Faculty Publications
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Item Microwave-assisted batch synthesis of Pongamia biodiesel(2010) Venkatesh Kamath, H.; Iyyaswami, I.; Saidutta, M.B.Background: The major bottleneck of biodiesel synthesis is its cost and this is mainly attributed to the feedstock material. Pongamia pinnata oil is a nonedible oil that is available in plenty in India and has negligible applications. Several methods of synthesis have been established, each having their own advantages and disadvantages. Results & discussion: Biodiesel from high-free fatty acid, nonedible, Pongamia oil was synthesized under microwave irradiation with single- and two-step methods. Experimental investigations showed that although the single-step method had a high yield (80%), the acid value of biodiesel was quite high. Hence, the two-step method seems to be a better approach as it yielded 90%, with 1:10 oil:methanol molar ratio and 1 wt% KOH. Along with a decrease in the reaction time to 4-5 min, separation time was also decreased by at least 90%. A conventional heating method was employed to compare the effects of microwave irradiation on biodiesel synthesis. Conclusion: The results indicate significant improvement in the yield, reaction time and processing time of biodiesel under microwave irradiation. The synthesis of Pongamia biodiesel under microwave irradiation could perhaps lead to cost effective and faster technology in countries such as India. © 2010 Future Science Ltd.Item Optimization of two step karanja biodiesel synthesis under microwave irradiation(2011) Venkatesh Kamath, H.; Iyyaswami, I.; Saidutta, M.B.The free fatty acid of crude karanja oil (Pongamia pinnata) was reduced and biodiesel was synthesized from pretreated oil under microwave irradiation. The process variables such as irradiation time, methanol-oil ratio and sulfuric acid concentration for pretreatment step; irradiation time, methanol-oil ratio and KOH concentration were optimized through the Box-Behnken experimental design. The free fatty acid of crude karanja oil was reduced to 1.11 ± 0.07% with an optimal combination of 190 s irradiation time (180 W), 33.83 (w/w)% methanol-oil ratio and 3.73 (w/w)% sulfuric acid concentration. An optimal combination of 150 s irradiation time, 33.4 (w/w)% methanol-oil ratio and 1.33 (w/w)% KOH concentration yielded 89.9 ± 0.3% biodiesel. The model was validated by conducting experiments at optimal design conditions. The present work confirmed that the microwave energy has a significant effect on esterification and transesterification reaction. © 2010 Elsevier B.V. All rights reserved.Item Two-step biodiesel production and its kinetics studies using indion-190/amberliteira-900 from waste cooking oil(Taylor and Francis Inc. 325 Chestnut St, Suite 800 Philadelphia PA 19106, 2015) Satheesh, K.; JagadeeshBabu, P.E.; Saidutta, M.B.Free fatty acid of waste cooking oil was reduced through esterification using Indian-190 and then transesterified using AmberliteIRA-900 to produce biodiesel. Maximum conversion of 93.69% was observed during esterification at optimized conditions (temperature: 337 K; duration: 4 h; methanol:oil: 20:1; catalyst: 8 wt%). Biodiesel conversion of 98.69% was observed with a yield of 80% through transesterification. Temperature dependence was analyzed using the Langmuir-Hinshelwood model. Activation energy of 134.952 kJ/mol and a frequency factor of 5.49 × 1015 min-1 were observed. Thermodynamic parameters were determined using the Vant Hoff plot. Properties of biodiesel were found to be within ASTM standard. Reusability of Indion-190 was analyzed for five cycles, and found to be satisfactory. © © © Taylor & Francis Group, LLC.