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Item Effective Usage of Biochar and Microorganisms for the Removal of Heavy Metal Ions and Pesticides(MDPI, 2023) Manikandan, S.K.; Pallavi, P.; Shetty K, V.; Bhattacharjee, D.; Giannakoudakis, D.A.; Katsoyiannis, I.A.; Nair, V.The bioremediation of heavy metal ions and pesticides is both cost-effective and environmentally friendly. Microbial remediation is considered superior to conventional abiotic remediation processes, due to its cost-effectiveness, decrement of biological and chemical sludge, selectivity toward specific metal ions, and high removal efficiency in dilute effluents. Immobilization technology using biochar as a carrier is one important approach for advancing microbial remediation. This article provides an overview of biochar-based materials, including their design and production strategies, physicochemical properties, and applications as adsorbents and support for microorganisms. Microorganisms that can cope with the various heavy metal ions and/or pesticides that enter the environment are also outlined in this review. Pesticide and heavy metal bioremediation can be influenced by microbial activity, pollutant bioavailability, and environmental factors, such as pH and temperature. Furthermore, by elucidating the interaction mechanisms, this paper summarizes the microbe-mediated remediation of heavy metals and pesticides. In this review, we also compile and discuss those works focusing on the study of various bioremediation strategies utilizing biochar and microorganisms and how the immobilized bacteria on biochar contribute to the improvement of bioremediation strategies. There is also a summary of the sources and harmful effects of pesticides and heavy metals. Finally, based on the research described above, this study outlines the future scope of this field. © 2023 by the authors.Item Creep cavitation damage of K-type thermocouples(Elsevier Ltd, 2023) Rakshan Kumar, J.K.; Bhattacharjee, D.; Dsilva, P.; Praveen, R.; Hegde, S.R.This work investigates premature failure of K-Type thermocouples that were used in a chemical processing plant. The work presents a detailed metallurgical failure analysis involving, site visit, visual inspection, metallography, optical microscopy, scanning electron microscopy, and fractography. The analysis reveals that the thermocouple wires endured creep cavitation damage during service and eventually failed by creep-rupture. Interestingly, the influence of creep on the degradation of industrial thermocouples is not detected and reported thus far. By presenting analytical stress calculations using temperature dependent materials properties, the current work reveals that the thermal expansion mismatch between various materials of thermocouple causes high tensile stresses in the thermocouple wires during elevated temperature services. The work concludes that high tensile stresses at elevated temperature operation caused premature creep failure of the K-type thermocouples. © 2022
