Faculty Publications

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    Highly transparent and conducting ITO/Ag/ITO multilayer thin films on FEP substrates for flexible electronics applications
    (Elsevier B.V., 2017) Sibin, K.P.; Srinivas, G.; Shashikala, H.D.; Dey, A.; Sridhara, N.; Sharma, A.K.; Barshilia, H.C.
    Transparent and conducting ITO/Ag/ITO (IAI) multilayer coatings were deposited on glass and flexible fluorinated ethylene propylene (FEP) substrates by reactive sputtering using metallic In:Sn (90%:10%) and Ag targets at room temperature. Middle Ag layer thickness was optimized to obtain maximum figure of merit (?) and the optimum Ag layer thickness was found to be ~13 nm. The optimized IAI multilayer on glass substrate showed transmittance of ~88.6% and sheet resistance of ~7.1 ?/sq. The transmittance increased to ~91.4% for the IAI multilayer deposited on one side etched glass. The optimized IAI multilayer coating was also deposited on flexible FEP substrates. The electrical, optical, structural and morphological properties of IAI deposited on glass and FEP substrates were compared. IAI deposited on FEP substrate showed transmittance of ~90.2% at ? = 550 nm, sheet resistance of ~6.9 ?/sq. and figure of merit of ~52 × 10?3 ??1. Bending test of IAI deposited FEP proved the high flexibility of IAI multilayer for the flexible transparent electrode applications. Solar selectivity study of IAI on FEP substrate showed it can effectively reflect the higher wavelength region of solar spectrum and can be used as a flexible solar spectrum segregator. Optical haze measurements of IAI coated glass and FEP show that high haze value can be achieved by increasing the roughness on non-coated side of the FEP substrate. © 2017
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    Influence of titanium redox states on luminescence and conductivity in TiO2 -doped borophosphate glass system
    (Elsevier B.V., 2025) Rashmi, R.; Ingle, A.; Raghuvanshi, V.; Shashikala, H.D.; Nagaraja, H.S.
    Borophosphate glasses have garnered significant interest due to their potential for optical and electronic applications. This research delves into the luminescent and conductive properties of 40P2O5–25B2O3-(35-x) BaO-xTiO2 (x = 0–5 mol%) glasses synthesized via the melt-quench method. The glass doped with 4 mol% TiO2 exhibited intense luminescence within the 400–600 nm spectrum, manifesting as a vivid blue emission and the highest Ti3+ ion concentration. Beyond this threshold, the luminescence intensity waned, highlighting the significance of Ti4+/Ti3+ ratios. Absorption spectra and X-ray photoelectron spectroscopy were utilized to study these multivalent ions. Temperature-dependent AC conductivity, exhibited a linear increase, consistent with the Correlated Barrier Hopping (CBH) model. Enhanced polaron hopping between Ti3+ and Ti4+ with increasing TiO2 content improved the dielectric constant and conductivity, peaking at 4.145×10?5 Scm?1 at 5 mol% TiO2 within the 450–530 °C range. These findings underscore the tunability of TiO2-doped glasses for optoelectronic applications. © 2024 Elsevier B.V.