Faculty Publications
Permanent URI for this communityhttps://idr.nitk.ac.in/handle/123456789/18736
Publications by NITK Faculty
Browse
4 results
Search Results
Item Organic cation linkers polyoxomolybdate-polypyrrole nanocomposite-based supercapacitors(Springer Science and Business Media Deutschland GmbH, 2021) Muhammed Anees, P.K.; Anandan Vannathan, A.; Kella, T.; Shee, D.; Mal, S.A few new hybrid electrode materials have been synthesized and immobilized for the next-generation energy storage device. The hybrid electrodes PVMo11-TBA, PVMo11-BTA, PVMo11-TBP, PVMo11-TBA-PPy, PVMo11-BTA-PPy, and PVMo11-TBP-PPy were well characterized by NMR, XRD, FTIR, FESEM, BET, and tested for electrochemical performance. Among these hybrid electrode materials, the PVMo11-TBA-PPy electrode shows a high specific capacitance of 144.37 F/g at a 1A/g current density and incredible power and energy density of 1100.16 W/kg and 15.28 Wh/kg, respectively. The high electrode’s capacitance was due to the synergistic effect between the PPy and TBA-PVMo11 and high ionic diffusion compared with other synthesized electrodes. It also exhibited high cycle stability of 72.78% after 4500 cycles at 1 M H2SO4 electrolyte. The EIS offers a lower ESR value of 0.72 ohms for the PVMo11-TBA-PPy than PVMo11-TBA, indicating the rapid charge/discharge rate. On the other hand, the PVMo11-BTA-PPy and PVMo11-TBP-PPy electrodes showed lower capacitance values of 26.98 and 19.53. F/g at 0.4 and 1 A/g current density, respectively. Lowering the capacitance could be the prevention of the interaction of organic cations with the counter polyanion. © 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.Item Electrochemical performance of activated carbon-supported vanadomolybdates electrodes for energy conversion(Elsevier Ltd, 2021) Maity, S.; Anandan Vannathan, A.; Kella, T.; Shee, D.; Das, P.P.; Mal, S.Reinforcing polyoxomolybdates (POMs) into the activated carbon (AC) template engenders a nanohybrid electrode material for high-performance supercapacitor applications. Herein, a first-time novel integration of two polyoxometalates ([PVMo11O40]4-, [PV2Mo10O40]5-) with AC has been demonstrated, and their structural and electrochemical performances were analyzed. AC-VMo11 composite displayed an enhanced capacitance of 450 Fg-1 with an improved energy density of 59.7 Whkg-1. Furthermore, the symmetric supercapacitor cell for AC-VMo11 and AC-V2Mo10 showed high cell capacitances of 38.8 and 20.01 mF, respectively, alongside 99.99% capacitance retention of over 5000 cycles. In addition, the influence of ionic liquid as an electrolyte on AC-V2Mo10 based supercapacitor cell was investigated in tetrabutylammonium bromide (TBAB) electrolyte solution. © 2021 Elsevier Ltd and Techna Group S.r.l.Item Imidazolium cation linkers of polyoxomolybdate-polypyrrole nanocomposite electrode-based energy storage supercapacitors(Elsevier Ltd, 2022) Muhammed Anees, P.K.; Anandan Vannathan, A.A.; Abhijith, M.B.; Kella, T.; Shee, D.; Mal, S.S.The electrochemical properties of a new hybrid electrode, liquid-polyoxometalate-polypyrrole (BMIM-PVMo11-PPy) have been studied. The H4[PVMo11O40] (PVMo11) was combined with 1-Butyl-3-methyl-imidazolium (BMIM) ionic liquid and then doped on the polypyrrole (PPy) surface. In order to investigate the interaction between the BMIM, PVMo11, and PPy compound was characterized using various analytical techniques, such as Infrared spectroscopy, thermal stability analysis, powder X-ray diffraction, multinuclear NMR (1H and 13C), FESEM, EDX, and surface adsorption studies. The electrochemical performance of the BMIM-PVMo11-PPy composite material has been tested in an aqueous 0.25 M H2SO4 electrolytic solution. The BMIM-PVMo11-PPy composite exhibits the highest specific capacitance of 527.39 F g−1 at a current density of 1 A g−1, along with remarkable specific energy and power of 51.07 Wh kg−1 and 1078.96 W kg−1, respectively. The BMIM-PVMo11-PPy composite was observed to light up red and blue color LED bulbs for 66 and 16 s, respectively, with 84 mg of sample coated on carbon cloth, suggesting an incredible specific power of that material. © 2021 Elsevier B.V.Item Investigations of redox-active polyoxomolybdate embedded polyaniline-based electrode material for energy application(Springer Science and Business Media Deutschland GmbH, 2022) Anandan Vannathan, A.A.; Kella, T.; Shee, D.; Mal, S.S.Higher capacitance supercapacitors have received considerable attention, including their massive power density, high stability, and long cycle life. On the other hand, polymers have been known for their energy storage device application because of the pseudocapacitance behavior resulting from the extended conjugation over the polymer backbone. Here, we report a simple chemical bath deposition method for the synthesis of two polyoxometalates (H4[PVMo11O40] and H5[PV2Mo10O40]) impregnated polyaniline (PAni) composite (PVMo11@PAni and PV2Mo10@PAni) for electrochemical supercapacitors. Various analytical methods characterized the electrode materials, e.g., Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) method, and the morphological features of those electrodes were acquired by field emission scanning microscopy (FESEM). The exceptionally high average capacitance of 1371 F g−1 was obtained for the composite PVMo11@PAni electrode at a 3 A g−1 current density and 1 V potential window with an energy density of 137.5 W h kg−1. The PVMo11@PAni composite electrode showed almost 4.3 times the higher energy density than pure PAni and 2.3 times higher than PV2Mo10@PAni. In contrast, PV2Mo10@PAni composite showed 1.9 times more energy density than pure PAni composite electrode. Interestingly, high average capacitance, charge–discharge rates, and high energy density with high-level power delivery make them promising electrode candidates for supercapacitors. © 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.