Faculty Publications
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Item Microstructural and mechanical properties of AlCoCrCuFeNiSix (x = 0 and 0.9) high entropy alloys(Elsevier Ltd, 2021) Chandrakar, R.; Kumar, A.; Chandraker, S.; Rao, K.R.; Chopkar, M.In this work, the effect of addition of Si on the phase evolution and mechanical properties of AlCoCrCuFeNiSix alloy system has been studied. The High Entropy Alloys (x = 0 and 0.9) have been synthesised by powder metallurgy route which includes mechanical alloying (MA) and spark plasma sintering. X-ray diffraction technique was performed to understand the alloying behaviour and to investigate the phase formation of the high entropy alloys. The samples after spark plasma sintering comprised mainly of body centered cubic structured phase with a small extent of face centered cubic structured phase. With the addition of silicon, the XRD peak intensity of body centered cubic appears strong compared to the face centered cubic structured phase. Moreover, no intermetallic is observed in AlCoCrCuFeNi high entropy alloy system. However, further accumulation of Silicon results in the evolution of sigma (?) phase. © 2020 Elsevier LtdItem Effect of metalloid element on the microstructural and mechanical properties of AlCoCrCuFeNi high-entropy alloys(Taylor and Francis Ltd., 2024) Chandrakar, R.; Chandraker, S.; Kumar, A.; Jaiswal, A.The impact of the metalloid element silicon (Si) addition on the microstructural and mechanical properties of the AlCoCuCrFeNiSix high-entropy alloy system is examined in this paper. The alloys were synthesized using a vacuum arc melting route. X-ray diffraction was used to analyse the current high-entropy alloys’ phase formation to comprehend the alloying process’s behaviour. It is evident from the peak pattern of the X-ray diffraction that the inclusion of Si promotes the growth of body-centred cubic structures. The microhardness and wear resistance were increased by increasing the Si content from 0 to 0.9. Si presence enhances the hardness of the alloys and strengthens the grain boundary. Improved hardness and wear resistance results from the enhanced body-centred cubic-phase formation, which poses a barrier to the dislocation movement and prevents further deformation. Furthermore, the inclusion of Si improved corrosion resistance in potentiodynamic polarization measurements. Excellent compressive strength is possessed by all of the high-entropy alloys with Si addition. © 2024 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group.Item Investigation of phase transformation and mechanical properties of silicon addition on AlCrFeMnNi high entropy alloys(Institute of Physics, 2024) Chandrakar, R.; Chandraker, S.; Kumar, A.; Jaiswal, A.This paper examines the impact of silicon in the AlCrFeMnNi high-entropy alloy system, focusing on both its microstructural and mechanical properties. Alloys with varying silicon content (x = 0, 0.3, 0.6, 0.9 atomic ratio) were synthesized using vacuum arc melting. The phase formation of these high-entropy alloys was analyzed using x-ray diffraction to comprehend the alloying process behaviour. The findings revealed that the solidification of the AlCrFeMnNi alloy occurred in dendritically, with dendrite cores containing Cr, Fe, and Ni, while interdendritic regions were enriched in Al and Ni after adding Silicon. Increasing the silicon content from 0 to 0.9 led to significant improvements in microhardness and wear resistance. This improvement is attributed to the reinforcement of grain boundaries provided by silicon. The formation of an Al and Ni rich B2 phase is crucial in resisting dislocation motion and preventing further deformation. Additionally, the addition of silicon led to improved corrosion resistance, as demonstrated by potentiodynamic polarization measurements. However, a trade-off was observed between compressive strength and ductility: compressive strength increased with higher silicon concentrations, but at the expense of ductility. © 2024 The Author(s). Published by IOP Publishing Ltd.