Faculty Publications
Permanent URI for this communityhttps://idr.nitk.ac.in/handle/123456789/18736
Publications by NITK Faculty
Browse
2 results
Search Results
Item Drilling parameter optimization of cenosphere/HDPE syntactic foam using CO2 laser(Elsevier Ltd, 2022) Singh, S.; Yaragatti, N.; Doddamani, M.; Powar, S.; Zafar, S.High-density polyethylene is a high-strength, and low-weight material system. Besides numerous applications in a variety of fields and products, its machining for generation of holes is rather difficult with traditional methods such as drilling as the process is not very conducive for composites due to associated damage. Hence, a non-contact material removal process such as laser machining provides an appealing, cost-effective, accurate, and fast alternative. For this study, the effect of the laser process controls key parameters such as laser power and laser speed on the cut surface integrity defined by surface roughness, kerf taper angle, and heat-affected zone of neat HDPE and HDPE with 60 wt% cenosphere was investigated and optimized using response surface methodology. Also, the machining operation was visualized using a Photron FASTCAM SA 1.1 high-speed camera to observe the effects of the high-intensity laser beam on specimens and to investigate the mechanism of laser machining. The optimum values for a defect-free cut surface (minimum surface roughness and low kerf taper angle) in neat HDPE comes out to be as laser power of 97.5 W and laser speed of 5 mm/s, with corresponding surface roughness and kerf taper angle of 54.304 μm and 0.152 degrees respectively and the optimum input values for HDPE with 60 wt% cenosphere are 102.126 W laser power and 5 mm/s laser speed, with corresponding surface roughness and kerf taper angle of 26.574 μm and 0.253 degrees. This study finds importance for the industrial and medical application to creates small size holes for mechanical joints such as rivets, bolts, and screws in assembly as low surface roughness and kerf width are always preferred as quality parameters in creating holes for industrial applications. © 2022Item Mango Leaves (Mangifera indica)-Derived Highly Florescent Green Graphene Quantum Dot Nanoprobes for Enhanced On-Off Dual Detection of Cholesterol and Fe2+ Ions Based on Molecular Logic Operation(American Chemical Society, 2024) Ratnesh, R.K.; Singh, M.K.; Kumar, V.; Singh, S.; Chandra, R.; Singh, M.; Singh, J.In the present study, we have engineered a molecular logic gate system employing both Fe2+ ions and cholesterol as bioanalytes for innovative detection strategies. We utilized a green-synthesis method employing the mango leaves extract to create fluorescent graphene quantum dots termed “mGQDs”. Through techniques like HR-TEM, i.e., high-resolution transmission electron microscopy, Raman spectroscopy, and XPS, i.e., X-ray photoelectron spectroscopy, the successful formation of mGQDs was confirmed. The photoluminescence (PL) characteristics of mGQDs were investigated for potential applications in metal ion detection, specifically Fe2+ traces in water, by using fluorescence techniques. Under 425 nm excitation, mGQDs exhibited emission bands at 495 and 677 nm in their PL spectrum. Fe2+-induced notable quenching of mGQDs’ PL intensity decreased by 97% with 2.5 μM Fe2+ ions; however, adding 20 mM cholesterol resulted in a 92% recovery. Detection limits were established through a linear Stern-Volmer (S-V) plot at room temperature, yielding values of 4.07 μM for Fe2+ ions and 1.8 mM for cholesterol. Moreover, mGQDs demonstrated biocompatibility, aqueous solubility, and nontoxicity, facilitating the creation of a rapid nonenzymatic cholesterol detection method. Selectivity and detection studies underscored mGQDs’ reliability in cholesterol level monitoring. Additionally, a molecular logic gate system employing Fe2+ metal ions and cholesterol as a bioanalyte was established for detection purposes. Overall, this research introduces an ecofriendly approach to craft mGQDs and highlights their effectiveness in detecting metal ions and cholesterol, suggesting their potential as versatile nanomaterials for diverse analytical and biomedical applications. © 2024 American Chemical Society.