Faculty Publications

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    High-Temperature Oxidation Studies of Plasma-Sprayed NiCrAlY/TiO2 and NiCrAlY/Cr2O3/YSZ Cermet Composite Coatings on MDN-420 Special Steel Alloy
    (Springer, 2021) Madhu Sudana Reddy, G.; Prasad, C.D.; Shetty, G.; Ramesh, M.R.; Rao, T.N.; Patil, P.
    The plasma spray process was used to form 70%NiCrAlY + 30%TiO2 and 70%NiCrAlY + 25%Cr2O3 + 5%YSZ cermet coatings on MDN-420 special steel alloy. Cyclic oxidation testing was conducted on coated and uncoated specimens at 700°C under a static air environment. Thermogravimetric analysis was applied to establish the oxidation kinetics. X-ray diffraction (XRD), scanning electron microscopy (SEM)/energy-dispersive x-ray spectroscopy (EDS), and electron probe microanalysis (EPMA) techniques were used to analyze the oxidized products. The NiCrAlY + Cr2O3 + YSZ coating was found to be most resistive when compared with the NiCrAlY + TiO2 coating in the aggressive oxidation environment. Net weight loss was observed for bare MDN-420 alloy due to sputtering. The oxidation resistance of the coatings was due to formation of Cr2O3, NiCr2O4, NiO, and Al2O3 phases. © 2021, ASM International.
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    High-temperature oxidation behavior of plasma-sprayed NiCrAlY/TiO2 and NiCrAlY/Cr2O3/YSZ coatings on titanium alloy
    (Springer Science and Business Media Deutschland GmbH, 2022) Reddy, G.M.S.; Prasad, C.D.; Shetty, G.; Ramesh, M.R.; Rao, T.N.; Patil, P.
    The 70% NiCrAlY + 30% TiO2 and 70% NiCrAlY + 25% Cr2O3 + 5% YSZ metallic coatings are sprayed on titanium-15 alloy of ASTM B338, Grade 2, by using the plasma spray coating technology. Cyclic oxidation studies are conducted on the uncoated and coated alloys at 700 °C under static air environment. The kinetics of oxidation is studied by using the thermo-gravimetric method. Phase, microstructural, and chemical analysis tests are performed on as-sprayed and oxidized coatings. The coated alloys are found to be more resistant when compared to the uncoated alloys. The NiCrAlY + Cr2O3 + YSZ coating is found to be more protective when compared to NiCrAlY + TiO2 coating. It is concluded that the formation of Cr2O3, NiCr2O4, and Al2O3 is attributed to the development of oxidation resistance in the coatings. © 2022, International Institute of Welding.
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    Solid Particle Erosion Behaviour of Plasma-Sprayed (WC–Co)/(Cr3C2–NiCr) Coatings
    (Springer Science and Business Media Deutschland GmbH, 2022) Reddy, G.M.S.; Ramesh, S.; Anne, G.; Ramesh, M.R.; Rao, T.N.; Patil, P.
    This study reports the high-temperature erosion behaviour of plasma-sprayed 35% (WC–Co)/65% (Cr3C2–NiCr) coating on MDN-420 alloy. Plasma spray coatings have always played a pivotal role in enabling industries to combat problems of premature degradation of components that operate in harsh environments. (WC–Co) + (Cr3C2–NiCr) coating is investigated for erosion under various laboratory-simulated conditions. Coating surface is characterized by using an optical microscope, scanning electron microscope (SEM), and X-ray diffraction (XRD). Porosity, microhardness, surface roughness, and adhesion strength of the coating are measured. The solid particle erosion test is conducted at the temperatures of 300 °C, 500 °C and 700 °C with the impact angles of 30° and 90° by using Al2O3 as an erodent in the hot air jet erosion testing machine. The optical profilometer is used to evaluate the erosion volume loss of the coated and uncoated samples. It is observed that erosion resistance of the substrate is found to be higher than the coating at the different test temperatures. As the temperature increases, the erosion resistance of the coating is also increased at all the temperatures for both impact angles of 30° and 90°.The eroded coating surface morphology reveals that the generalized behaviour of the coating is ductile in nature. © 2022, The Author(s), under exclusive licence to Springer Nature Switzerland AG.
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    Investigation of thermally sprayed NiCrAlY/TiO2and NiCrAlY/Cr2O3/YSZ cermet composite coatings on titanium alloys
    (Institute of Physics, 2022) Madhu Sudana Reddy, G.; Prasad, C.D.; Patil, P.; Shetty, G.; Ramesh, M.R.; Nageswara Rao, T.
    The present work investigates the hot corrosion behavior of thermally sprayed 65 pct NiCrAlY + 35 pct TiO2 and 65 pct NiCrAlY + 30 pct Cr2O3 + 5 pct YSZ coatings on titanium 15 alloys. The coatings on the titanium 15 alloy substrates exhibit a near-uniform, dense, and adherent microstructure with a porosity of 2.7 to 2.9%. Thermogravimetric studies are made to examine the hot corrosion performance of coatings in a molten salt environment of Na2SO4 + 60%V2O5 at the temperature of 700 °C for 50 cycles. One cycle is carried out by heating for a period of one hour and cooling the sample at ambient conditions. The corrosion products are analyzed based on scanning electron microscopy, energy dispersive analysis, and X-ray diffraction techniques to study the morphology, phase composition, and abundance of the high-temperature corrosion constituents. The bare titanium-15 alloy, 65 pct NiCrAlY + 35 pct TiO2 coating and 65 pct NiCrAlY + 35 pct Cr2O3 + 5 pct YSZ coating produced a weight gain of 307.92 mg cm-2, 42.16 mg cm-2 and 44.02 mg cm-2 respectively after the period of 50 cycles. The effective resistance of the coatings is due to the formation of Ni3V2O8, NiCr2O4, Cr2O3 & AlV2O4 phases. © 2022 IOP Publishing Ltd.
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    High temperature erosion performance of NiCrAlY/Cr2O3/YSZ plasma spray coatings
    (Taylor and Francis Ltd., 2023) Reddy, G.M.S.; Prasad, C.D.; Patil, P.; Shetty, G.; Naresh, N.; Ramesh, M.R.
    The current investigation's objective was to assess the air jet erosion tester's ability to measure the erosive behaviour of plasma sprayed coatings on titanium-15 alloy. 65% NiCrAlY, 30% Cr2O3, and 5% YSZ make up the coating's chemical composition. A study of microstructure and phases was carried out. Microhardness and adhesive strength have both been measured in this work. With impact angles of 30° and 90° at 300°C, 500°C, and 700°C, Al2O3 erodent was utilised in a solid particle erosion test. An optical profilometer was used to calculate the erosion volume loss. The coating erosion resistance was found to be higher than the substrate sample for the test temperature that was employed, and this was more obvious at higher impact angles and higher temperatures The ductile character of the coating is seen in the contour of the deteriorated coating surface. © 2023 Institute of Materials Finishing Published by Taylor & Francis on behalf of the Institute.
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    Investigation of the effect of NiCrAlY/Cr2O3/YSZ plasma coatings on erosion performance of MDN 420 steel at high temperature
    (Inderscience Publishers, 2023) Reddy, G.M.S.; Prasad, C.D.; Patil, P.; Shetty, G.K.; Kakur, N.; Ramesh, M.R.
    The purpose of the current study was to use an air jet erosion tester to examine the erosive behaviour of plasma sprayed coatings on MDN-420 that were composed of 70% NiCrAlY, 25% Cr2O3, and 5% YSZ. Microstructure and phase studies were performed. Measurements were made on the microhardness and adhesion strength. Al2O3 erodent was used in a solid particle erosion test with impact angles of 30° and 90° at 300°C, 500°C, and 700°C. The erosion volume loss was measured using an optical profilometer. For the test temperature used, it was found that the coating’s erosion resistance was greater than that of the substrate and that it was more pronounced at higher impact angles and higher temperatures. The shape of the degraded coating surface reflects the coating’s ductile nature. © © 2023 Inderscience Enterprises Ltd.