Faculty Publications
Permanent URI for this communityhttps://idr.nitk.ac.in/handle/123456789/18736
Publications by NITK Faculty
Browse
10 results
Search Results
Item Improved electrochemical performance of graphene oxide supported vanadomanganate (IV) nanohybrid electrode material for supercapacitors(Elsevier Ltd, 2020) Kumari, S.; Maity, S.; Anandan Vannathan, A.A.; Shee, D.; Das, P.P.; Mal, S.S.Graphene oxide (GO)-supported polyoxometalates (POMs) have been considered as promising electrode materials for energy storage applications due to their ability to undergo fast and reversible redox reactions. Herein, vanadomanganate-GO composites (K7MnIVV13O38.18H2O-GO with 2:1 and 4:1 ratio) were investigated for use as potential electrode materials in supercapacitors (SCs). The K7MnIVV13O38.18H2O (MnV13) was synthesized and anchored on GO through electron transfer interaction and electrostatic interaction to make the composite electrodes for the present study. All synthesized electrode materials were fully characterized by various techniques, e.g., Fourier Transform Infrared (FTIR) Spectroscopy, Powder X-ray Diffraction (XRD), Scanning Electron Microscopy/Energy Dispersive X-ray Spectroscopy (SEM/EDS) and High Resolution-Transmission Electron Microscopy (HR-TEM). The electrochemical properties of MnV13/GO composites with different MnV13/GO ratios were investigated by two-electrode cyclic voltammetry (CV) and galvanostatic charge/discharge (GCD) in different electrolytes. The MnV13/GO composite of ratio 2:1 in 1 M LiCl electrolyte and that of ratio 4:1 in 1 M Na2SO4 electrolyte showed significant specific capacitance values of 269.15 F/g and 387.02 F/g, respectively and energy density of 37.38 Wh/kg and 53.75 Wh/kg, respectively for a scan rate of 5 mV/s. Interestingly, the 1:1 (MnV13/GO) composite in 1 M Na2SO4 and 1 M LiCl electrolytes showed very low specific capacitance values as the deposition of MnV13 on GO was not sufficient, as indicated by FTIR and SEM. Thus, it is evident that the specific capacitance value of these composite materials depends on the amount of MnV13 deposited on GO and these composite materials exhibit the potential to improve the performance of GO-based SCs. © 2019Item Redox-Active Vanadium-Based Polyoxometalate as an Active Element in Resistive Switching Based Nonvolatile Molecular Memory(Wiley-VCH Verlag info@wiley-vch.de, 2020) Sterin, N.S.; Basu, N.; Cahay, M.; Satyanarayan, M.N.; Mal, S.S.; Das, P.P.Resistive switching (RS)-based random access memory has been envisaged as a viable alternative to existing memory technology due to its nonvolatility, high switching speed, high endurance/retention, and considerably low operating voltage. Herein, a new uniform, repetitive, and stable RS phenomenon is demonstrated based on very low-cost two-terminal metal–insulator–metal stack fabricated using a highly redox-active vanadium-based polyoxometalate (POM) molecular clusters, [V10O28]6?—belonging to polyoxovanadate (POV) family. The RS is observed to be unipolar and nonvolatile in nature, and occur at a fairly low operating bias voltage (less than 2 V), making it suitable for low-power operations. The switching event is attributed to the cycling between formation and rupture of tiny conductive nanofilaments formed due to trapping and detrapping of positively charged ionized oxygen vacancy sites present in the active switching layer of [V10O28]6?. POMs, in their rich abundance, are highly stable early transition-metal oxide nanosized clusters, capable of storing as well as releasing a large number of electrons. In addition, they can undergo fast and reversible redox reactions (both in solid and liquid electrolyte media) in “stepwise” manner—a property that makes them a promising candidate for ultrafast and multi-level nonvolatile molecular memory for high-density data storage. Preliminary investigations on the POV-based memory cells result in device resistance ratio ?25, endurance for more than 200 cycles, and stable retention time around 2200 s, in fully open air condition. © 2020 Wiley-VCH GmbHItem In situ vanadophosphomolybdate impregnated into conducting polypyrrole for supercapacitor(Elsevier Ltd, 2020) Anandan Vannathan, A.A.; Maity, S.; Kella, T.; Shee, D.; Das, P.P.; Mal, S.S.The fast modernization and advancement in lifestyle increase the consumption of power daily due to all innovative technologies, e.g., hybrid vehicles, solar cells, smart power grid, communication devices, artificial hearts, etc. Conducting organic polymer-based energy storage devices had attracted much attention due to the conductive nature for a long time. However, its application has been restricted because of swelling and shrinking capability during the charge and discharge cycle. The combination of redox-active inorganic metal oxides, such as polyoxometalates (multi-metal oxide cluster) with conduction polymers, could enhance the material's stability due to its fast multi-electron redox property. Here, we report the two polypyrroles combined vanadophosphomolybdates, namely PPy-H4[PVMo11O40] and PPy-H5[PV2Mo10O40] nanohybrid electrode materials. The PPy-H5[PV2Mo10O40] electrode material behaves as pseudocapacitance and can deliver an excellent capacitance of 561.1 F/g in 0.1 M H2SO4 electrolyte solution at a 0.2 A/g current density, indicating capacitive composite material. The electrochemical impedance spectroscopy (EIS) reveals that PPy-H5[PV2Mo10O40] is more capacitive than PPy-H4[PVMo11O40] and PPy with equivalent series resistance (ESR) of 5.74 ?. The cell capacitance of PPy-H5[PV2Mo10O40] and PPy-H4[PVMo11O40] are found to be 5.38 and 9.15 mF, stipulating in small SC cell application. Likewise, the PPy-H5[PV2Mo10O40] nanohybrid electrode shows better responsive behavior with a relaxation time of 0.16 ms. Furthermore, the PPy-H5[PV2Mo10O40] electrode exhibits outstanding cycle stability, retaining ~95% of its capacitance after 4500 cycles as compare to PPy-H4[PVMo11O40] (~91%) electrode. © 2020Item Enhanced Power Density of Graphene Oxide–Phosphotetradecavanadate Nanohybrid for Supercapacitor Electrode(Springer, 2021) Maity, S.; Anandan Vannathan, A.A.; Kumar, K.; Das, P.P.; Mal, S.S.Successful exploration of supercapacitor (SC) material to integrate with high energy and high power density storage device still remains a daunting challenge. Conducting carbon nanostructures have been primarily used for this purpose; however, most of their surface area remains unutilized throughout the storage process. Herein, a new type of hybrid material has been reported by effectively using active sides of carbon nanostructures. Insertion of faradaic-type polyoxometalates (POMs), namely phosphotetradecavanadate (Na7[H2PV14O42], hereafter described as PV14), into the graphene oxide (GO) matrix creates a novel hybrid material for SC applications. Owing to the formation of nanohybrid, it can store charges both electrostatically and electrochemically. PV14/GO composite’s electrochemical behavior in different electrolyte (acidic/neutral) solutions shows different types of characteristics. The PV14/GO composite as a working electrode exhibits a high galvanostatic capacitance of 139 F/g while maintaining at a power density of 97.94 W/kg in 0.25 M H2SO4 electrolyte. The specific energy density was also found out to be around 56.58 Wh/kg at a 5 mV/s scan rate for the same electrolyte. Furthermore, in 1 M Na2SO4 solution, PV14/GO composite demonstrates a specific capacitance of 85.4 F/g at a scan rate of 5 mV/s. The equivalent series resistance for the device was found to be approximately 0.51 ? with a circuit resistance of 3.881 ?, using electrochemical impedance spectroscopy. The cell capacitance, employing the Nyquist plot, was calculated to be around 2.78 mF. © 2021, ASM International.Item Activated carbon- supported Vanado-nickelate (IV) based hybrid materials for energy application(Elsevier Ltd, 2021) Maity, S.; BM, N.; Kella, T.; Shee, D.; Das, P.P.; Mal, S.S.The rapid development of supercapacitor (SC) technology leads to increased demand for nanofabrication of novel and effective electroactive hybrid materials for next-generation energy storage devices. Herein, nickel tetradecavanadate, K2H5[NiV14O40](NiV14), is doped into porous activated carbon (AC), for the first time, in different wt.% in order to investigate the homogeneous loading of the inorganic metal-oxide component on the AC matrix. The resulting complex, AC-NiV14, is found to have possessed an enhanced electrochemical characteristic (for both symmetric and asymmetric SC cell), which operates at a significantly higher potential of 1.2 V. The combination of the double-layer capacitance (EDLC) and the redox-active polyoxometalate cluster leads to an intrinsic increase in specific capacitance (capacity) (from 45.3 Fg?1 (54.4 Cg?1) for AC to 316 Fg?1 (379.2 Cg?1) for 15 wt.% AC-NiV14 at a current density of 1 Ag?1). It was also observed that there is an increase of 20% in the operating voltage compared to conventional AC supercapacitors with acidic aqueous electrolytes. Firstly, symmetric supercapacitor's electrochemical performances of various wt.% of NiV14 composition were studied in acidic aqueous electrolyte (0.5 M H2SO4) solution. We observed that the 15 wt.% of AC-NiV14 hybrid electrode showed remarkable specific energy value (~63.2 Wh kg?1) compared with pristine AC and NiV14 electrodes, separately. Besides, the asymmetric layout (AC//AC-NiV14) increased the potential window up to 1.5 V and enhanced the specific energy and power values (90.1 Whkg?1 and 2400 Wkg?1, respectively), with 98% coulombic efficiency. Meanwhile, the AC-NiV14//NiV14 asymmetric cell possesses a specific capacitance (capacity) of 375 Fg?1 (450 Cg?1) with a maximum power of 3140 Wkg?1 at the high current density of 2 Ag?1. © 2021 Elsevier LtdItem Phosphomolybdic acid embedded into biomass-derived biochar carbon electrode for supercapacitor applications(Elsevier B.V., 2023) J.e, M.; Chandewar, P.R.; Shee, D.; Mal, S.S.In high-performance, clean, safe, and cost-effective ways, supercapacitors are among the most promising ways to store and release nonfossil energy. In recent years, renewable biomass-derived activated carbon has been explored as a potential option for electrode material. It restricts their specific capacitance despite being environment-friendly and possessing intrinsic mechanical strength. In order to overcome this limitation and preserve all other properties, we are infusing polyoxometalate into the activated carbon; this increases specific capacitance with its fast reversible redox behaviour and preserves the carbon's characteristics. Beside suffusing phosphomolybdic acid (PMA) into biomass waste material, such as orange peel-derived activated carbon (OPAC), a new hybrid material (OPAC-PMA) was developed. The nanohybrid design was revealed by structural and morphological research, which showed high interfacial contact, allowing polyanions to redox rapidly. The novel hybrid electrode material (OPAC-PMA) has a capacitance value of 66% higher than the bare OPAC electrode. A further study showed that OPAC-PMA composite showed 88.23% cycle stability in 0.5 M H2SO4 electrolyte at 6 A g−1 for 4000 cycles. © 2023 Elsevier B.V.Item High-performance hybrid supercapacitor-immobilized Wells-Dawson polyoxometalates on activated carbon electrodes(Royal Society of Chemistry, 2023) Madhusree, J.E.; Chandewar, P.R.; Shee, D.; Mal, S.S.The nanofabrication of electroactive hybrid materials for next-generation energy storage devices is becoming increasingly significant as supercapacitor (SC) technology develops rapidly. The present study utilizes activated carbon (AC) templates reinforced with Wells-Dawson polyoxotungstates (POMs) to produce nanohybrid electrodes for high-performance supercapacitors. This study analyzes Wells-Dawson polyoxotungstates (P2W18) for the first time integrated with AC, and its structural and electrochemical performances are discussed. First, the electrochemical performances of symmetric supercapacitors were characterized in an acidic aqueous electrolyte (0.5 M H2SO4). It was observed that a supercapacitor cell containing the 5 wt% AC-P2W18 hybrid symmetric displayed a noteworthy specific capacitance of 289 F g−1 and a remarkable energy density of 40 W h kg−1. Moreover, 5% AC-P2W18 symmetric supercapacitor cells showed 89% cyclic stability over 4000 cycles. Three LED lights were charged onto the electrode. The LEDs continued to illuminate continuously for red until 160 seconds, yellow until 20 seconds, and blue until 10 seconds after removing the electrode from the electrochemical workstation, demonstrating the device's power and energy density. © 2023 The Royal Society of Chemistry.Item High-performance electrochemical supercapacitors based on polyoxometalate integrated into polyaniline and activated carbon nanohybrid(Springer Science and Business Media Deutschland GmbH, 2023) Anandan Vannathan, A.A.; Kella, T.; Shee, D.; Mal, S.S.Polyaniline (PANI) and carbonaceous materials and metallic compounds have played a significant role in energy storage and conversion devices. PANI has demonstrated tremendous potential in the supercapacitor industry due to its high specific capacitance, high flexibility, and economical price. The CPs damage the hierarchical structure during the charging and discharging process and start swelling. Thus, incorporating polyoxometalates (POMs) into the conducting polymer matrix increases the stability of the electrode material. Here, we have demonstrated a comparative study of two newly synthesized composite materials consisting of K5H2[PV4W8O40] ·11H2O, (PV4W8) POM incorporated into two different supports, such as pseudocapacitive polyaniline (PANI) and EDLC activated carbon (AC) matrix. It was observed that the PANI-PV4W8 composite exhibited excellent capacitance nature at 0.5 M H2SO4 electrolyte solution than AC-PV4W8. The PANI-PV4W8 composite demonstrated the specific capacitance of 584 F g−1 at 0.8 A g−1. The composite also exhibited energy and power density of 81Wh kg−1 and 1598 W kg−1, respectively. Besides, the composite shows 93.13% capacity retention after 4500 cycles by cyclic voltammetry measurement at a 500 mV s−1 scan rate. Furthermore, the AC-PV4W8 showed a specific capacitance of 62 F g−1 at the current density of 0.6 A g−1. Interestingly, The PANI-PV4W8 composite could glow up the red and yellow LED bulb for more than a minute, suggesting a promising electrode material for practical supercapacitor purposes. © 2023, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.Item Fabrication of supercapacitor electrode material using carbon derived from waste printer cartridge(Springer Science and Business Media Deutschland GmbH, 2024) Biradar, B.R.; Maity, S.; Chandewar, P.R.; Shee, D.; Das, P.P.; Mal, S.S.Transforming recyclable materials into a suitable product is an important area of research nowadays. This report demonstrates that carbon material derived from waste printer cartridges can be exploited to fabricate electrochemical cells—particularly supercapacitors (SCs). SCs are electrochemical energy storage devices currently attracting much attention in the research community due to their salient features, such as cost-effectiveness, extended cycle stability, and durability. Here, we report the results of thoroughly examining the effects of acidic, basic, and neutral aqueous electrolytes on printer waste carbon electrode material in SC efficiency. In our work, the waste carbon collected from used printer cartridges shows a specific capacitance of 178.4 F/g with energy and power density of 24.77 Wh/kg and 999.68 W/kg, respectively, at 0.5 A/g current density in acidic (1 M H2SO4) electrolyte medium. Moreover, it exhibited very promising capacitance of 135.04 F/g and 87.04 F/g in basic (1 M LiOH) and neutral (1 M NaCl) electrolyte medium, respectively, at 0.8 A/g current density with considerably better cycle stability. In an acidic medium, printer waste carbon drives a DC motor for 1 min with a three-cell series arrangement. The properties of that waste carbon (extracted from the cartridges) are similar to high-rate activated carbon available commercially. Graphical Abstract: (Figure presented.). © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.Item Dual-functional phosphomolybdic acid–polypyrrole–ionic liquid nanocomposites for energy storage and hydrogen evolution: experimental and theoretical studies(Royal Society of Chemistry, 2025) Anees, M.P.K.; Iniyan, S.; Pratap Singh, C.; Murugavel, M.; Krishnamurty, S.; Mal, S.S.Recent advancements in pseudocapacitive materials for energy storage and catalytic activities highlight the benefits of incorporating nanostructured active materials. This study investigates the modification of polypyrrole (PPy) surfaces using polyoxometalate H4[PVMo11O40].xH2O (PVMo11) combined with ionic liquids hexadecyltrimethylammonium chloride (CTAC) and 1-benzyl-3-methylimidazolium chloride (BMI). Among various synthesized nanocomposites, PVMo11-BMI-PPy demonstrated superior electrochemical properties in a 0.25 M H2SO4 aqueous electrolyte, achieving a remarkable specific capacitance of 400 F g?1, an energy density of 49.5 W h kg?1 and a power density of 906 W kg?1 at a current density of 1 A g?1. It achieves a capacitive contribution of 94.5% at 10 mV s?1 with an impressive cyclic retention rate of 91.1% and a coulombic efficiency of 98.9% after 10?000 GCD cycles. Additionally, PVMo11-BMI-PPy exhibited outstanding electrocatalytic activity for hydrogen evolution reaction (HER), achieving the highest catalytic activity of 19 mV at a current density of 10 mA cm?2, outperforming the benchmark Pt catalyst. Its superior performance is underscored by a high TOF of 6.91 × 10?7 s?1 and excellent long-term stability in 0.5 M H2SO4 over 24 hours. It is a promising candidate for bifunctional activities such as energy storage and catalytic applications. Additionally, density functional theory (DFT) studies were conducted to gain insights into the enhanced performance of PVMo11-BMI-PPy. The thermodynamic and electronic characteristics indicate that the V site of PVMo11-BMI-PPy offers the most efficient and balanced catalytic environment for hydrogen evolution reaction (HER) compared with all other sites examined. These theoretical findings align well with experimental observations, demonstrating superior HER activity of the PVMo11-BMI-PPy catalyst, thereby confirming the computational predictions. This journal is © The Royal Society of Chemistry, 2026