Faculty Publications
Permanent URI for this communityhttps://idr.nitk.ac.in/handle/123456789/18736
Publications by NITK Faculty
Browse
3 results
Search Results
Item Role of thermally grown oxide and oxidation resistance of samarium strontium aluminate based air plasma sprayed ceramic thermal barrier coatings(Elsevier B.V., 2017) Baskaran, T.; Arya, S.B.Samarium Strontium Aluminate (SSA) based ceramic oxide was synthesized and coated on a bond coated (NiCrAlY) Inconel 718 superalloy by air plasma spray (APS) process. Thermally grown oxide (TGO) thicknesses were controlled at different pre-oxidation times of 10, 20 and 30 h at 1050 °C in the argon atmosphere, the highest TGO thickness being found for 30 h pre-oxidized samples. The percentage elastic recovery of pre-oxidized samples increased (45, 48, and 50%) with an increasing pre-oxidation time at 1050 °C. The isothermal oxidation test was performed on pre-oxidized samples at 1100 °C for 15 h in air. The parabolic oxidation rate constant decreased from 6.08 × 10? 5 to 3.90 × 10? 5 mg2 cm? 4 s? 1 (from 10 to 20 h) and then increased up to 4.55 × 10? 5 mg2 cm? 4 s? 1 for 30 h pre-oxidized SSA samples at 1100 °C. SSA based TBCs showed 65% lower weight gain as compared to conventional YSZ TBCs after oxidation at 1100 °C in air. Cross-sectional SEM results revealed that the threshold TGO thickness of SSA TBCs is about 5.3 to 5.8 ?m. Failure of SSA TBCs was observed at the interface of TGO and ceramic top coat due to the formation of SmAlO3 along with spinel oxides. © 2017Item Influence of ceramic top coat and thermally grown oxide microstructures of air plasma sprayed Sm2SrAl2O7 thermal barrier coatings on the electrochemical impedance behavior(Elsevier B.V., 2018) Baskaran, T.; Arya, S.B.Electrochemical impedance spectroscopy (EIS) technique is used to examine the top coat and thermally grown oxide (TGO) microstructures of Samarium Strontium Aluminate (SSA) thermal barrier coatings (TBCs) after exposed to pre-oxidation and oxidation at 1050 and 1100 °C, respectively. EIS spectra showed that the three relaxations frequencies in Bode plot corresponded to SSA top coat, TGO, and TGO-bond coat interface. A significant reduction in polarization resistance of SSA top coat and increase in capacitance for different pre-oxidation times of 10, 20 and 30 h are being found due to increasing the defects (pores and cracks) of about 13, 29 and 45%, respectively at 1050 °C. The reduction in bi-axial residual stresses was calculated to be about 57% as a consequence of decrement in top coat resistance. The growth of SSA TGO was found from 10 to 20 h of pre-oxidation treatment caused to decrease the capacitance which indicates the presence of highly enriched ?-Al2O3 at the bond coat-top coat interface. The highest charge transfer resistance and lowest capacitance were found to be about 0.48 × 106 ? cm2 and 1.1 nF cm?2 respectively for 20 h of pre-oxidation which could reflect the overall impedance kinetics of TBC system (SSA top coat and TGO) at the TGO-bond coat interface. The impedance responses of SSA top coat, TGO, and TGO-bond coat interface were reduced drastically after oxidation at 1100 °C for 10 h pre-oxidized specimen as compared to 20 and 30 h due to the compositional change of pure ?-Al2O3 based TGO into more conductive NiCr2O4. The lowest diffusion coefficient, DCr3+ in the NiO lattice which reduced the formation of metal ion vacancies at the TGO-top coat interface caused to exhibit higher TGO resistance for 20 h pre-oxidized specimens over 10 and 30 h after oxidation at 1100 °C. © 2018 Elsevier B.V.Item Hot corrosion resistance of air plasma sprayed ceramic Sm2SrAl2O7 (SSA) thermal barrier coatings in simulated gas turbine environments(Elsevier Ltd, 2018) Baskaran, T.; Arya, S.Samarium strontium aluminate (Sm2SrAl2O7-SSA) and Yttria-stabilized zirconia (YSZ) thermal barrier coatings (TBCs) were developed on NiCrAlY bond coated Inconel 718 superalloy substrate using air plasma spray process. The hot corrosion study was conducted in simulated gas turbine environments (molten mixtures of 50 wt% Na2SO4 + 50 wt% V2O5 and 90 wt% Na2SO4 + 5 wt% V2O5 + 5 wt% NaCl) for two different temperatures of 700 and 900 °C. A developed SSA TBCs showed about 8% and 22% lower lifetime at 700 and 900 °C, respectively than YSZ TBCs in 50 wt% Na2SO4 + 50 wt% V2O5 (vanadate). The hot corrosion life of SSA TBCs being found about 13% and 39% lower than YSZ TBCs in 90 wt% Na2SO4 + 5 wt% V2O5 + 5 wt% NaCl (chloride) at 700 and 900 °C, respectively. X-ray diffraction results showed the formation of SmVO4, SrV2O6, and SrSO4 as a major hot corrosion product in 50 wt% Na2SO4 + 50 wt% V2O5 and 90 wt% Na2SO4 + 5 wt% V2O5 + 5 wt% NaCl environments respectively for SSA TBCs. Similarly, YSZ TBCs also showed YVO4 as hot corrosion product in vanadate and chloride environments. Both the TBCs suffer a more severe hot corrosion attack in chloride environment at 900 °C. The leaching of Sr2+ and Y3+ ions from SSA and YSZ respectively play a vital role in the destabilization of coating in vanadate and chloride environments at 700 and 900 °C. In both SSA and YSZ TBCs, the leaching of ion has significantly low influence as compared to attack by chloride ions at the bond coat-top coat interface in the presence of chloride environment. The hot corrosion resistance of SSA TBCs was improved three times higher in the presence of MgO and NiO inhibitor in vanadate environment at 900 °C mainly due to the formation of a stable Ni3V2O8 phase at the surface. © 2018 Elsevier Ltd and Techna Group S.r.l.