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Item Third-order nonlinear optical properties and optical switching of palladium (I) complex(2011) Manjunatha, K.B.; Dileep, R.; Shelar, M.S.; Umesh, G.; Satyanarayan, M.N.; Badekai Ramachandra, B.R.We report the third-order nonlinear optical, optical power limiting and optical switching study of palladium-N-(2-pyridyl)-N′- (5-amino salicylidene) hydrazine triphenylphosphine, using Z-scan technique and pump-probe technique. The measured nonlinear refractive index is n 2=-6.022×10-9esu. The complex exhibits the reverse saturable absorption (RSA), the nonlinear absorption coefficient of β=10.748×10-9m/W. The good optical power limiting and optical switching behavior were observed in this complex. These suggest that this complex is a potential molecule for photonic applications. © 2011 American Institute of Physics.
