Faculty Publications

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    The uptake mechanism of Cd(II), Cr(VI), Cu(II), Pb(II), and Zn(II) by mycelia and fruiting bodies of Galerina vittiformis
    (Hindawi Publishing Corporation 410 Park Avenue, 15th Floor, 287 pmb New York NY 10022, 2013) Damodaran, D.; Mohan Balakrishnan, R.M.; Shetty K, K.
    Optimum concentrations of heavy metals like copper, cadmium, lead, chromium, and zinc in soil are essential in carrying out various cellular activities in minimum concentrations and hence help in sustaining all life forms, although higher concentration of these metals is lethal to most of the life forms. Galerina vittiformis, a macrofungus, was found to accumulate these heavy metals into its fleshy fruiting body in the order Pb(II) > Cd(II) > Cu(II) > Zn(II) > Cr(VI) from 50 mg/kg soil. It possesses various ranges of potential cellular mechanisms that may be involved in detoxification of heavy metals and thus increases its tolerance to heavy metal stress, mainly by producing organic acids and phytochelatins (PCs). These components help in repairing stress damaged proteins and compartmentalisation of metals to vacuoles. The stress tolerance mechanism can be deduced by various analytical tools like SEM-EDX, FTIR, and LC-MS. Production of two kinds of phytochelatins was observed in the organism in response to metal stress. © 2013 Dilna Damodaran et al.
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    Effect of chelaters on bioaccumulation of Cd (II), Cu (II), Cr (VI), Pb (II) and Zn (II) in Galerina vittiformis from soil
    (2013) Damodaran, D.; Shetty K, K.; Raj Mohan, B.
    Remediation of heavy metal contaminated soil and water streams are of great necessity as heavy metals are toxic and pose hazardous ecological impacts. Low cost mitigation measures like phytoremediation and mycoremediation are commonly employed. Mycoremediation using macro fungi (mushroom) have proven to provide effective tolerance using an efficient accumulation mechanism in removing heavy metals from soil. The current paper reports the heavy metal remediation potential of macro fungi on soil artificially contaminated with 50mgkg-1 of Cu (II), Cd (II), Cr (VI), Pb (II), and Zn (II) ions. Galerina vittiformis belonging to Strophariacea family was found to be effective in removing the heavy metal from the soil under study within 30 days. Both chemical and biological chelaters at 1, 5, and 10mmolkg-1 concentrations were found to increase the mycoremediation potential of the organism. This study showed that G. vittiformis are efficient in remediating heavy metal from contaminated soil and that their remediation potential can be enhanced by the addition of chelaters. © 2013 Elsevier Ltd.
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    Uptake of certain heavy metals from contaminated soil by mushroom-Galerina vittiformis
    (Academic Press, 2014) Damodaran, D.; Shetty K, K.; Raj Mohan, B.
    Remediation of soil contaminated with heavy metals has received considerable attention in recent years. In this study, the heavy metal uptake potential of the mushroom, Galerina vittiformis, was studied in soil artificially contaminated with Cu (II), Cd (II), Cr (VI), Pb (II) and Zn (II) at concentrations of 50 and 100. mg/kg. G. vittiformis was found to be effective in removing the metals from soil within 30 days. The bioaccumulation factor (BAF) for both mycelia and fruiting bodies with respect to these heavy metals at 50. mg/kg concentrations were found to be greater than one, indicating hyper accumulating nature by the mushroom. The metal removal rates by G. vittiformis was analyzed using different kinetic rate constants and found to follow the second order kinetic rate equation except for Cd (II), which followed the first order rate kinetics. © 2013 Elsevier Inc.
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    Solvent selection for highly reproducible carbon-based mixed-cation hybrid lead halide perovskite solar cells via adduct approach
    (Elsevier Ltd, 2020) Keremane, K.S.; Prathapani, S.; Haur, L.J.; Damodaran, D.; Vasudeva Adhikari, A.V.; Priyadarshi, A.; Mhaisalkar, S.G.
    The major problem identified in carbon-based mixed cation perovskite solar cells (PSCs) is the selection of a suitable solvent for single-step solution-processed perovskite deposition in order to promote their scalable production. Herein we report a detailed study on the selection of appropriate solvent for the one-step deposition of cesium-formamidinium lead iodide (Cs0.1FA0.9PbI3) perovskite via Lewis acid-base adduct approach for fully printable mesoporous PSCs with mesoporous TiO2/ZrO2/C architecture. Highly reproducible Cs0.1FA0.9PbI3 solar cells were fabricated via adducts of PbI2 with eco-friendly dimethyl sulfoxide (DMSO). The best cells fabricated with the above approach yielded a photoconversion efficiency (PCE) of 12.33% for a small area device (active area: 0.09 cm2) and 10.1% for a large area device (active area 0.7cm2). The average power conversion efficiency for 62 PSCs was found to be 10.5% under an AM 1.5G illumination. Finally, the mixed cation perovskite in carbon architecture using the Lewis acid-base adduct approach is remarkably stable, with less than 1% change from the initial PCE after 1800h of storage under dark ambient conditions (25 °C, 60–70% RH). © 2020 International Solar Energy Society