Faculty Publications

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Author: search.filters.author.Hegde, S.Subject: search.filters.subject.bioremediation

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    Surface treated Pteris vittata L. pinnae powder used as an efficient biosorbent of Pb(II), Cd(II), and Cr(VI) from aqueous solution
    (Taylor and Francis Inc. 325 Chestnut St, Suite 800 Philadelphia PA 19106, 2018) Prabhu, S.G.; Srinikethan, G.; Hegde, S.
    Biosorption is a surface-dependent phenomenon. Surface modifications by chemical treatment methods could either improve or reduce the biosorption capacity of potential biosorbents. In the present work, pristine Pteris vittata L. pinnae (PPV) powder was treated separately with sodium hydroxide (NaOH), calcium chloride (CaCl2), and nitric acid (HNO3). The pristine and treated biosorbents were used to assess the biosorption of Pb(II), Cd(II), and Cr(VI) as a function of pH. Kinetics and adsorption isotherms were studied. Attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy and scanning electron microscope combined with energy dispersive x-ray (SEM-EDX) spectroscopic techniques were used to characterize the biosorbents before and after chemical treatments. The possible functional groups contributing to the metal sorption were identified. Results revealed favorable biosorption of Pb(II), Cd(II), and Cr(VI) described by pseudo-second order kinetics. NaOH-treated P. vittata (NPV) showed higher biosorption capacity for Pb(II) and Cd(II) compared to that of PPV. ATR-FTIR studies indicated that -OH, -COOH, and -NH2 groups were mainly involved in Cr(VI) and -OH in Pb(II) and Cd(II) biosorption. The enhanced efficiency of NPV and CaCl2 treated P. vittata (CPV) in the uptake of Pb(II) and Cd(II) compared to PPV can be associated with their altered physicochemical characters. © 2018, © 2018 Taylor & Francis Group, LLC.
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    Spontaneous Cr(VI) and Cd(II) biosorption potential of native pinnae tissue of Pteris vittata L., a tropical invasive pteridophyte
    (Taylor and Francis Inc. 325 Chestnut St, Suite 800 Philadelphia PA 19106, 2019) Prabhu, S.G.; Srinikethan, G.; Hegde, S.
    Heavy metal pollution is a prevalent and critical environmental concern. Its rampancy is attributed to indiscriminate anthropogenic activities. Several technologies including biosorption have been continuously researched upon to overcome the limitations of the conventional method of treatments in removal of heavy metals. Biosorption technology involves the application of a biomass in its nonliving form. Pteris vittata L., a pteridophyte, considered as an invasive weed was investigated in the present study as a potential decontaminant of toxic metals, Cr(VI) and Cd(II). The adsorption capacity of the biosorbent for Cr(VI) and Cd(II) under equilibrium conditions was investigated. The morphology, elemental composition, functional groups, and thermal stability of the biosorbent before and after metal loading were evaluated. At 303 K and an equilibrium time of 120 min, the maximum loading of Cr(VI) on the biosorbent was estimated to be 166.7 mg/g at pH 2 and Cd(II) to be 31.3 mg/g at pH 6. Isotherm models, kinetic studies, and thermodynamic studies indicated the mechanisms, chemisorption, ion exchange and intraparticle diffusion, controlling the Cr(VI) and Cd(II) uptake, respectively. The interactive effect of multi-metal ions in binary component systems was synergistic for Cd(II) uptake. The results validate the toxic metal removal potency of the biosorbent. © 2019, © 2019 Taylor & Francis Group, LLC.