Faculty Publications
Permanent URI for this communityhttps://idr.nitk.ac.in/handle/123456789/18736
Publications by NITK Faculty
Browse
11 results
Search Results
Item Role of Rare Earth Oxide Reinforcements in Enhancing the Mechanical, Damping and Ignition Resistance of Magnesium(Springer, 2019) Kujur, M.S.; Manakari, V.; Parande, G.; Doddamani, M.; Mallick, A.; Gupta, M.Magnesium based nanocomposites, on account of their excellent dimensional stability coupled with mechanical integrity, have provided the much-needed impetus for utilization in both aerospace-related and automobile-related applications. However, the perceived easy ignition and flammability of magnesium alloys create a detrimental safety feature that hinders the aerospace application opportunities. Incorporation of rare earth metal oxides into magnesium matrix can induce ‘reactive element effect’ (REE), due to their strong rare earth–oxygen interactions. Along with enhancing the protective characteristics of oxides on many metals and alloys, the addition of such rare earth oxides also helps in realizing a refined microstructure and good strength–ductility combination in the composites. This manuscript presents the mechanical properties, damping and ignition resistance characteristics of the new and improved composite materials engineered by reinforcing magnesium with rare earth oxide nanoparticle. Rationale for the observed properties is discussed while concurrently establishing the relationship between microstructure of the engineered composites and resultant mechanical properties. © 2019, The Minerals, Metals & Materials Society.Item Extracting elastic modulus at different strain rates and temperatures from dynamic mechanical analysis data: A study on nanocomposites(Elsevier Ltd, 2019) Xu, X.; Koomson, C.; Doddamani, M.; Behera, R.K.; Gupta, N.Viscoelastic nature of polymers makes their properties strongly dependent on temperature and strain rate. Characterization of material properties over a wide range of strain rates and temperatures requires an expensive and time consuming experimental campaign. While viscoelastic properties of materials are widely tested using dynamic mechanical analysis (DMA) method, the frequency dependent component of the measured properties is underutilized due to a lack of correlation between frequency, temperature, and strain rate. The present work develops a method that can extract elastic modulus over a range of strain rates and temperatures from the DMA data for nanocomposites. Carbon nanofiber (CNF) reinforced high-density polyethylene (HDPE) matrix nanocomposites are taken as the study material. Four different compositions of CNF/HDPE nanocomposites are tested using DMA from 40 to 120 °C at 1–100 Hz frequency. First, time-temperature superposition (TTS) principle is used to develop an extrapolation for the results beyond the test parameter range. Then the TTS curve is transformed to a time domain relaxation function using integral relations of viscoelasticity. Finally, the strain rate sensitive elastic modulus is extracted and extrapolated to room temperature. The transform results are validated with tensile test results and the error found to be below 13.4% in the strain rate range 10?5 to 10?3 for all four nanocomposites. Since the materials are tested with the aim of finding a correlation among the test methods, the quality of the material is not a study parameter and the transform should yield accurate results for any material regardless of composition and quality. © 2018 Elsevier LtdItem Mechanical behavior of additively manufactured nanoclay/HDPE nanocomposites(Elsevier Ltd, 2020) Beesetty, P.; Kale, A.; Patil, B.; Doddamani, M.Nanoclay (NC) has blended with relatively inexpensive, widely consumed HDPE (high density polyethylene) for the development of filament to be used in 3D printers. NC/HDPE blends are prepared by varying NC wt. % (0.5, 1, 2, and 5) and are subjected to melt flow index (MFI) measurements. MFI has noted to be decreasing with NC loadings. NC/HDPE nanocomposite blends are further extruded using a single screw extruder. Developed nanocomposites filaments are fed to the fused filament fabrication (FFF) based 3D printer for realizing NC/HDPE nanocomposite prints. The density of printed sample increases with filler content. Filament and printed samples thermal study is carried out using differential scanning calorimeter (DSC). NC addition increases crystallinity and crystallization temperature without significant change in melting peak temperature. Freeze fractured prints reveal the uniform distribution of NC in HDPE. The tensile test is conducted on the filaments and prints. Further printed nanocomposites are subjected to flexural investigations. Tensile modulus and strength of filament increase with NC additions in HDPE matrix. Tensile and flexural properties (modulus and strength) of the nanocomposite prints increases with NC content. Finally, results obtained from the tensile and flexural tests of prints are compared with different HDPE composites available in the literature. © 2020 Elsevier LtdItem Mechanical characterization of 3D printed MWCNTs/HDPE nanocomposites(Elsevier Ltd, 2022) Kumar, S.; Ramesh, M.R.; Doddamani, M.; Rangappa, S.M.; Siengchin, S.The development of polymer nanocomposite blends using multi-walled carbon nanotubes (MWCNTs) and high-density polyethylene (HDPE) is presented in this paper. Fused Filament Fabrication (FFF) based 3D printer is used to realize MWCNT (0.5, 1, 3, and 5 by wt. %)/HDPE nanocomposite (NC) 3D printed samples. The addition of MWCNT increases TCryst, αCryst and TMelt. Thermogravimetric analysis (TGA) of neat HDPE and MWCNT/HDPE NCs is also carried out to check their thermal stability at higher working temperatures. The degradation temperature of MWCNT/HDPE NCs is observed to be higher than neat HDPE and increasing with MWCNT content. The filaments are tested for tensile, while specimens are tested for both tensile and flexural properties. It is observed that tensile and flexural modulus and strength improve with increasing MWCNT. Finally, the results of the tensile tested specimens are compared to those of various HDPE composites found in the literature. © 2022Item Compressive behavior of 3D printed MWCNT/HDPE nanocomposites(Elsevier Ltd, 2022) Kumar, S.; Ramesh, M.R.; Doddamani, M.The current work investigates the compressive behavior of three-dimensional (3D) printed functionalized MWCNTs (multi-walled carbon nanotubes)/HDPE (high-density polyethylene) nanocomposite (NC) samples. The NCs are prepared by varying functionalized MWCNTs in the proportion of 0.5–5 wt. (weight) % in HDPE through compounding. The NC pellets are further used for extruding feedstock filaments to be used in fused filament fabrication based 3D printer. The crystallinity of NC filaments and prints is higher than HDPE filaments and prints respectively. The compressive modulus, yield strength, and the peak stress of the prints are observed to be increasing, whereas the energy absorption is observed to be decreasing with functionalized MWCNTs loading. © 2022 Elsevier LtdItem Recycling potential of MWCNTs/HDPE nanocomposite filament: 3D printing and mechanical characterization(Springer, 2023) Kumar, S.; Ramesh, M.R.; Doddamani, M.Fused filament fabrication (FFF) based additive manufacturing (AM) process is a widely used and emerging manufacturing process for polymer-based products. The recycled filaments are realized through wastage generated while extruding the constant diameter feedstock filament, which is otherwise dumped in landfills or incinerated, releasing hazardous and toxic gases that influence the ecological environment. The wastage of these filaments can be eliminated by recycling and reusing them, addressing materials circular economy effectively, presented in this paper. The functionalized MWCNT reinforced HDPE (high-density polyethylene) nanocomposite (NC) is realized through a brabender, which is further used for filament extrusion. The waste/unrecycled (W/UR) and the recycled filaments are checked for quality. The density of the recycled filaments increases compared to the W/UR filament in each extrusion pass. The crystallinity and tensile properties of the recycled filaments increase compared to the W/UR filament with each additional extrusion cycle. Further, these filaments are used for 3D printing, and investigated for density, XRD and tensile tests. It is observed that the density, crystallinity and tensile properties of the recycled prints increase compared to the W/UR print. The tensile strength and modulus of 1 × , 2 × and 3 × prints are 63.82, 67.11 and 67.76%, and 45.63, 55.34 and 97.81% respectively, higher than those of the W/UR print. The highest tensile strength and modulus are observed for 3 × print which is 67.76 and 97.81% respectively, higher than those of the W/UR print. 3D prints exhibited enhanced performance as compared to their respective filaments. Finally, the present tensile results are mapped on a property chart, and compared with the available HDPE composites. © 2023, Springer Nature Japan KK, part of Springer Nature.Item Investigation on hardness, impact, and compression responses of additively manufactured functionally graded nanocomposites(Elsevier Ltd, 2023) Kumar, S.; Ramesh, M.R.; Doddamani, M.Functionally graded nanocomposites (FGNCs) are fabricated using 3D printing for hardness, impact and compression investigations with different wt. % (0.5⟶H0.5, 1⟶H1, 3⟶H3, 5⟶H5) of functionalized MWCNTs in high-density polyethylene (HDPE). Further, they are extruded as feedstock filament for 3D printing. The hardness, impact strength, and compressive properties increase while the energy absorption decreases with a % increase in the functionalized MWCNTs. The highest hardness, impact strength, compressive moduli, and strength observed for FGNC-2 (H1⟶H3⟶H5) are 76.80, 119.99, 61.14, and 11.56%, respectively, higher than HDPE. The betterment in the mechanical properties is attributed to the strengthening and stiffening effects due to the homogeneous distribution of the functionalized MWCNTs in HDPE. The FGNC-2 exhibited the highest mechanical properties, and can be used in various applications wherein variational stiffness is required. © 2023 Elsevier LtdItem Buckling and dynamic responses of 3D printed nanocomposites and their graded variants(Elsevier Ltd, 2023) Kumar, S.; Ramesh, M.R.; Jeyaraj, P.; Doddamani, M.The experimental and numerical investigations are carried out for buckling and vibration of 3D printed functionalized MWCNTs/HDPE based nanocomposite (NC) and their functionally graded nanocomposite (FGNC) variants. Pcr(critical buckling load) is computed through MBC (modified budiansky criteria) and DTM (double tangent method) techniques. It is observed that Pcr of the 3D printed NCs and FGNCs increases with the functionalized MWCNTs content. The Pcr values for the NCs (H0.5-H5) computed using DTM and MBC increased in the range of 16–79%, while for FGNC-1 (H0.5-H1-H3) and FGNC-2 (H1-H3-H5), the Pcr increased from 54 to 91% compared to HDPE. Further, it is observed that the natural frequency of the NCs and FGNCs increases with the functionalized MWCNTs loading while decreases with rise in compression. The natural frequency of the NCs (H0.5-H5) and FGNCs increased up to 41% than HDPE. The highest Pcr and the natural frequency is noted for H5 and FGNC-2 prints. The experimental and numerical results showed good agreement. © 2023 Elsevier LtdItem Buckling behavior of non-uniformly heated 3D printed plain and functionally graded nanocomposites(John Wiley and Sons Inc, 2023) Kumar, S.; Ramesh, M.R.; Jeyaraj, J.; Powar, S.; Doddamani, M.The functionalized multi-walled carbon nanotubes (MWCNTs) (0.5–5 wt.%) are compounded with high density polyethylene (HDPE), and, subsequently, used for extruding nanocomposite filaments to fabricate nanocomposites (NCs) and functionally graded nanocomposites (FGNCs) through 3D printing. The 3D printed NCs are investigated for coefficient of thermal expansion (CTE), and buckling under different non-uniform temperature distributions (case-1: left edge heating, case-2: centre heating, and case-3: left and right edge heating). A significant reduction in CTE is observed with MWCNT addition and gradation. The highest reduction in CTE is observed for H5 (5 wt.% of MWCNT in HDPE) NC and H1 ⟶ H3 ⟶ H5 (FGNC-2) among the NCs and the FGNCs. It is noted that Tcr (critical buckling temperature) is highest for case-3 and lowest for case-2. The highest deflection is noticed in case-2, while no significant difference is observed in case-1 and case-3 heating conditions. It is also observed that Tcr increases with gradation and MWCNTs addition. The H5 NC and FGNC-2 exhibited the highest Tcr among the NCs and FGNCs, respectively. The maximum deflection is noticed for HDPE, whereas the minimum deflection is noticed for FGNC-2 and H-5 NC among the tested samples. The results also revealed that Tcr is very sensitive to type of heating. © 2023 Society of Plastics Engineers.Item Fabrication and Characterization of Silicon Dioxide-Reinforced Polydimethylsiloxane Composite Coating for Corrosion Protection of Galvanized Iron(SAE International, 2024) Kumar, P.; Ramesh, M.R.; Doddamani, M.The present work highlights the significance of nanocomposite coatings for their ease of processing and applicability in combating corrosion. Ongoing research is dedicated to the development of an effective nanocomposite hydrophobic coating. A hydrophobic nanocomposite coating was deposited on galvanized iron (GI) using a sol-gel route with polymethylsiloxane (PDMS) reinforced with nano-SiO2. Surface morphology and chemical composition analysis, conducted with scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDAX) and Fourier transform infrared spectroscopy (FTIR), revealed the coating's structural and compositional attributes. The resulting hydrophobic coating exhibits a water contact angle (WCA) of 104.1°, indicating a 30.45% increase compared to bare GI. Subsequent to these characterizations, the adhesion of the coated GI, rated as 4B per ASTM D3359, is followed by commendable resistance to corrosion, as evidenced by electrochemical tests. The corrosion rate for the coated GI sheet is notably low, at 62.78 × 10-3 mpy, underscoring its anti-corrosive efficacy. © 2024 SAE International.