reduced in the presence of PCM except for the inorganic type. It was observed from the results that PCMs negatively influenced the rate of strength development of a cementitious mortar. The slow rate of strength development was found to be attributed to interrupted hydration, which was confirmed through mineralogical studies. Further, from the thermo-gravimetric analysis, it was observed that the presence of PCMs in a cementitious system increased calcium hydroxide content and reduced the content of water related to hydration products. © 2020 ICE Publishing: All rights reserved.Item Acid, alkali and chloride resistance of binary, ternary and quaternary blended cementitious mortar integrated with nano-silica particles(Elsevier Ltd, 2021) Snehal, K.; Das, B.B.This paper investigates the quantification of ettringite (Ca6Al2(SO4)3(OH)12.26H2O, AFt), gypsum (CaSO4.2H2O, Gy) and Friedel's salt (Ca4Al2(OH)12Cl2.4H2O, Fs) formed for binary, ternary and quaternary blended cementitious mortar mixes that were exposed to acid (H2SO4), alkali (Na2SO4) and chloride (NaCl) solutions. Quantification was carried out through a thermogravimetric analyzer by characterizing the mass loss associated to the decomposition of these compounds at specific boundaries of temperature (50–120 °C for AFt, 120–150 °C for Gy and 230–380 °C for Fs). Binary, ternary and quaternary blended cementitious mortar mixes were designed by adopting modified Andreasen and Andersen particle packing model. A long-term exposure period was spanned to the duration of 180 days for all kind of aggressive media and its effect on engineering properties of blended cementitious mortar were measured. Deterioration due to acid (H2SO4) exposure is found to be more intense due to the synergistic action of acid and sulfates. It is to be noted that for acid exposure period of 180 days, control mortar underwent an acute density and strength losses of 18% and 59%, respectively. However, cementitious mortar mix consisting of 3% nano-silica performs the best against aggressive media. The optimistic resistance to the formation of AFt and Gy was also found to be offered by quaternary blended mix. A similar trend was also observed in the formation of Fs for the mortar mixes exposed to NaCl solution. Significant improvement in particle packing density by the inclusion of micron to nano sized finer particles for quaternary blended mortar mix has minimized the permeable porosity, thus reduced the susceptibility to the formation of voluminous compounds. Enhanced pozzolanic activity due to the presence of nano-silica could be one of the primary reasons for quaternary blended mortar to perform better against the aggressive media that can be adopted in the practice considering sustainability and economical point of view. © 2021 Elsevier LtdItem Pozzolanic Reactivity, Hydration and Microstructure Characteristics of Blended Cementitious Composites Comprising of Ultrafine Particles(Springer Science and Business Media Deutschland GmbH, 2022) Snehal, K.; Das, B.B.; Sudhi, A.; Pandey, D.Performance of ultrafine fly ash (UFFA, 5–10 µm) and fly ash (FA, 45–50 µm) particles in cementitious composites was investigated individually as well as in combination. To study the physicochemical behaviour of blended cementitious composites, engineering properties and pozzolanic reactivity test were conducted. Further, characterization techniques such as thermogravimetric analysis (TGA), X-ray diffraction (XRD) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM–EDX) were employed. The results showed good amplification in the development of early compressive strength and durability on admixing ultrafine particles of fly ash (UFFA) in cementitious system. Particle size and specific surface area of UFFA greatly influenced on the phase assemblages of cementitious composites, i.e. due to enriched pozzolanic reactivity which reduced Ca/Si atomic ratio (≤ 1.82) in the pore solution of cementitious matrix. On contrary, the presence of UFFA particles in cementitious composite mix developed disjoining pressure in addition to self-desiccation thereby induced early age cracks and also reduced the workability in correspondence to that of FA particles. Further, use of UFFA in conjunction with FA particles, cementitious composites showed much superior performance in terms of both physical and chemical characteristics, which necessitates the crucial need of admixing micron and submicron size particles in the design of sustainable and high-performance cementitious composites at this point of time. © 2022, The Author(s), under exclusive licence to Shiraz University.