Faculty Publications
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Item Effect of Microwave Hybrid Heating on High-Temperature Adhesive Wear Behavior of High-Velocity Oxygen Fuel-Sprayed WC-CrC-Ni and WC-Co/NiCrFeSiB Coatings(Springer, 2023) Medabalimi, S.; Ananthu, M.R.; Gudala, S.; Ramesh, M.R.HVOF-processed coatings are chemically inhomogeneous and are not metallurgically bonded to the substrate. As a result, components coated with HVOF experience considerable material degradation during sliding wear. Microwave hybrid heating (MHH) is a novel surface modification technique for modifying the as-sprayed properties of the coating. Hence, this paper investigates and compares the wear and frictional behavior of HVOF as-sprayed coatings against MHH samples of WC-CrC-Ni and WC-Co/NiCrFeSiB coatings at elevated temperatures. MHH had a significant impact on wear rate and coefficient of friction by optimizing the porosity, integrated oxide phases and intersplat cohesion strength of the coatings. A modified domestic oven was used to perform MHH on HVOF-coated samples for 5 min at 1200 °C. Wear tests were performed using a pin-on-disk tribometer from room temperature to 200, 400, and 600 °C with Al2O3 disk as a counterface. SEM/EDS and XRD were utilized to examine the microstructural characterization of the coatings and substrate. Both the coatings showed higher wear resistance than the substrate at all temperatures. The WC-Co/NiCrFeSiB coating produced an oxide layer on the worn surfaces and integrated WC, CoWO4, and Fe2SiO4 splats, enhancing wear resistance. The MHH WC-CrC-Ni coating formed Cr2O3 and NiWO4 phases on the worn surfaces, increasing the intersplat cohesion strength between matrix and carbide splats, lowering the overall wear rate. After MHH, the wear rate of a substrate and WC-CrC-Ni coating was 3.5 and 1.12 times more at room temperature and 8.07 and 2.92 times more at 600 °C than WC-Co/NiCrFeSiB coating. © 2022, ASM International.Item Elevated temperatures erosion wear behavior of HVOF sprayed WC-Co-Cr/Mo coatings on Ti6Al4V substrate(Elsevier B.V., 2023) Behera, N.; Medabalimi, S.; Ramesh, M.R.The present research aims to investigate the effect of different impact angles and temperatures on volumetric erosion loss of WC-Co-Cr coating containing 10 wt% Mo. The composite coating was developed using High-Velocity Oxy Fuel (HVOF) process on a titanium substrate (Ti-31). A solid particle erosion behavior of the coatings is carried out at different impact angles (30°, 60°, and 90°) and temperatures (200 °C, 400 °C,600 °C, and 800 °C). The volumetric erosion loss of the coated samples was measured using an air jet erosion tester at high temperatures using Al2O3 as an erodent. The XRD, SEM/EDS, porosity, density, microhardness, bond strength, and scratch tests characterized the as-sprayed coatings. The 3D optical profilometer was employed to evaluate the volumetric erosion loss and the mode of erosion. The scratch resistance of WC-Co-Cr coating is better than WC-Co-Cr/Mo coating. The WC-Co-Cr coating shows a brittle mode of erosion up to 600 °C and a ductile mode of erosion at 800 °C. In contrast, the WC-Co-Cr/Mo coating shows a brittle mode of erosion at 200 °C and a mixed mode of erosion at 400 °C to 800 °C. The volumetric erosion loss of WC-Co-Cr is less than WC-Co-Cr/Mo for all temperatures and impact angles. The formation of oxide phases on the coating surfaces demonstrates erosion resistance at high temperatures. The results of volumetric erosion loss measured by the weight loss method correlate well with a non-contact type 3D optical profilometer. © 2023 Elsevier B.V.Item Effect of Impact Angles and Temperatures on the Solid Particle Erosion Behavior of HVOF Sprayed WC-Co/NiCr/Mo and Cr3C2-CoNiCrAlY Coatings(Springer, 2023) Behera, N.; Medabalimi, S.; Ramesh, M.R.Extreme erosion wear from elevated temperature caused by the impact of entrained solid particles in the fluid stream primarily affects aerospace components and marine parts. This work focuses on increasing the base material erosion resistance by applying thermally sprayed carbide-based coatings. A high-temperature Solid particle erosion behavior of WC-Co/NiCr/Mo and Cr3C2-CoNiCrAlY coatings deposited by the HVOF process on a titanium-31 was evaluated using an air-jet erosion tester. The erosion test was conducted utilizing alumina erodent of grit size 35-50 µm. The effects of impact angles (30°, 60°, and 90°) and temperatures (200-800 °C) on the erosion performance of two coatings are compared. The feedstock powder and as-sprayed coatings were characterized for micro-structure phase composition, porosity, density, micro-hardness, and adhesion strength. SEM/EDS and a 3D optical profilometer were used to examine eroded samples further to determine the erosion mode. The Cr3C2-CoNiCrAlY coating shows a brittle mode behavior of erosion at 200-400 °C and ductile mode behavior of erosion at 600-800 °C. In contrast, the WC-Co/NiCr/Mo coating shows brittle mode behavior of erosion at 200-400 °C and 600-800 °C, a mixed mode behavior of erosion. The erosion loss in volume of Cr3C2-CoNiCrAlY is lower than WC-Co/NiCr/Mo for all temperatures and impact angles. The development of carbide and oxide phases on the eroded surfaces demonstrates increasing erosion resistance at high temperatures. The optical profilometer measures the volumetric erosion loss, compares it with the weight loss method, and finds consistency between them. © 2023, ASM International.Item Cyclic Oxidation and Hot-Corrosion Behavior of HVOF-Sprayed NiCrAl Coating on Industrial Boiler Tube Steels(Springer, 2024) Ramesh, M.R.; Medabalimi, S.; Rupanagudi, R.S.; Prasad, C.D.; Sollapur, S.B.At high temperatures, coatings provide a protective scale development on surfaces to maintain long-term stability. In the current study, ASTM-SA210-Grade A1 (GrA1) and ASTM-SA213-T-11 (T11) boiler tube steels were coated with NiCrAl alloy with high-velocity oxy-fuel (HVOF) to prevent oxidation and hot corrosion. For hot corrosion and oxidation, 50 cycles at 900°C were taken into account. Additionally, tests of hot-corrosion behavior were conducted in an atmosphere containing molten salt (Na2SO4-60%V2O5), while tests of oxidation behavior were conducted in static air. The kinetics of oxidation were calculated using the thermogravimetric method. Using XRD, EPMA, and SEM/EDAX methods, the produced oxide scales were characterized. The oxidation rate of NiCrAl-coated steels was found to be lower than that of uncoated steels. The coated steels subjected to oxidation in air exhibit slow scale growth kinetics and oxides of α-Al2O3 and Cr2O3 on the outermost surface, while accelerated oxidation caused by the molten salt exhibits metastable Al2O3. Along the nickel-rich splat boundary, Cr and Al were formed a preferential oxidation, which prevents other oxygen from entering the coating via pores and voids, resulting in steady-state oxidation. © The Minerals, Metals & Materials Society 2024.Item Microstructural evolution and cyclic oxidation behavior of HVOF-sprayed NiCrSi and NiCrC coatings on T11 steel(Elsevier Inc., 2024) Medabalimi, S.; Hebbale, A.M.; Singh, R.; Desai, V.; Ramesh, M.R.This study analyzes NiCrSi and NiCrC coatings developed on low alloy ferritic stainless steel (grade T11) through the HVOF spraying technique. The coatings were characterized by their phase constitution, microstructure, cyclic oxidation behavior, and hardness. X-ray diffraction (XRD) analysis confirmed the presence of the NiCr solid solution matrix as the primary phase in both coatings. Moreover, the microstructure of the NiCrSi coating included the hard intermetallic compounds like Cr?Si and Ni?Si and the NiCrC coating contained the hard phases like Cr?C? and Ni?C which improved the hardness and the wear resistance of the coatings. Microhardness measurements revealed that the coatings had an average hardness of 300 ± 50 HV, significantly greater than the substrate hardness of 225 ± 25 HV. Cyclic oxidation tests were carried out at 700 °C revealed that both the coatings showed a lower weight gain than the uncoated substrate, suggesting enhanced oxidation resistance. This was because the protective oxide layers like Cr?O? and SiO? in the NiCrSi coating and Cr?O? and NiO in the NiCrC coating were formed. X-ray analysis establish ed. the presence of these oxides, which inhibited oxygen penetration through the coatings and provided additional protection against oxidation. Therefore, the study revealed that both NiCrSi and NiCrC coatings have good mechanical and oxidation resistance properties, which make them suitable for high-temperature applications where there is a need for improved durability, wear resistance, and protection against oxidation. © 2024Item Studies on high temperature erosion behavior of HVOF-sprayed (Cr?C?-NiCr)Si and WC-Co/NiCrAlY composite coatings(Elsevier Ltd, 2025) Medabalimi, S.; Hebbale, A.M.; Gudala, S.; Rokkala, U.; Ramesh, M.R.The present study investigates the high temperature erosion behavior of HVOF sprayed composite coatings on T11 steel substrates by studying (Cr?C?-NiCr)Si and WC-Co/NiCrAlY coatings. Phase composition, cross sectional microstructure, mechanical properties, and erosion resistance were analyzed by XRD, EDS, SEM and three-dimensional optical profilography. The results demonstrate that the WC-Co/NiCrAlY coating has higher erosion resistance and oxidation stability for all temperatures and impact angles tested. Its enhanced performance in high temperature and erosive conditions is attributable to the formation of stable protective oxides such as Al?O? and Cr?O? and intermetallic phases such as Ni?Al and Cr?C?. The NiCrAlY matrix prevents significant decarburization of WC particles, and hence phase stability and oxidation resistance. The (Cr?C?-NiCr)Si coating has higher microhardness due to silicide phases, but is more vulnerable to direct impacts and inferior oxidation resistance. The phase transformations for both coatings are favorable at elevated temperatures which enhances erosion resistance. The WC-Co/NiCrAlY coating is smooth and shallower in erosion craters and is perfectly suited for harsh environments demanding high toughness, impact resistance and oxidation stability. For applications in which high hardness is needed in less severe conditions, the (Cr?C?-NiCr)Si coating is more suitable. © 2024Item Microstructure and elevated temperature wear behavior of HVOF-sprayed SS304L stainless-steel coating(Springer Nature, 2025) Medabalimi, S.; Gudala, S.; Rokkala, U.; Hebbale, A.M.; Ramesh, M.R.The paper aims to investigate the performance of the SS304L stainless steel coating on wear properties by varying load, temperature and velocity. Stainless-steel coatings were fabricated by high-velocity oxy-fuel spraying (HVOF) on superfer800. Surface morphology, elemental distribution and phase analysis were expressed by SEM, EDS, and XRD, respectively. The porosity, average surface roughness, and average microhardness of HVOF stainless steel coating are 2%, 7 µm, and 1167 ± 54 HV0.3, respectively. The wear rate of stainless-steel coating is 0.5 × 10?3 mm3/m at 600 °C with 20 N loads, which is about 16 times lower than the substrate. Adhesion and abrasion are the main wear mechanisms of HVOF stainless steel coatings during high-temperature tests. Comparing to superfer800 substrate, stainless steel coatings showed superior wear resistance at all the loads, temperature and velocities. © The Author(s) 2025.Item Studies on high-temperature erosion behaviour of HVOF sprayed NiCr based composite coatings(Elsevier B.V., 2025) Medabalimi, S.; Hebbale, A.M.; Gudala, S.; Ramesh, M.R.; Gujar, R.; Aravindan, N.; Petr?, J.Solid particle erosion at high temperature is a major problem in many industries and advanced protective coatings are needed to extend the service life of components subjected to harsh environment. The main objective of this study is to investigate the erosion behavior of HVOF sprayed (NiCr) + 5 % Si and (NiCr)+ 2% C based composite coatings at different impact angles and temperature, with specific emphasis on the effect of coating composition. The coatings exhibited excellent erosive wear resistance at elevated temperatures due to the formation of stable oxide layers (CrO, NiCr?O?, SiO?) and the incorporation of silicide phases (Ni?Si) to the NiCrSi coatings. However, NiCrC coatings containing hard carbide phases (such as NiC) showed higher erosion resistance at higher temperatures and normal impact angles (90°) because of their robust microstructure and thermal stability. The analysis of microhardness indicated that NiCrSi coatings provided higher hardness attributable to silicides and were therefore better suited to moderate erosive environments, whereas NiCrC coatings, with slightly lower hardness, exhibited excellent resilience under severe erosive environments. SEM, EDAX and XRD analyses showed that preferential erosion mechanisms were cutting and plowing at oblique angles (30°) and brittle fracture at normal angles (90°). Notably, at 800 °C, NiCrC coatings outperformed the NiCrSi coatings via consistently superior thermal and erosion resistance. These findings indicate that HVOF sprayed NiCrC coatings are suitable for high temperature erosion protection, and NiCrSi coatings are specifically developed for high erosive wear resistance at low impact angles. © 2025 The Author(s)Item Wear and frictional behaviour of partially oxidized and plasma sprayed NiCr and NiCrBSiFe coatings(Nature Research, 2025) Medabalimi, S.; Rokkala, U.; Gudala, S.; Behera, N.; Ramesh, M.R.; Dejene, M.The wear performance of partially oxidized NiCr and NiCrBSiFe coatings were investigated by varing load and speed. The partial oxidized powders were processed from the alloy powder using a flame spray process that involved spraying into distilled water. The partially oxidized powder was then plasma-sprayed onto MDN321 steel. The coatings were characterized for adhesive strength, microhardness, and density. The wear behavior was evaluated at disc speeds of 1, 2, and 3 m/s, with loads ranging from 10 to 50 N, over a 3000 m sliding distance. A significant difference in wear rates between the coating and substrate was observed. Operating at a sliding velocity of 1 m/s under a 10 N load, the substrate’s wear rate was found to be 3.56 times higher than that of the NiCrBSiFe coating, whereas for NiCr coating, it was 2.78 times higher. Wear rate coefficient performance shift takes place between the coatings at 12 N-m/s, product of applied load (C) and sliding velocity (V). In NiCrBSiFe coating, the wear mechanism observed at lower speeds and loads is micro-brittle and mechanism shifts to abrasive wear at higher speeds and loads. In the NiCr partially oxidized coating, the wear mechanism observed involves spallation of the coating at higher loads and adhesive wear at lower loads. Thermo gravimetric analysis of the coatings revealed a weight loss percentage of 1.42 for NiCrBSiFe and 14.09 for NiCr coatings. These findings highlight the NiCrBSiFe partially oxidized coating as being tenfold more stable at high temperatures compared to the NiCr partially oxidized coating. © The Author(s) 2025.