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Item Magnetron sputtered MoO3/carbon nanotube composite electrodes for electrochemical supercapacitor(Elsevier B.V., 2013) Aravinda, L.S.; Nagaraja, K.K.; Bhat, K.; Badekai Ramachandra, B.Molybdenum oxide (MoO3) has been deposited on multiwalled carbon nanotubes (MWCNTs) using DC reactive magnetron sputtering of molybdenum for supercapacitor applications. The deposits of MoO3 have been developed under different intervals of time. The structure and surface morphology of the deposits have been characterized by means of X-ray diffraction (XRD) analysis and field emission scanning electron microscopy (FESEM). X-ray diffraction peaks of the composite films reveal the formation of crystalline structure of MoO3. The electrochemical performance of the composite films was studied using cyclic voltammetry (CV), galvanostatic charge discharge and electrochemical impedance spectroscopy measurements. The composite film exhibits maximum specific capacitance of 70 F g-1 at a scan rate of 10 mV s-1 in 1 M Na2SO4 electrolyte. The nanocomposite electrode material shows specific capacitance which is almost four fold increase with respect to that of bare MWCNTs. The effect of coating duration on specific capacitance has been studied. The nanocomposite film is found to display good cycleability, even up to 1000 cycles. © 2013 Elsevier Inc. All rights reserved.Item ZnO/carbon nanotube nanocomposite for high energy density supercapacitors(2013) Aravinda, L.S.; Nagaraja, K.K.; Nagaraja, H.S.; Bhat, K.; Badekai Ramachandra, B.A facile, green and highly efficient method for the decoration of carbon nanotubes with ZnO was developed for the fabrication of binder-free composite electrode for supercapacitor applications. The nano composite was prepared by using reactive magnetron sputtering in Ar/O2 environment. This approach leads to more uniform coating with tuneable thickness, which alters the electrochemical performance of the nano composite electrodes. The structure and surface morphology of the composite film have been studied by means of X-ray diffraction (XRD) analysis, scanning electron microscopy and field emission scanning electron microscopy (FESEM). The XRD study reveals the formation of Wurtzite ZnO structure. The electrochemical performance of nano composite electrode was investigated using cyclic voltammetry, chronopotentiometry and electrochemical impedance measurements in non-aqueous electrolyte. The nano composite electrode shows significant increase in the specific capacitance up to 48 F g-1 with an energy density 13.1 Wh kg-1 in the potential range -2 V to 1 V. © 2013 Elsevier Ltd. All rights reserved.Item Binder free MoO3/multiwalled carbon nanotube thin film electrode for high energy density supercapacitors(2013) Aravinda, L.S.; Bhat, K.; Badekai Ramachandra, B.MoO3/multiwalled carbon nanotube (MWCNT) composites were prepared by Magnetron sputtering in Ar/O2 atmosphere. This will provide a greener alternative for the fabrication of binder free composite electrode for supercapacitor applications. MWCNT provides good support for the growth of MoO3 thin films. This integrated composite electrode exhibited specific capacitance of 93 F g-1 and a corresponding energy density of 7.28 Wh kg-1 in non-aqueous electrolyte, which is almost fourfold increase compared to the bare MWCNT. Also the electrode maintains high power density of 4930 W kg-1 at high current rates, suggesting a potential energy storage material for portable and consumer electronics. © 2013 Elsevier Ltd. All rights reserved.