Faculty Publications
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Item The ultrafast nonlinear optical response and multi-photon absorption of a new metal complex in the near-infrared spectral range(Institute of Physics Publishing, 2010) Kiran, A.J.; Lee, H.W.; Sampath Kumar, H.C.; Rudresha, B.J.; Badekai Ramachandra, B.; Yeom, D.-I.; Kim, K.; Rotermund, F.A new coordination compound, chloro(1,10-phenanthroline-N, N ?)(triphenylphosphine)copper(I) dichloromethane, incorporated in poly(methyl methacrylate) exhibits superior nonlinear optical properties in the near-infrared spectral region. Its nonlinear response time and third-order nonlinear optical susceptibility at 800nm are ? 90fs and 1.8 × 10 -10esu, respectively. Considerable nonlinear absorption is observed with this sample, near 800 and 1250nm. The contribution of the excited states to the total nonlinear absorption process is discussed. The results reveal the potential of this newly designed compound for multi-photon absorption-based photonic applications. © 2010 IOP Publishing Ltd.Item Nonlinear optical study of palladium Schiff base complex using femtosecond differential optical Kerr gate and Z-scan techniques(2012) Rudresha, B.J.; Badekai Ramachandra, B.R.; Ramakrishna, D.; Anthony, J.K.; Lee, H.W.; Rotermund, F.A femtosecond differential optical Kerr gate (DOKG) and Z-scan techniques, have been applied to investigate the third-order optical nonlinearity of composite film of the coordination complex [PdLPPh 3] (L=N-(2-pyridyl)-N'-(salicylidene)hydrazine, PPh 3=triphenylphosphine) . Film exhibits superior nonlinear optical properties in the near-infrared spectral region. The nonlinear response time and third-order nonlinear optical susceptibility of complex were found to be?90 fs and 3.9×10 -10 esu, respectively. The Z-scan result shows that saturable absorption property of the film and its nonlinear absorption coefficient of the sample was found to be -23 cm/GW. © 2011 Elsevier Ltd. All rights reserved.
