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Author: search.filters.author.Sankar Rao, C.S.Subject: search.filters.subject.biofuel

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    Novel strategies for glucose production from biomass using heteropoly acid catalyst
    (Elsevier Ltd, 2020) Nayak, A.; Pulidindi, I.N.; Sankar Rao, C.S.
    Bioethanol and direct glucose fuel cells pledged clean energy to the world. Cellulose depolymerization for glucose production has been a successful approach in bioethanol production. Heteropoly acids (HPAs) are strong Brønsted solid acid catalysts for biomass hydrolysis. Keggin type HPAs, namely, Silicotungstic acid (HSiW), Phosphotungstic acid (HPW), and Phosphomolybdic acid (HPMo), were used for the hydrolysis of lignocellulosic biomass to glucose. Five different biomass feedstocks, namely, miscanthus, sugarcane leaves, switchgrass, sunflower seeds, and bamboo leaves, were examined for the feasibility of total reducing sugar (TRS) yield through the composition analysis and catalytic biomass hydrolysis. Sunflower seeds contained the maximum holocellulose with 90.6%, and switchgrass contained the least i.e., 77.63%. Among the five biomass tested, switchgrass resulted in the highest TRS (5.77 wt/dry wt. %) with HPMo catalyst at a catalyst to biomass ratio of 30:100 (wt./wt. %), a reaction temperature of 120 °C for 3 h. The reaction parameters for depolymerization were optimized for all three HPAs, and the optimized conditions were 3 h and 120 °C. HPMo showed maximum TRS yield (5.77 wt/dry wt.%) among the three HPAs at 30:100 catalyst to biomass ratio. However, a catalyst to biomass ratio of 20:100 (wt./wt.%) was economical (5.25 wt/dry wt.%) for commercial application. © 2020 Elsevier Ltd
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    Synthesis of sustainable chemicals from waste tea powder and Polystyrene via Microwave-Assisted in-situ catalytic Co-Pyrolysis: Analysis of pyrolysis using experimental and modeling approaches
    (Elsevier Ltd, 2022) Suriapparao, D.V.; Sridevi, V.; Ramesh, R.; Sankar Rao, C.S.; Tukarambai, M.; Kamireddi, D.; Gautam, R.; Dharaskar, S.A.; Pritam, K.
    In the current study, catalytic co-pyrolysis was performed on waste tea powder (WTP) and polystyrene (PS) wastes to convert them into value-added products using KOH catalyst. The feed mixture influenced the heating rates (17–75 °C/min) and product formation. PS promoted the formation of oil and WTP enhanced the char formation. The maximum oil yield (80 wt%) was obtained at 15 g:5 g, and the maximum char yield (44 wt%) was achieved at 5 g:25 g (PS:WTP). The pyrolysis index (PI) increased with the increase in feedstock quantity. High PI was noticed at 25 g:5 g, and low PI was at 5 g:5 g (PS:WTP). Low energy consumption and low pyrolysis time enhanced the PI value. Significant interactions were noticed during co-pyrolysis. The obtained bio-oil was analyzed using GC–MS and a plausible reaction mechanism is presented. Catalyst and co-pyrolysis synergy promoted the formation of aliphatic and aromatic hydrocarbons by reducing the oxygenated products. © 2022 Elsevier Ltd
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    The role of solvent soaking and pretreatment temperature in microwave-assisted pyrolysis of waste tea powder: Analysis of products, synergy, pyrolysis index, and reaction mechanism
    (Elsevier Ltd, 2022) Talib Hamzah, H.; Sridevi, V.; Seereddi, M.; Suriapparao, D.V.; Ramesh, R.; Sankar Rao, C.S.; Gautam, R.; Kaka, F.; Pritam, K.
    This study focuses on microwave-assisted pyrolysis (MAP) of fresh waste tea powder and torrefied waste tea powder as feedstocks. Solvents including benzene, acetone, and ethanol were used for soaking feedstocks. The feedstock torrefaction temperature (at 150 °C) and solvents soaking enhanced the yields of char (44.2–59.8 wt%) and the oil (39.8–45.3 wt%) in MAP. Co-pyrolysis synergy induced an increase in the yield of gaseous products (4.7–20.1 wt%). The average heating rate varied in the range of 5–25 °C/min. The energy consumption in MAP of torrefied feedstock (1386 KJ) significantly decreased compared to fresh (3114 KJ). The pyrolysis index dramatically varied with the solvent soaking in the following order: ethanol (26.7) > benzene (25.6) > no solvent (10) > acetone (6). It shows that solvent soaking plays an important role in the pyrolysis process. The obtained bio-oil was composed of mono-aromatics, poly-aromatics, and oxygenated compounds. © 2022 Elsevier Ltd