Faculty Publications
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Item Experimental and theoretical studies of various solar control window glasses for the reduction of cooling and heating loads in buildings across different climatic regions(Elsevier Ltd, 2018) G, K.K.; Saboor, S.; Kumar, V.; Kim, K.-H.; Babu, A.The glass material and position/orientation of windows are very important to control the heat gain in buildings. In this article, we studied the effect of different window glazing materials (such as bronze, green, grey, bronze-reflective, green-reflective, grey-reflective, gold-reflective, opal blue-reflective, and sapphire blue-reflective glass) in controlling the heat gain by the buildings. The spectral data of diverse window glasses have thus been measured in solar spectrum range of 300–2500 nm. Moreover, the MATLAB codes have been developed to compute solar optical properties (including transmittance, reflectance, and absorbance), solar heat gain coefficient (SHGC), and heat transfer through the glazing material. Thermal analysis was carried out using a total of nine window glasses in eight coordinal directions (E, W, N, S, SE, SW, NE, and NW) against three climatic conditions (hot and dry, warm and humid and composite) in India. In terms of net annual cooling and heating cost savings per window, the grey reflective glass was found to be the most energy saving glass among all glasses tested in this study. The grey reflective glass exhibited the highest cost saving in net annual cooling and heating in all eight orientations across three climatic regions. The grey reflective glass saved the net cost of heating and cooling by $ 61.24 per annum in the south orientation of Jodhpur climatic conditions. © 2018 Elsevier B.V.Item Large and Uniform Single Crystals of MoS2Monolayers for ppb-Level NO2Sensing(American Chemical Society, 2022) Patel, C.; Singh, R.; Dubey, M.; Pandey, S.K.; Upadhyay, S.N.; Kumar, V.; Sriram, S.; Than Htay, M.; Pakhira, S.; Atuchin, V.V.; Mukherjee, S.Recently, unprecedented interest has been immersed toward the synthesis of two-dimensional (2D) transition metal dichalcogenides via the chemical vapor deposition (CVD) system. Synthesis of a uniform and large-sized monolayer MoS2atomic thin film via CVD is still a major bottleneck owing to strong dependence on diverse associated growth parameters. In this work, we have proposed the most viable recipe which is suitable for controlling the nucleation density of Mo and producing a 90 μm-long MoS2monolayer crystal and (695 × 394.8) μm2large MoS2monolayered film on SiO2/Si and c-plane sapphire, respectively. Moreover, MoS2monolayer sensing performance has been thoroughly investigated for NO2exposure at room temperature with a varying response of 4-57.5 for the 100-100 ppm level. Furthermore, the MoS2monolayer sensor exhibits an ultrasensitive NO2detection with limit of detection and limit of qualification values of 1.4 and 4.6 ppb, respectively. In addition, the first-principles-based density functional theory has been employed to analyze the adsorption of NO2on the surfaces of the 2D MoS2monolayer. It is observed that the electronic band gap of the MoS2monolayer after NO2adsorption is reduced by 0.7 eV due to molecular orbital hybridization. © 2022 American Chemical Society. All rights reserved.