Faculty Publications
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Item Sustainable structural materials: From fundamentals to manufacturing, properties and applications(CRC Press, 2025) Elango, E.; Markandan, K.; Hassan, C.S.B.; Koppad, P.G.The current trend is to develop novel sustainable composite materials to enhance their properties for use in wider range of applications. With an emphasis on SDG 9, SDG 11 and SDG 12, academicians and industrialists have intensified R&D on sustainable composite materials for use in myriad applications such as construction, membrane technology, water purification and energy capture. This book aims to provide comprehensive understanding of fundamentals, properties and applications of sustainable composite materials. The book, comprising of 21 chapters, promises to be highly beneficial for academicians and early career researchers working in the field of sustainable composite materials. © 2025 Elango Natarajan, Kalaimani Markandan, Cik Suhana Binti Hassan and Praveennath G. Koppad. All rights reserved.Item Tribological aspects of Al and Mg composites(Elsevier, 2025) Koppad, P.G.; Joladarashi, S.; Ramesh, M.R.; Keshavamurthy, R.It is well known that the technical function of a large number of engineering components/parts depends on motion. However, the term motion here is not as simple as it sounds, because it comes with consequences in the form of friction and wear. Along with lubrication, the science that deals with friction and wear is known as tribology. Therefore, it is necessary to pay more attention to tribology and acquire knowledge on the tribological behavior of materials, as the tribological characteristics such as friction and wear have been causing poor efficiency in engineering structures, huge economic losses, and environmental impacts. One way of addressing these issues lies in the development of lightweight materials based on metals such as aluminum and magnesium. Although one cannot employ these metals in their pure form, but modification in their microstructure and properties can certainly address the needs required for tribological applications. Keeping this in mind, this chapter covers the properties of aluminum and magnesium metals, basic aspects of tribology and most importantly, the work carried out on the friction and wear behavior of aluminum- and magnesium-based composites. The importance of this chapter lies in promoting better knowledge of the tribological behavior of aluminum and magnesium composites, especially from a various wear parameters point of view. The influence of material composition and wear parameters on tribological behavior is covered with a follow-up section on numerical and optimization methods employed for predicting tribological characteristics. © 2026 Elsevier Inc. All rights reserved..Item Effect of surface treatment on wetting behavior of copper(Elsevier Ltd, 2019) Kalgudi, S.; Pavithra, G.P.; Prabhu, N.K.; Koppad, P.G.; Venkate Gowda, C.; Satyanarayan, S.Super-hydrophobic surfaces are very useful in cleaning activities. Surfaces with water contact angles above 150° are regarded as superhydrophobic surfaces. In the present study an attempt has been made to achieve superhydrophobicity on copper substrate by electrochemical etching and electro-deposition of Co-Ni alloy and Co-Ni-Graphene composite. A contact angle of about 105° was obtained on Cu surface with electro-deposited Co-Ni alloy and on electro-deposited Co-Ni-G alloy contact angle was found to be 106°. The contact angle was significantly higher at about 142° with electro etched surface. Corrosion test was carried out with electrochemically etched Cu. Electrochemical etching time was varied from 30 to 240 min. The electro-etched Cu substrate etched for 60 min. showed better corrosion resistance with a corrosion rate of 0.197 mm/year. The surface topography of both etched and electrodeposited samples was studied by atomic force microscopy (AFM) and the results were correlated with the wettability data. © 2019 Elsevier Ltd.Item A review of various materials for additive manufacturing: Recent trends and processing issues(Elsevier Editora Ltda, 2022) Srivastava, M.; Rathee, S.; Patel, V.; Kumar, A.; Koppad, P.G.Tremendous growth has been witnessed in the field of additive manufacturing (AM) technology over the last few decades. It offers a plethora of applications and is already being utilized in almost every sphere of life. Owing to inherent differences between each AM technique, newer fields of research consistently emerge and demand attention. Also, the innovative applications of AM open up newer challenges and thus avenues for focused attention. One such avenue is AM materials. Raw material plays an important role in determining the properties of fabricated part. The type and form of raw material largely depend on the type of AM fabricators. There is a restriction on material compatibility with most of the established AM techniques. This review aims to provide an overview of various aspects of AM materials highlighting the progress made especially over the past two decades. © 2022 The Author(s).Item HVOF sprayed Ni3Ti and Ni3Ti+(Cr3C2+20NiCr) coatings: Microstructure, microhardness and oxidation behaviour(Elsevier Ltd, 2018) Reddy, N.C.; Kumar, B.S.A.; Reddappa, H.N.; Ramesh, M.R.; Koppad, P.G.; Kord, S.This paper reports the development of Ni3Ti and Ni3Ti+(Cr3C2+20NiCr) coatings on AISI 420 stainless steel (MDN-420) and titanium alloy ASTM B265 (Ti-15) by HVOF technique. Microstructure, microhardness and high temperature oxidation behaviour of coatings were investigated. Microstructure of coatings was dense and displayed layers depicting lamellar structure. The microhardness of coatings was significantly higher than that of substrate owing to higher density and cohesive strength between individual splats of coating materials. Cyclic oxidation studies conducted on Ni3Ti and Ni3Ti+(Cr3C2+20NiCr) coatings showed oxide scale was composed of various oxides like NiO, NiCr2O4 and Cr2O3 phases. The formation of compact and protective NiO phase in case of Ni3Ti coatings; NiO and Cr2O3 phases in Ni3Ti+(Cr3C2+20NiCr) coatings stabilised the weight gain exhibited slow oxidation rate at higher temperatures. © 2017 Elsevier B.V.Item Microstructure and Adhesion Strength of Ni3Ti Coating Prepared by Mechanical Alloying and HVOF(Pleiades Publishing compmg@maik.ru, 2018) Reddy, N.C.; Ajay Kumar, B.S.; Ramesh, M.R.; Koppad, P.G.In the present work we report the development of Ni3Ti intermetallic compound by high energy ball milling of Ni and Ti powders. The ball milled powders were taken at various intervals (4, 6, 8, 10, and 11 h) to analyze the formation of NixTix intermetallic compounds. The ball milled powders were analyzed using scanning electron microscopy and X-ray diffraction. The layered shaped powder particles of Ni3Ti phase were formed after 11 h of ball milling, which was confirmed by X-ray peaks. Further High-Velocity Oxy-Fuel (HVOF) process was used to coat Ni3Ti and Ni3Ti + (Cr3C2 + 20NiCr) on MDN 420 steel. Both the coated materials displayed excellent cohesion with minimal porosity less than 2%. The tensile adhesion strength test was carried out on these coatings to check the bond strength. Out of the two the Ni3Ti coating showed excellent bond strength of 41.04 MPa compared to that of Ni3Ti + (Cr3C2 + 20NiCr) coating. © 2018, Pleiades Publishing, Ltd.Item Microstructure and tribological characteristics of APS sprayed NiCrBSi/flyash cenosphere/Cr2O3 and NiCrBSi/flyash cenosphere/Mo composite coatings at elevated temperatures(Institute of Physics Publishing helen.craven@iop.org, 2019) Nagabhushana, N.; Rajanna, S.; Mathapati, M.; Ramesh, M.R.; Koppad, P.G.; Reddy, N.C.In the present investigation NiCrBSi/flyash/Cr2O3 and NiCrBSi/flyash/Mo composite coatings are developed using atmospheric plasma spray technique on superni 76 alloy. Coatings are characterized in terms of microstructure, phase analysis, and microhardness. Tribological properties of the coatings are evaluated using a pin on disc tribometer. Test is conducted under dry sliding conditions at room temperature, 200 °C, 400 °C, and 600 °C respectively. Microstructure and worn surfaces of the coatings are analyzed by utilizing Scanning Electron Microscope (SEM) where in phase analysis is carried out using x-ray diffractometer (XRD). XRD results revealed the presence of ?-Ni as primary phase along with Ni3B, Cr7C3, SiO2 and Al2O3 as minor phases in both the NiCrBSi/flyash/Cr2O3 and NiCrBSi/flyash/Mo coatings. Among the two coatings, Mo composite coating exhibited lower porosity and higher microhardness. The friction coefficient of both the coatings decreased with increasing temperature. The wear rate is found to decrease at lower temperatures but increased at a higher temperature (>400 °C) for Cr2O3 composite coating wherein Friction coefficient is decreased with increase in the temperature for Mo composite coatings. The worn surface analysis conducted revealed abrasive wear at lower temperatures while the transition from abrasive to adhesive is observed at higher temperatures. © 2019 IOP Publishing Ltd.Item Hot corrosion behaviour of HVOF sprayed Ni3Ti and Ni3Ti + (Cr3C2 + 20NiCr) coatings in presence of Na2SO4-40%V2O5 at 650 °c(IOP Publishing Ltd custserv@iop.org, 2019) Reddy, N.C.; Koppad, P.G.; Reddappa, H.N.; Ramesh, M.R.; Babu, E.R.; Varol, T.Ni3Ti and Ni3Ti + (Cr3C2 + 20NiCr) coatings were deposited on gas turbine based ASTM B265 titanium (Ti-15) and AISI 420 stainless steel (MDN-420) substrate materials using HVOF technique. Thermocyclic hot corrosion tests were carried out at 650 °C in molten salt environment of Na2SO4-40%V2O5 for about 50 cycles. Thermogravimetric analysis was carried out to study the hot corrosion kinetics of uncoated and coated titanium and stainless steel substrates. The weight gain per unit area showed that the coated substrate materials displayed better resistance to hot corrosion when compared with that of uncoated substrate materials. The surface morphology of uncoated and coated substrate materials were analysed using scanning electron microscopy and elemental analysis. The formation of different types of oxides and compounds were analysed using x-ray diffraction. The uncoated substrates surface showed microspalling at several regions while coated substrates surface were composed of protective oxide layers. The presence of ternary NiCr2O4 protective oxides on the surface of Ni3Ti + (Cr3C2 + 20NiCr) coated substrates leads to reduction in the diffusion of corrosive species inside the coating. © 2019 IOP Publishing Ltd.Item Microstructure, mechanical and wear properties of the A357 composites reinforced with dual sized SiC particles(Elsevier Ltd, 2019) Avinash, A.; Bontha, S.; Krishna, M.; Koppad, P.G.; Ramprabhu, T.Current work reports on the development of A357 alloy composite which is reinforced with dual size SiC particles by stir casting route. Influence of different weight fractions (3% coarse+ 3% fine, 4% coarse + 2% fine, and 2% coarse + 4% fine) of dual size SiC particles on mechanical properties and wear resistance of A357 composites is the focus of this work. Hardness and tensile properties were studied for dual size composites and then were compared with A357 alloy. Microstructural study, fractured surface and worn surface investigation were carried out using optical and scanning electron microscopes respectively. Microstructural analysis showed fairly uniform dispersion of dual size SiC particles in A357 matrix with good interfacial bonding. Compared to A357 alloy, the composites showed improvement in hardness, yield, and tensile strength. In particular, composite with 4 wt. % of fine and 2 wt. % of large SiC particles displayed the highest tensile strength while composite with 4 wt. % of large and 2 wt. % of fine SiC particles exhibited high hardness and wear resistance among A357 alloy and dual particle size composites. The strengthening mechanisms that contributed to improvement in strength values were effective load transfer and dislocation strengthening due to thermal mismatch. © 2019 Elsevier B.V.Item The effect of heat treatment on the mechanical and tribological properties of dual size SiC reinforced A357 matrix composites(Elsevier Editora Ltda, 2020) Avinash, A.; Prabhu, T.R.; Babu, U.S.; Koppad, P.G.; Gupta, M.; Krishna, M.; Bontha, S.In the present work, the effect of aging temperature and particle size ratio of SiC particles on the mechanical and tribological properties of A357 composites reinforced with dual particle size SiC were investigated. The composites were prepared by melt-stirring assisted permanent mold casting technique with different weight fractions (3% coarse +3% fine, 4% coarse +2% fine, and 2% coarse +4% fine) of large and small size SiC particles. These three prepared composites are referred as DPS1, DPS2 and DPS3 composites. The solutionizing temperature was maintained constant at 540 ?C for 9 h while the aging was done at 160 ?C, 180 ?C and 200 ?C (T6 treatment) for 6 h. Optical and scanning electron microscopy studies showed fairly uniform dispersion of dual size SiC particles in A357 matrix with good interfacial bonding. High-resolution transmission electron microscopy images showed formation of uniformly dispersed needle-like phase and spherical shaped -Mg2Si precipitates under peak aging conditions. Compared to T6 treated A357 alloy, the T6 treated DPS A357 composites showed improved yield strength, tensile strength, hardness and wear resistance. Among the three composites, hardness and wear resistance of T6 treated DPS2 composite was found to be significantly higher when compared to the other two composites (DPS1 and DPS3). Ratio of large particles to small particles also seems to effect the mechanical and tribological properties. Presence of more small particles was found to be good for strength and ductility whereas more large particles were found to be good for hardness and wear resistance. © 2020 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license
