Faculty Publications

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    Evolution of Microstructure and High-Temperature Tribological Performance of Self-Lubricating Nickel-Based Composite Tungsten Inert Gas Coatings
    (Springer, 2021) Gudala, S.; Ramesh, M.R.; Siva Shanmugam, S.S.
    The present study aims to assess the effect of Ag/BaF2 solid lubricant encapsulation in the nickel-based composite coatings for high-temperature tribological applications. The composite coatings (NiCrSiB/WC and NiCrSiB/WC/Ag/BaF2) have successfully been fabricated on the titanium 31 substrate by tungsten inert gas (TIG) cladding technique. The influence of the TIG processing current on the microstructure, microhardness, and fracture toughness was investigated. Mechanical characteristics of the coatings were further correlated with the microstructural morphologies. The coating fabricated at 70 A exhibited significantly higher hardness than other coatings. The tribological performances of the NiCrSiB/WC/Ag/BaF2 composite coatings were superior to those of the NiCrSiB/WC coatings at both low (200 °C) and high (600 °C) temperatures. The synergistic lubrication effect of the Ag/BaF2 solid lubricant combination provided lubrication at a wide range of temperatures. The addition of these solid lubricants in the nickel-based coating helped achieve the low coefficient of friction of 0.2 and lower wear rates. Particularly, oxide phases (such as NiO, TiO, Ni3Ti3O, and W3O) formed on the worn surface at 600 °C, and the lubricant phases (Ag, Ag2F, and Ba (TiO3)) provided excellent resistance to wear. © 2021, ASM International.
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    Development of Self-lubricating Nickel Based Composite Clad using Microwave Heating in Improving Resistance to Wear at Elevated Temperatures
    (Korean Institute of Metals and Materials, 2022) Gudala, S.; Ramesh, M.R.; Srinath, M.S.
    This paper reports on a study of the high-temperature tribological performance of self-lubricating nickel-based composite clad. A porous and crack free clad containing matrix, reinforcement, and lubricant phase is developed on titanium 31 alloy using microwave irradiation. The microstructure of both NiCrSiB/WC and NiCrSiB/WC/Ag/BaF2 clad revealed very good metallurgical bonding with the substrate. The average microhardness of NiCrSiB/WC and NiCrSiB/WC/Ag/BaF2 clad is 710.58 HV and 650.25 HV respectively, is comparatively higher than the titanium 31 substrate (320 HV). The addition of Ag and BaF2 solid lubricants in the clad endowing clad to operate at a broad temperature range. Compared with the NiCrSiB/WC clad, solid lubricant encapsulate clad has shown very low friction coefficient and wear rates. The sliding wear characteristics of the clad were investigated by varying load and temperatures. The results revealed that oxide phases (NiO and Cr3O) and lubricant phases (Ag and BaWO4) formed at low and high temperatures are adequate to reduce delamination and material loss. Graphical abstract: [Figure not available: see fulltext.] © 2021, The Korean Institute of Metals and Materials.
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    MICROSTRUCTURE AND TRIBOLOGICAL PERFORMANCE OF SELF-LUBRICATE CLADDING PRODUCED BY TUNGSTEN INERT GAS AND MICROWAVE HYBRID HEATING TECHNIQUES
    (World Scientific, 2022) Gudala, S.; Ramesh, M.R.; Siva Shanmugam, N.S.; Srinath, M.S.
    The wear reduction of moving components is highly desirable because wear limits their reliability and service life, mainly at elevated temperatures. This study produced thick clads of NiCrSiB/WC/MoS2/BaF2 by tungsten inert gas (TIG) and microwave hybrid heating (MHH) cladding techniques, which were compared for microstructural and high-temperature tribological properties. The clad samples were subjected to sliding contact using a pin on disc tribometer at 200°C, 400°C, 600°C under 20 and 40N load. The worn surface was analyzed using FESEM, XRD and three-dimensional (3D) profilometer. The experimental results revealed a significant effect of the TIG current and MHH exposure time on the microhardness value, which predominantly depends on the morphological characteristics. The average hardness of TIG clads was found to be 1.2 times higher than the MHH clad. Because of the MoS2 and BaF2 encapsulation, the continuous lubricant layer formation compensated for improved wear resistance with good reliability and longer service life. This work provides significant insights into the wear behavior of TIG and MHH clads at elevated temperatures and the prospective applications in turbines, where inadequate wear resistance of titanium alloy is the major concern for its use. © 2022 World Scientific Publishing Company.
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    Effect of Microwave Hybrid Heating on High-Temperature Adhesive Wear Behavior of High-Velocity Oxygen Fuel-Sprayed WC-CrC-Ni and WC-Co/NiCrFeSiB Coatings
    (Springer, 2023) Medabalimi, S.; Ananthu, M.R.; Gudala, S.; Ramesh, M.R.
    HVOF-processed coatings are chemically inhomogeneous and are not metallurgically bonded to the substrate. As a result, components coated with HVOF experience considerable material degradation during sliding wear. Microwave hybrid heating (MHH) is a novel surface modification technique for modifying the as-sprayed properties of the coating. Hence, this paper investigates and compares the wear and frictional behavior of HVOF as-sprayed coatings against MHH samples of WC-CrC-Ni and WC-Co/NiCrFeSiB coatings at elevated temperatures. MHH had a significant impact on wear rate and coefficient of friction by optimizing the porosity, integrated oxide phases and intersplat cohesion strength of the coatings. A modified domestic oven was used to perform MHH on HVOF-coated samples for 5 min at 1200 °C. Wear tests were performed using a pin-on-disk tribometer from room temperature to 200, 400, and 600 °C with Al2O3 disk as a counterface. SEM/EDS and XRD were utilized to examine the microstructural characterization of the coatings and substrate. Both the coatings showed higher wear resistance than the substrate at all temperatures. The WC-Co/NiCrFeSiB coating produced an oxide layer on the worn surfaces and integrated WC, CoWO4, and Fe2SiO4 splats, enhancing wear resistance. The MHH WC-CrC-Ni coating formed Cr2O3 and NiWO4 phases on the worn surfaces, increasing the intersplat cohesion strength between matrix and carbide splats, lowering the overall wear rate. After MHH, the wear rate of a substrate and WC-CrC-Ni coating was 3.5 and 1.12 times more at room temperature and 8.07 and 2.92 times more at 600 °C than WC-Co/NiCrFeSiB coating. © 2022, ASM International.
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    Comparative Study of Plasma Spray and Friction Stir Processing on Wear Properties of Mg-Zn-Dy Alloy
    (Springer, 2024) Rokkala, U.; Gudala, S.; Ramesh, M.R.
    Mg alloys are becoming increasingly popular as lightweight materials in recent years. Wear resistance, on the other hand, is a severe issue with Mg alloys. Plasma spray and friction stir processing (FSP) are being investigated in this context for developing composite surfaces with improved surface characteristics. Scanning electron microscopy (SEM), energy dispersive spectroscopy, and x-ray diffraction are used to examine the microstructural changes and phase changes of all materials. After FSP, SEM analysis indicated that the coated particles were equally dispersed throughout the Mg matrix. The composite samples had the lowest wear rate as compared to other samples, according to the wear tests. In comparison to AC, the F-1 sample surface has much higher wear resistance. As a consequence, the findings of this investigation for the F-1 sample appear encouraging for biological wear resistant applications. © ASM International 2023.
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    Effect of dilution on the microstructure and high-temperature wear resistance of self-lubricating nickel alloy claddings
    (SAGE Publications Inc., 2024) Gudala, S.; Rokkala, U.; Rao Medabalimi, S.; M.r, R.; Konovalov, K.S.
    In this study, the impact of substrate dilution on the microstructure and tribological properties of tungsten inert gas (TIG)-deposited self-lubricating claddings was investigated. The dilution of Ti content on cladding increased as the TIG current increased, and the microhardness of the cladding decreased. The content of intermetallic phases such as TiNi and TiC increased with the increase in TIG current. The tribological studies revealed that coating dilution at higher TIG currents has prominent effects on wear behaviour at elevated temperatures. In both clads, the percentage decrease in hardness from higher TIG current to lower TIG current was noted as 31%. The higher dilution of Ti content in the cladding was found to be beneficial in tribological studies performed, especially at higher temperatures (≥400). Also, solid lubricants such as MoS2 and BaF2 encapsulation in the nickel alloy were found to be beneficial at both low and high temperatures. © The Author(s) 2024.