Faculty Publications

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Potential utilization of regional cashew nutshell ash wastes as a cementitious replacement on the performance and environmental impact of eco-friendly mortar
(Elsevier Ltd, 2023) Manjunath, B.; Ouellet-Plamondon, C.M.; Das, B.B.; Bhojaraju, C.
Globally, agro-waste ashes are increasing significantly due to the rapid implementation of biomass-based power plants. In the present trend, agro-wastes are disposed of in an unsustainable manner. The recycling of agro-waste has significantly contributed to sustainable goals. In the construction sector, it is possible to dispose of waste more efficiently. However, the efficiency of locally available agro-residual waste in cementitious composites is not well understood. In the present investigation, the practicability of using agro-residual ash obtained from the burning of cashew nutshells on the properties of eco-friendly blended cement paste and mortars is explored. Blended cement mixtures containing cashew nutshell ash (CNSA) were prepared at five replacement levels, 5, 10, 15, 20, and 25%, relative to the weight of the cement. To understand the characteristics of CNSA, microstructure investigations such as X-ray diffraction, thermogravimetric analysis (TGA), scanning electron microscopy, and energy-dispersive spectroscopy analyses were performed. Paste properties of CNSA-based cement are observed through consistency, setting time, mini-slump flow, and expansion tests. For the CNSA-based mortars flow table, compressive strength, ultrasonic pulse velocity (UPV), electrical resistivity (ER), water absorption, bulk density, and porosity tests were performed to understand its efficiency. The strength indices of mortars were used to quantify the pozzolanic effect of CNSA. With the incorporation of CNSA, water demand increased by 57%, initial and final setting time decreased by 90% and 83%, respectively. Results showed that CNSA-based mortars absorbed more water and had higher porosity, which reduced compressive strength, UPV, and ER values. CNSA blended mortar is more suitable for applications that do not require high compressive strength. Results indicated that the compressive strength, UPV, and ER are within the limit specified. Strength indices indicated that CNSA has a positive and negative pozzolanic effect during early and later ages, respectively. Further, the sustainable assessment showed that the introduction of CNSA in mortar could substantially reduce embodied carbon, embodied energy, and strength efficiency over the control mortar. The inadequate amount of SiO2, Fe2O3, and Al2O3 in CNSA makes it an unsuitable pozzolanic material. However, it can be utilized in smaller amounts as a fractional replacement of cement and is found to be promising for specific desired properties of cement as a cost-effective accelerator. © 2023 Elsevier Ltd
Development of sustainable conductive cementitious composite using graphite-coated spent catalyst waste
(Elsevier Ltd, 2024) Bhagithimar, Y.; Manjunath, B.; Das, B.B.; Bhojaraju, C.
This study presents an innovative approach to developing sustainable conductive composites by coating graphite onto the surface of spent catalyst waste through nano-surface engineering techniques. The process ensures uniform adsorption of graphite onto the surface of the spent catalyst waste particles, followed by oven treatment and milling. This results in better integrity and effective bonding, leading to the production of graphite-coated spent catalyst waste (G-SCW). Scanning electron microscopy indicates the successful coating of spent catalyst waste with graphite. The research investigates the effect of G-SCW on the cementitious properties of paste and mortar. Incorporating G-SCW results in acceptable workability and setting time, while the compressive strength increases at early and later stages, with up to 20 % G-SCW content. The addition of G-SCW in the mortar significantly reduces the electrical resistivity, resulting in a 63 % reduction in resistivity compared to the reference mix, thereby enhancing the conductivity. Hydration studies confirm the presence of pozzolanic reaction in blended paste, as evidenced by a decrease in calcium hydroxide content. The sustainability assessment indicates a substantial reduction in embodied carbon and possibly producing mortar with lower cement content. These findings suggest great potential for developing sustainable conductive mortar with G-SCW, enabling smart building construction, and supporting sensor networks for structural health monitoring. © 2024 Elsevier Ltd
Areca nut husk biochar as a sustainable carbonaceous filler for cement: Pyrolysis temperature and its effect on characterization, strength, and hydration
(Elsevier B.V., 2024) Manjunath, B.; Ouellet-Plamondon, C.M.; Das, B.B.; Rao, S.; Bhojaraju, C.; Rao, M.
This study addresses the gap in sustainable agro-based materials for cement by exploring locally available areca nut husk pyrolyzed into areca nut husk biochar (AB). The research investigated the effect of pyrolysis temperature (300°C, 400°C, and 500°C) on the characteristics of AB and its impact on cementitious performance. The study found that increasing pyrolysis temperatures led to lower yield, greater aromaticity, and increased surface area of AB. Fourier Transform Infrared Spectroscopy (FTIR) analysis showed decreased functional groups in AB at higher temperatures, confirming enhanced carbonization. Thermogravimetric analysis (TGA) revealed greater thermal stability of AB. X-ray diffraction (XRD) indicated a carbon-rich amorphous structure and crystalline graphite carbon formation in AB. Incorporating AB at 2 % into cementitious composites substantially increased the compressive strength compared to the control mortar. At 7 and 28 days, the compressive strength increased by 8 % and 12 % for AB 300, 16 % and 21 % for AB 400, and 27 % and 34 % for AB 500. This improvement was due to the micro filler effect of AB, which improved the compactness of the cementitious matrix. Hydration studies from TGA showed that the addition of AB accelerated early-stage hydration, with the degree of hydration increasing from 46 % (in control mix) to 48–53 % in AB blended mixes using Bhatty's method. FTIR analysis demonstrated improved hydration of silicate phases and C-S-H formation in the presence of AB, supported by XRD analysis. AB blended mortar reduced the CO2 equivalent emission by 22 % compared to the control mortar attributed to its carbon sequestration capacity. These results highlight the potential of AB as a sustainable carbonaceous filler for cementitious composites, offering an environmentally friendly option for future research in construction materials. © 2024 Elsevier B.V.

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