Faculty Publications
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Item Introduction to Carbon Capture with Membranes(Elsevier, 2024) Lee, M.D.; Makarem, M.A.; Pragadeesh, K.S.Carbon capture and storage (CCS) is an emerging technology that aims to reduce carbon emissions from industrial processes. Carbon capture with membranes is a subfield of CCS that utilizes specialized membranes to selectively separate CO2 from other gases. This technology is considered to be an efficient and cost-effective option for reducing carbon emissions. This article aims to provide an introduction to carbon capture with membranes and the current state of the technology. The different types of membranes used in carbon capture and their advantages and limitations are discussed. The article also explores the potential for scaling up the technology for large-scale deployment. Additionally, the challenges that need to be addressed for the technology to be widely adopted are also discussed. The article concludes with a brief overview of the potential for carbon capture with membranes to play a significant role in achieving global emissions reduction targets. © 2024 Elsevier Inc. All rights are reserved, including those for text and data mining, AI training, and similar technologies.Item Primary Fragmentation Behavior of Indian Coals and Biomass during Chemical Looping Combustion(American Chemical Society service@acs.org, 2018) Pragadeesh, K.S.; Ruben Sudhakar, D.R.Devolatilization and fragmentation are important physical phenomena occurring during solid fuel chemical looping combustion (CLC). Primary fragmentation during devolatilization strongly affects the rate of fuel conversion, emissions, and fine particulates generation in a fuel reactor of a fluidized bed CLC unit, thus forming a critical design input. The present study focuses on investigating the primary fragmentation behavior of large coal and biomass (wood) particles during the devolatilization phase of CLC. Three types of coals (two Indian coals, one Indonesian coal) and one type of Casuarina wood of three sizes in the range of 8-25 mm, at different fuel reactor bed temperatures (800, 875, and 950 °C) are studied for primary fragmentation. Iron ore with 64% Fe is used as the oxygen carrier bed material, with steam as the fluidizing medium in the fuel reactor. The fragmentation behavior is expressed in terms of the number of fragments, fragmentation index, frequency of fragmentation, and particle size distribution of fragments at different residence times of coal during devolatilization in the fuel reactor. Under the conditions of study, the number of fragments increases with an increase in particle size and temperature, for all fuels studied. Also, it is found that the number of fragments increases with the decrease in compressive strength of both coal and biomass particles. The Indian coals are found to fragment in the earlier stages of devolatilization, while the Indonesian coal and the biomass particles begin to fragment in the later stages of devolatilization. The maximum fragmentation index is found with Indian coal - IC1, which has the highest fixed carbon content among the fuels studied, and the least value is observed in biomass. Different modes of fragmentation exhibited by each fuel type is discussed. Indian coals do not show any volumetric changes as such, whereas Indonesian coal indicates some degree of volumetric expansion. © 2018 American Chemical Society.Item Color Indistinction Method for the Determination of Devolatilization Time of Large Fuel Particles in Chemical Looping Combustion(American Chemical Society service@acs.org, 2019) Pragadeesh, K.S.; Ruben Sudhakar, D.R.Chemical looping combustion (CLC) is one of the promising fuel conversion technologies for carbon capture with low energy penalty. Devolatilization is an important physical phenomenon occurring during solid fuel CLC. Devolatilization behavior influences fragmentation, combustion rate, emission, and particulates generation in fluidized bed CLC (FB-CLC), thus a critical input for its design. Existing visual techniques for determining devolatilization time cannot be applied in CLC conditions because of its flameless combustion nature. In the present study, a new, simple, and quick technique called "color indistinction method" (CIM) is proposed for the determination of devolatilization time (?d) in FB-CLC, where the end of devolatilization is inferred from the disappearance of fuel particle in a hot fluidized bed. Single-particle devolatilization studies in FB-CLC are conducted to determine the devolatilization time using CIM for two types of fuels, viz., coal and biomass (Casuarina equisetifolia wood), of size range 8-25 and 10-20 mm, respectively, at three different fuel reactor bed temperatures (800, 875, and 950 °C) and one fluidization velocity. The proposed technique is validated in three ways: (i) the measurement of residual volatiles present in char by thermogravimetric analysis; (ii) mass loss history of the fuel during devolatilization; and (iii) diagnostics using particle center temperature measurements. The results of CIM experiments, in terms of degree of error involved, are compared with an established flame extinction technique (FET) and a more accurate particle center temperature (PCT) method. The amount of volatiles released during devolatilization, as determined by CIM, is 91.3% for coal and 98.9% for biomass. These values compare very well with the results of the established FET, in which the volatile release is 90.7% for coal and 99.1% for biomass samples. The devolatilization times determined using CIM are in line with particle center temperature measurements with an acceptable error range of -7.57 to +3.70%. The proposed CIM is successful in establishing the devolatilization time of different fuels in CLC conditions and can also be applied in other flameless combustion conditions. © 2019 American Chemical Society.Item Study of devolatilization during chemical looping combustion of large coal and biomass particles(Elsevier B.V., 2020) Pragadeesh, K.S.; Iyyaswami, I.; Ruben Sudhakar, D.R.Chemical Looping Combustion (CLC) is one of the emerging technologies for carbon capture, with less energy penalty. The present way of using pulverized coals in a fluidized bed (FB)-CLC have limitations like loss of unconverted char and gaseous combustibles, which could be mitigated by use of coarser fuel particles. Devolatilization time is a critical input for the effective design of FB-CLC systems, primarily when large fuel particles are used. The present study investigates the devolatilization time and the char yield of three coals of two shapes, namely, two high ash Indian coals and a low ash Indonesian coal and a wood (Casuarina equisetifolia) in the size range of +8–25 mm, at different fuel reactor temperatures (800–950 °C) of a hematite based CLC unit. The devolatilization times of single fuel particles during CLC are determined using a visual method called ‘Color Indistinction Method’. Indonesian coal has the longest devolatilization time among the fuels, and biomass has the least. Increasing the bed temperature enhances the rate of volatile release, whereas this effect is less pronounced in larger particles. Devolatilization of Indonesian coal is found to be strongly influenced by the changes in operating conditions. With the decrease in sphericity, a maximum of 56% reduction in devolatilization time is observed for the +20–25 mm slender particles of Indonesian coals when compared to the near-round particles. The maximum average char yields at the end of the devolatilization phase for coal and biomass are about 55–76% and 16% respectively. Char yield in coal particles increases with an increase in particle size, whereas biomass particles show relatively consistent yield across all experimental conditions. Increase in bed temperature reduces the char yields of coal up to 12% and in biomass up to 30%. High volatile Indian coal is the most influenced fuel by the changes in fuels shape. A correlation for determining devolatilization time under CLC environment is presented, and it successfully fits most of the experimental values within ±20% deviation for coals (R2 = 0.95) and within ±15% deviation for biomass (R2 = 0.97). © 2020 Energy InstituteItem Insitu gasification – chemical looping combustion of large coal and biomass particles: Char conversion and comminution(Elsevier Ltd, 2021) Pragadeesh, K.S.; Iyyaswami, I.; Ruben Sudhakar, D.Utilization of large solid fuel particles in fluidized bed – Chemical Looping Combustion (CLC) has the benefits of reduced energy penalty related to carbon capture. When large fuel particles (mm-sized) are used, comminution plays a vital role in the fuel conversion rate, characteristics of ash, inventory loading and thus in the effective design of CLC systems. The present work deals with the conversion of char of large fuel particles and char fragmentation phenomenon in the insitu-gasification CLC environment. Three different coals and a woody biomass in the size range of + 8–25 mm are tested at three different bed temperatures (800 to 950 °C) in a hematite-based batch CLC unit, using steam as the fluidizing/gasification agent. The char conversion time is found to increase by 60 to 170% when particle size changes from 8 to 25 mm and reduced by 42 to 86% with the increase in bed temperature. Regardless of fuel type and feed size, the inception of char fragmentation is noticed in the very first quarter of conversion indicating its significant influence on the char burnout time. A minimum critical char size exists below which char weakening does not yield breakage, whose values vary between 4.4 and 14.2 mm depending on fuel type and feed size. Fuel type is found to be the prime influencer of char conversion time and fragmentation phenomena. This study recommends the use of large particles of all fuels up to 25 mm in CLC systems without any prior size reduction, except the high-ash coals. © 2021 Elsevier Ltd