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    Technical aspects of biodiesel and its oxidation stability
    (2009) Kapilan, N.; Ashok Babu, T.P.; Reddy, R.P.
    Biodiesel is a clean burning alternative renewable fuel made from natural renewable sources. It is defined as mono-alkyl esters of long chain fatty acids derived from vegetable oils or animal fats, which conform to ASTM specifications for use in diesel engines. Biodiesel present a very promising alternative fuel to diesel oil and properties of this oil offer the advantage of immediate substitution in existing diesel engines with little or no modifications at all. But one of the major technical problems associated with the biodiesel is its susceptibility to oxidation, which can cause the fuel to become acidic and to form insoluble gums and sediments that can plug fuel filters. This is due to the unsaturated fatty acid chains and the presence of the double bond in the molecule, which produce a high level of reactivity with the oxygen, especially when it placed in contact with air. The oxidation of fatty acid chains is a complex process that proceeds by a variety of mechanisms. The various other factors influence the oxidation process of biodiesel includes light, temperature, extraneous materials, peroxides, size of the surface area between biodiesel and air. One of the methods of improving biodiesel oxidative stability includes the deliberate addition of antioxidants or modification of the fatty ester profile. This article discusses the technical aspects of biodiesel and its oxidation stability.
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    Characterization and effect of using Mahua oil biodiesel as fuel in compression ignition engine
    (2009) Kapilan, N.; Ashok Babu, T.P.; Reddy, R.P.
    There is an increasing interest in India, to search for suitable alternative fuels that are environment friendly. This led to the choice of Mahua Oil (MO) as one of the main alternative fuels to diesel. In this investigation, Mahua Oil Biodiesel (MOB) and its blend with diesel were used as fuel in a single cylinder, direct injection and compression ignition engine. The MOB was prepared from MO by transesterification using methanol and potassium hydroxide. The fuel properties of MOB are close to the diesel and confirm to the ASTM standards. From the engine test analysis, it was observed that the MOB, B5 and B20 blend results in lower CO, HC and smoke emissions as compared to diesel. But the B5 and B20 blends results in higher efficiency as compared to MOB. Hence MOB or blends of MOB and diesel (B5 or B20) can be used as a substitute for diesel in diesel engines used in transportation as well as in the agriculture sector. © 2009 Science Press, Institute of Engineering Thermophysics, CAS and Springer Berlin Heidelberg.
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    Performance and emission characteristics of a Kirloskar HA394 diesel engine operated on fish oil methyl esters
    (2010) Godiganur, S.; Suryanarayana Murthy, Ch.; Reddy, R.P.
    The high viscosity of fish oil leads to problem in pumping and spray characteristics. The inefficient mixing of fish oil with air leads to incomplete combustion. The best way to use fish oil as fuel in compression ignition (CI) engines is to convert it into biodiesel. It can be used in CI engines with very little or no engine modifications. This is because it has properties similar to mineral diesel. Combustion tests for methyl ester of fish oil and its blends with diesel fuel were performed in a kirloskar H394 DI diesel engine, to evaluate fish biodiesel as an alternative fuel for diesel engine, at constant speed of 1500 rpm under variable load conditions. The tests showed no major deviations in diesel engine's combustion as well as no significant changes in the engine performance and reduction of main noxious emissions with the exception on NOx. Overall fish biodiesel showed good combustion properties and environmental benefits. © 2009 Elsevier Ltd. All rights reserved.
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    Performance characteristics of a dual fuel engine operated with Mahua biodiesel and liquefied petroleum gas
    (ASTM International, 2011) Kapilan, N.; Ashok Babu, T.P.; Reddy, R.P.
    Fuel crisis because of dramatic increase in vehicular population and environmental concerns have renewed the interest of the scientific community to look for alternative fuels of bio-origin such as vegetable oils and ethanol. India is looking at biodiesel derived from Mahua oil (MO), as one of the renewable alternative fuels for compression ignition (CI) engine. Although MO biodiesel (MOB) has several advantages over fossil diesel, in the present scenario, the use of biodiesel is restricted due to its high cost. In India, liquefied petroleum gas (LPG) is easily available and is one of the cheapest gaseous fuels. Hence, use of LPG to fuel a CI engine along with MOB seems to be an option for substitution of fossil diesel. In the present work, LPG, which was fumigated along with the air and biodiesel was admitted into the engine cylinder through conventional fueling device as an igniter. A single cylinder CI engine was modified to work in dual fuel mode and engine tests were carried out at rated speed under variable load conditions. The performance of the engine in dual fuel mode was compared with the diesel. The dual fuel operation results in thermal efficiency close to the diesel and also reduces the NOx and smoke emissions significantly. From the experimental results, we concluded that biodiesel in dual fuel mode with cheaper gaseous fuel induction is an option for reducing the operating cost of the biodiesel fuelled CI engine. Copyright ©2011 by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959.
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    Performance characteristics of a dual fuel engine operatedwith mahua biodiesel and liquefied petroleum gas
    (2011) Kapilan, N.; Ashok Babu, T.P.A.; Reddy, R.P.
    Fuel crisis because of dramatic increase in vehicular population and environmental concerns have renewed the interest of the scientific community to look for alternative fuels of bio-origin such as vegetable oils and ethanol. India is looking at biodiesel derived from Mahua oil (MO), as one of the renewable alternative fuels for compression ignition (CI) engine. Although MO biodiesel (MOB) has several advantages over fossil diesel, in the present scenario, the use of biodiesel is restricted due to its high cost. In India, liquefied petroleum gas (LPG) is easily available and is one of the cheapest gaseous fuels. Hence, use of LPG to fuel a CI engine along with MOB seems to be an option for substitution of fossil diesel. In the present work, LPG, which was fumigated along with the air and biodiesel was admitted into the engine cylinder through conventional fueling device as an igniter. A single cylinder CI engine was modified to work in dual fuel mode and engine tests were carried out at rated speed under variable load conditions. The performance of the engine in dual fuel mode was compared with the diesel. The dual fuel operation results in thermal efficiency close to the diesel and also reduces the NOx and smoke emissions significantly. From the experimental results, we concluded that biodiesel in dual fuel mode with cheaper gaseous fuel induction is an option for reducing the operating cost of the biodiesel fuelled CI engine. Copyright © 2011 by ASTM International.