Faculty Publications

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Room-temperature detection of ammonia and formaldehyde gases by La xBa1?xSnO3?? (x = 0 and 0.05) screen printed sensors: effect of ceria and ruthenate sensitization
(Springer Science and Business Media Deutschland GmbH, 2021) Manjunath, G.; Vardhan, R.V.; Praveen, L.L.; Pothukanuri, P.; Mandal, S.
In the present work, gas sensing properties of the screen printed ceria and ruthenate-sensitized BaSnO3 (BSO) with La doping heterostructure sensors towards the detection of ammonia and formaldehyde gases at room temperature were studied. Adhered, porous screen printed films with different morphologies were obtained by depositing the LaxBa1?xSnO3?? (x = 0 and 0.05) powder particles prepared by the polymerized complex method. Ceria and ruthenate sensitization for screen printed LaxBa1?xSnO3?? (x = 0.05) film was processed through dip-coating in the 0.03 M aqueous solution of CeCl3 and RuCl3, respectively. La-doped BaSnO3 (LBSO) sensor with smaller crystallites, needle-like morphology and high concentration of oxygen vacancies exhibited superior gas response of 65 and 29 towards 50 ppm of ammonia and formaldehyde gases, respectively. Superabundant sensitization of ceria and ruthenate reduced the oxygen vacancy and structural open porosity in the LBSO sensor; therefore, the ammonia gas response was decreased from 65 to 14 and 3, respectively, whereas the formaldehyde gas response was reduced to less than 1/6th times the LBSO sensor. Limit of detection of LBSO sensors was estimated to be ~ 1 and ~ 2 ppm against ammonia and formaldehyde, respectively. The presence of fluorite structured phase ceria with high oxygen atoms storage capacity facilitates the rapid oxidization of analyte gases and caused the expeditious response (75 s) and recovery (60 s) in CeOx-sensitized LBSO sensor. This study might give a new insight into the development of doped and sensitized BSO-based gas sensors operating at ambient conditions. © 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature.
All-printed WO3 films on an Ag-interdigitated electrode derived from aqueous screen-printable inks for room-temperature ammonia gas detection
(Institute of Physics, 2025) Praveen, L.L.; Singh, N.P.; Vardhan, R.V.; Mandal, S.
In this work, all-printed tungsten oxide (WO3) sensors were fabricated from nanoparticle-based screen-printable inks, where the WO3 nanopowders were hydrothermally synthesized with various HCl concentrations to give enhanced room-temperature detection of ammonia (NH3) gas. The monoclinic phase of WC powders (calcined WO3) with square nanoplate-like morphology and porosities was identified from x-ray diffraction, field-emission scanning electron microscopy and Brunauer-Emmett-Teller surface area analysis. The silver precursor ink-derived interdigitated electrodes were found to be crystalline with an average finger width and Ag film thickness of 1 ± 0.4 mm and 3.8 ± 0.5 µm, respectively. The formulated WO3 inks with hydroxyethyl cellulose showed a thixotropic fluid-like behavior and exhibited a viscosity of ?9 × 104 mPa s, which is a key requirement for screen printing. Rheological study of the formulated WC inks revealed a thixotropic nature, with all WC inks showing a viscosity of 85 ± 3 Pa s and a recovery rate of 80% in the recovery stage. This work explains the role of pH in hydrothermally synthesis of WO3 by correlating the gas-sensing characteristics of the screen-printed sensors fabricated from formulated inks, where the WC-15 gas sensor showed a maximum gas response of ?340 towards 100 ppm of NH3 gas. This facile and cost-effective method for fabricating chemiresistive gas sensors could pave the way for the development of flexible and printable devices for ppb-level detection of NH3 gas and its monitoring. © 2025 IOP Publishing Ltd. All rights, including for text and data mining, AI training, and similar technologies, are reserved.
Ultra-high ammonia gas response of phase-stabilized (Fe0.2Ni0.2Cr0.2Mn0.2Zn0.2)3O4-? high-entropy spinel oxide sensor array and its machine learning predictions
(Elsevier Ltd, 2025) Praveen, L.L.; Upadhyay, B.; Potnuri, R.; Mandal, S.
In this work, the gas sensing performance of phase-stabilized (FeNiMnZnCr)3O4 high-entropy spinel oxide (HSO) gas-sensors via screen-printing were investigated, where the HSO powders were synthesized via solution combustion synthesis (SCS) using three different fuels: citric acid, urea, and glucose. Although all HSO powders were obtained at 500 °C, the formation of stable spinel phase was evidenced at 600 °C. Among all fabricated sensors, G-800 gas sensor depicted a stable ultra-high response of ?3471 towards 100 ppm of ammonia gas along with a notable response of ?162 even at 10 ppm (where G means glucose and 800 represents calcination temperature in °C) and it demonstrated a strong device-to-device reproducibility with stability of ?35 days. A synergy of crystallinity and increased porosities from XRD and FESEM micrographs resulted in ultra-high gas-response towards ammonia gas compared to volatile organic compounds such as formaldehyde, methanol, and ethanol). The presence of defect band and oxygen vacancies observed from the Raman and XPS analysis, were complemented by the presence of porosities confirmed from BET surface area analysis. Subsequently, the machine learning (ML) algorithms are applied on sensor signals to estimate the concentration of ammonia gas, and among all the ML classifiers, RFC gave reasonably better predictions in three concentrations regimes with a good classification accuracy of 93.3 ± 5.3 %, 90 ± 7.5 %, and 83.3 ± 13.1 % for G-600, G-700, and G-800, respectively. The proposed ML studies enable accurate detection of hazardous ammonia levels using HSO-based sensors, showing strong potential for integration into diagnostic platforms targeting ammonia breath markers. © 2025 Elsevier B.V.

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