Faculty Publications

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    Microstructural evolution and cyclic oxidation behavior of HVOF-sprayed NiCrSi and NiCrC coatings on T11 steel
    (Elsevier Inc., 2024) Medabalimi, S.; Hebbale, A.M.; Singh, R.; Desai, V.; Ramesh, M.R.
    This study analyzes NiCrSi and NiCrC coatings developed on low alloy ferritic stainless steel (grade T11) through the HVOF spraying technique. The coatings were characterized by their phase constitution, microstructure, cyclic oxidation behavior, and hardness. X-ray diffraction (XRD) analysis confirmed the presence of the NiCr solid solution matrix as the primary phase in both coatings. Moreover, the microstructure of the NiCrSi coating included the hard intermetallic compounds like Cr?Si and Ni?Si and the NiCrC coating contained the hard phases like Cr?C? and Ni?C which improved the hardness and the wear resistance of the coatings. Microhardness measurements revealed that the coatings had an average hardness of 300 ± 50 HV, significantly greater than the substrate hardness of 225 ± 25 HV. Cyclic oxidation tests were carried out at 700 °C revealed that both the coatings showed a lower weight gain than the uncoated substrate, suggesting enhanced oxidation resistance. This was because the protective oxide layers like Cr?O? and SiO? in the NiCrSi coating and Cr?O? and NiO in the NiCrC coating were formed. X-ray analysis establish ed. the presence of these oxides, which inhibited oxygen penetration through the coatings and provided additional protection against oxidation. Therefore, the study revealed that both NiCrSi and NiCrC coatings have good mechanical and oxidation resistance properties, which make them suitable for high-temperature applications where there is a need for improved durability, wear resistance, and protection against oxidation. © 2024
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    Microstructure and elevated temperature wear behavior of HVOF-sprayed SS304L stainless-steel coating
    (Springer Nature, 2025) Medabalimi, S.; Gudala, S.; Rokkala, U.; Hebbale, A.M.; Ramesh, M.R.
    The paper aims to investigate the performance of the SS304L stainless steel coating on wear properties by varying load, temperature and velocity. Stainless-steel coatings were fabricated by high-velocity oxy-fuel spraying (HVOF) on superfer800. Surface morphology, elemental distribution and phase analysis were expressed by SEM, EDS, and XRD, respectively. The porosity, average surface roughness, and average microhardness of HVOF stainless steel coating are 2%, 7 µm, and 1167 ± 54 HV0.3, respectively. The wear rate of stainless-steel coating is 0.5 × 10?3 mm3/m at 600 °C with 20 N loads, which is about 16 times lower than the substrate. Adhesion and abrasion are the main wear mechanisms of HVOF stainless steel coatings during high-temperature tests. Comparing to superfer800 substrate, stainless steel coatings showed superior wear resistance at all the loads, temperature and velocities. © The Author(s) 2025.
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    Studies on high-temperature erosion behaviour of HVOF sprayed NiCr based composite coatings
    (Elsevier B.V., 2025) Medabalimi, S.; Hebbale, A.M.; Gudala, S.; Ramesh, M.R.; Gujar, R.; Aravindan, N.; Petr?, J.
    Solid particle erosion at high temperature is a major problem in many industries and advanced protective coatings are needed to extend the service life of components subjected to harsh environment. The main objective of this study is to investigate the erosion behavior of HVOF sprayed (NiCr) + 5 % Si and (NiCr)+ 2% C based composite coatings at different impact angles and temperature, with specific emphasis on the effect of coating composition. The coatings exhibited excellent erosive wear resistance at elevated temperatures due to the formation of stable oxide layers (CrO, NiCr?O?, SiO?) and the incorporation of silicide phases (Ni?Si) to the NiCrSi coatings. However, NiCrC coatings containing hard carbide phases (such as NiC) showed higher erosion resistance at higher temperatures and normal impact angles (90°) because of their robust microstructure and thermal stability. The analysis of microhardness indicated that NiCrSi coatings provided higher hardness attributable to silicides and were therefore better suited to moderate erosive environments, whereas NiCrC coatings, with slightly lower hardness, exhibited excellent resilience under severe erosive environments. SEM, EDAX and XRD analyses showed that preferential erosion mechanisms were cutting and plowing at oblique angles (30°) and brittle fracture at normal angles (90°). Notably, at 800 °C, NiCrC coatings outperformed the NiCrSi coatings via consistently superior thermal and erosion resistance. These findings indicate that HVOF sprayed NiCrC coatings are suitable for high temperature erosion protection, and NiCrSi coatings are specifically developed for high erosive wear resistance at low impact angles. © 2025 The Author(s)