Faculty Publications

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    TiO2 nanosheet incorporated polysulfone ultrafiltration membranes for dye removal
    (Desalination Publications dwt@deswater.com, 2018) Nair, A.K.; Kumar, B.V.; Kalaiarasan, G.; JagadeeshBabu, J.B.
    Incorporation of nanomaterials in polymeric membranes is an effective means to improve membrane performance. In the present work, a novel additive TiO2 nanosheet was incorporated in polysulfone membrane. TiO2 nanosheets were synthesised by hydro-thermal method and blended with polysulfone to give nanocomposite membranes. The membranes performance was evaluated via pure water flux, bovine serum albumin rejection and anti fouling studies. Further the membranes were subjected to dye rejection application using Congo red and Rhodamine-B dyes. The membranes were characterised using scanning electron microscopy; X-ray diffraction and contact angle measurement. The nanocomposite membranes exhibited superior permeation, anti fouling and dye rejection traits. © 2018 Desalination Publications. All rights reserved.
  • Item
    Synthesis, Characterization and Performance Evaluation of TiO2-SnO2 photocatalyst for Removal of Toxic Hexavalent Chromium
    (Springer Science and Business Media Deutschland GmbH, 2022) Rathna, T.; JagadeeshBabu, J.B.; Ruben Sudhakar, D.R.
    Heavy metal pollution bears a substantial threat to flora, fauna, humans, and milieu. The elimination of hexavalent chromium [Cr(VI)] from polluted water is of considerable research interest from a health and environmental viewpoint. This work aims for photocatalytic reduction of Cr(VI) to Cr(III) using TiO2 and SnO2 as catalysts. The process parameters varied are catalyst dosage, pH, initial concentration of model pollutant with citric acid (CA) as a scavenger. TiO2-SnO2 (in the molar ratios 10:1, 20:1, 30:1, and 40:1)-based catalysts were synthesized using the hydrothermal method. The 40:1 catalyst showed higher photoactivity than other catalysts and could extend the optical activity in the visible light region. The complete reduction of Cr(VI) with a concentration of 15 mg/L and pH 3.0 was achieved when catalyst concentration was 0.6 g/L over a period of 30 min. The XRD (X-Ray Diffraction Spectroscopy) and ATR-FTIR (Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy) results confirm the Ti-Sn heterojunction formation, and XPS (X-ray Photoelectron Spectroscopy) analysis corroborate the presence of trivalent chromium [Cr(III)] on TiO2-SnO2 catalyst after reduction. © 2022, The Author(s), under exclusive licence to Springer Nature Switzerland AG.