Faculty Publications
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Item Study on low-frequency dielectric behavior of the carbon black/polymer nanocomposite(Springer, 2021) Hiremath, H.; Mathias, K.A.; Sondar, P.R.; Shrishail, M.H.; Kulkarni, S.M.Recently, polymer-based dielectric materials have become one of the key materials to play an essential role in clean energy production, energy transformation, and energy storage applications. The end usage is the energy storage capability because it is a trade-off between dielectric permittivity, dielectric loss, and dissipation factor. Hence, it is of prime importance to study the dielectric properties of polymer materials by adding filler material at a low-frequency range. In the present study, polydimethylsiloxane/carbon black nanocomposites are prepared using the solution cast method. The dielectric properties, such as dielectric constant, dielectric loss, and dissipation factors due to the concentration of filler particles and low-frequency effect on the nanocomposites, are examined. Also, different empirical models are used to estimate the dielectric permittivity of polymer nanocomposites. The low-frequency range of 100 Hz to 1 MHz and the effect of varying volume fractions of carbon black show a significant change in the dielectric properties. It is found that the nanocomposites have a higher dielectric permittivity than the base polymer material. It is also observed that an increase in filler concentration increases the dielectric permittivity, which is confirmed with an empirical model. © 2021, The Author(s).Item Physico-mechanical behavior of carbon black-infused polymer composite(Springer, 2022) Hiremath, H.; Rajole, S.; Sondar, P.R.; Mathias, K.A.; Kulkarni, S.M.This article deals with the development of polymer composites by incorporating carbon blacks (CBs) into polydimethylsiloxane (PDMS) matrix material for improving the mechanical and physical properties of the polymer composites. CBs of nano-size were used as filler material in varying volume percentages (5–25%), and the polymer composite was processed by solution casting method. Density, elastic modulus and hardness were measured in order to study the effect of the CB-reinforced PDMS matrix. Experimentally obtained mechanical properties were then compared with the standard empirical model. Density of the polymer composite was increased by five times as compared to the pure polymer material. With the increase in volume percentage of CB, both hardness and elastic modulus of the polymer composites were enhanced. Scanning electron microscope images of the composite material showed uniform distribution of CBs, implying strong binding with the matrix material, which attributed to improved mechanical properties. © 2021, Indian Academy of Sciences.