Faculty Publications
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Item Effect of temperature on magnetic and impedance properties of Fe3BO6 of nanotubular structure with a bonded B2O3 surface layer(American Institute of Physics Inc. subs@aip.org, 2018) Kumari, K.; Ram, S.; Kotnala, R.K.In this investigation, we explore a facile synthesis of Fe3BO6 in the form of small crystallites in the specific shape of nanotubes crystallized from a supercooled liquid Fe2O3-B2O3 precursor. This study includes high resolution transmission electron microscopy (HRTEM) images, magnetic, optical, and impedance properties of the sample. HRTEM images reveal small tubes of Fe3BO6 of 20 nm diameter. A well resolved hysteresis loop appears at 5 K in which the magnetization does not saturate even up to as high field as 50 kOe. It means that the Fe3BO6 nanotubes behave as highly antiferromagnetic in nature in which the surface spins do not align along the field so easily. The temperature dependent impedance describes an ionic Fe3BO6 conductor with a reasonably small activation energy Ea ? 0.33 eV. Impedance formalism in terms of a Cole-Cole plot shows a deviation from an ideal Debye-like behavior. We have also reported that electronic absorption spectra are over a spectral range 200-800 nm of wavelengths in order to find out how a bonded surface layer present on the Fe3BO6 crystallites tunes the 3d ? 3d electronic transitions in Fe3+ ions. © 2018 Author(s).Item Sensitivity Study of Nanocrystalline Fe3BO6 Sensor for Methane Gas Detection(Institute of Electrical and Electronics Engineers Inc., 2018) Kumari, K.; Ram, S.The iron borate Fe3BO6 with functionalized properties in a nanostructure is an important material useful for electrodes, gas sensors, and biological probes. In this paper, we studied the X-ray diffraction pattern, field-emission electron microscopy, and methane (CH4) gas sensing properties of synthesized Fe3BO6 nanocrystallites in a shape of nanoplates and nanobars from an iron borate glass 40Fe2O3-60B2O3 by annealing it in microwave for 15 min at 823 and 1023 K, respectively, in air. The temperature dependent sensitivity for CH4 (1000 ppm) illustrates a maximum value of 43% at an operating temperature 525 K for the 1023 K annealed sample. The sensitivity is found to be varied from 9% to 39% when the CH4 gas concentration is increased from 50 to 1000 ppm. Thus, the sample has a reasonably good sensitivity for methane. Furthermore, the sensor exhibits fast response (1 min) and a good recovery time (1.6 min) as compared with other oxide materials. © 2001-2012 IEEE.Item Thermal stability and spectroscopic properties of Fe 3 BO 6 of small crystallites with a bonded carbon surface layer(Elsevier Ltd, 2019) Kumari, K.A well-known canted antiferromagnetic Fe 3 BO 6 with functionalized properties is an important material useful for light energy carrier, electrodes, gas sensors, and biological probes. In this investigation, a facile synthesis is explored in order to obtain Fe 3 BO 6 of small crystallites in a specific shape of nanoplates by self-combustion method. To access (i) whether Fe 3 BO 6 is formed at the as-prepared stage and (ii) how it stands stable with a residual carbon surface layer, thermal gravimetric (TG) analysis has been carried out by heating 10–20 mg powder (as-prepared) at a typical 10 K/min heating rate over 300–1100 K under air or argon atmosphere. The electronic absorption, infrared (IR) and Raman spectra studied for the Fe 3 BO 6 sample in this investigation elucidate how the density of states of the phonons and valence electrons confine in small crystallites. IR and Raman bands in the oxygen polygons also confer the results of forming Fe 3 BO 6 with a bonded surface carbon layer. A stable bonded surface layer supports thermal stability of small crystallites and it affects other useful functional properties. © 2018 Elsevier B.V.Item Synthesis and characterization of zinc oxide incorporated iron borate glass-ceramic(Elsevier Ltd, 2019) Ramteke, R.; Kumari, K.; Bhattacharya, S.; Rahman, M.R.Here, zinc oxide (ZnO) incorporated iron borate (Fe3BO6) glass-ceramics have been synthesized using the traditional melt-quenching technique, and the role of ZnO has been investigated. X-ray diffraction (XRD) and scanning electron microscopy (SEM) reveals that the prepared samples have a single crystalline phase and crystalline nanostructures, respectively. The orthorhombic crystal structure has been retained without the formation of a new crystalline phase. The addition of ZnO is found to distort the Fe3BO6 lattice by substituting Zn2+ in the Fe3+ sites, with the formation of ZnO6 structural units as revealed by Fourier transform infrared spectroscopy (FTIR). FTIR and Raman spectroscopy conducted to study the structure of glass-ceramic, have also revealed the formation of other structural units like ZnO4, BO3, BO4, and FeO6 in the system. Surface analysis conducted by X-ray photoelectron spectroscopy (XPS) reveals that the addition of ZnO diminishes the formation of surface B2O3 layer which forms over the Fe3BO6 phase in the Fe3BO6 iron borate glass-ceramic system. ZnO addition has also shown a remarkable difference in the volume of the crystallization in the system, thereby paving the way for controlled crystallization in the iron borate glass-ceramic system. The controlled crystallization was achieved through additive content, retaining the iron borate (Fe3BO6) glass-ceramic system without the evolution of any secondary phases even with large additive concentrations up to 10 mol%. © 2019 Elsevier B.V.Item Impedance spectroscopy study of zinc oxide incorporated iron borate glass-ceramic(Elsevier B.V., 2021) Ramteke, R.; Kumari, K.; Bhattacharya, S.; Sharma, S.K.; Rahman, M.R.Here, the effects of zinc oxide (ZnO) on impedance and dielectric properties of the ZnO incorporated iron borate (Fe3BO6) glass-ceramics were studied using impedance spectroscopy in a wide range of frequency (1 Hz – 1 MHz) and temperature (25 °C–250 °C). With ZnO addition, the ?? and tan? values were reduced significantly, the strength of the relaxation process also decreased, along with a decrease in conductivity. Activation energies associated with modulus and conductivity plots suggest that similar type of charge carriers was responsible for the relaxation and conduction processes. The analysis of both complex impedance and conductivity show the negative temperature coefficient of resistance (NTCR) behavior of the samples. The thermistor constant B-values of 5ZnO and 10ZnO were found to be 7223 and 7088 respectively. The study of the NTCR properties suggests a potential candidate for thermistor applications. © 2021 Korean Physical Society