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Item Surface design of Mg-Zn alloy temporary orthopaedic implants: Tailoring wettability and biodegradability using laser surface melting(Elsevier B.V., 2018) Manne, B.; Thiruvayapati, H.; Bontha, S.; Motagondanahalli Rangarasaiah, R.; Das, M.; Balla, V.K.Magnesium-based alloys have attracted significant attention for biomedical applications due to its biodegradability as well as density and elastic modulus which are close to those of human bone. However, the uncontrolled biodegradation and hydrogen evolution are of major concern. In this work, laser surface melting (LSM) has been carried out to tailor initial corrosion rates of Mg-2.2Zn alloy implants. Melt pool dimensions, microstructure and surface topography of the LSM samples were analysed. The wettability and in vitro degradation characteristics of untreated and treated alloy were compared. LSM resulted in much finer cellular microstructural features than as-cast alloy and the melted region depths between 65 and 115 ?m. Higher treatment depths helped to extend the corrosion protection time by suppressing the corrosion front movement. Polished LSM samples resulted in overall corrosion rates of 0.5–0.62 mm/year which was about 40%–50% reduction compared to the as-cast alloy. Accelerated biomineralisation of the surface via enhancements in the surface energy due to microstructural refinement as well as microstructural homogeneity and Zn enrichment in ?-Mg, favoured improvement of the overall corrosion performance of LSM-treated alloy. © 2018 Elsevier B.V.Item Laser surface modification of Mg-Zn-Gd alloy: Microstructural, wettability and in vitro degradation aspects(Institute of Physics Publishing helen.craven@iop.org, 2018) Rakesh, K.R.; Bontha, S.; Ramesh, M.R.; Arya, S.; Das, M.; Balla, V.K.; Srinivasan, A.Mg-Zn-Gd have great potential for biomedical applications owing to excellent bioactivity and non-toxicity properties. In the present study, laser surface melting (LSM) was carried out on newly developed Mg-1Zn -2Gd (wt%) alloy. Effects of laser energy on microstructural evolution, corrosion properties, surface energy, and hardness have been investigated. The surface modified sample processed at different energy densities showed fine grain structure in the melt zone compared to the untreated substrate. Grain refinement in the laser melted region improved the hardness by 60%. The surface roughness was found to be increased with increasing laser energy density. At higher energy density, removal of materials from the surface is enhanced, resulting in deeper grooves and higher surface roughness. The wettability studies indicated that the variations in surface geometry, grain size and surface roughness of LSM samples strongly influence the surface energy and hydrophilicity. Improved wetting of LSM sample was achieved owing to grain refinement and low surface roughness. The corrosion resistance determined by immersion and electrochemical methods of laser melted sample in Hank's balanced salt solution improved considerably due to grain refinement, meltpool depth and uniform distribution of secondary phases. © 2018 IOP Publishing Ltd.Item Laser surface melting of Mg-Zn-Dy alloy for better wettability and corrosion resistance for biodegradable implant applications(Elsevier B.V., 2019) K.r, R.; Bontha, S.; M.r, R.; Das, M.; Balla, V.K.In order to improve the performance of magnesium (Mg) for resorbable implant applications, Mg-1Zn-2Dy alloy was developed and the surface of the alloy has been modified by melting using lasers. Laser melted samples, at different laser energy density, were then subjected to microstructural, hardness, wettability and in-vitro degradation assessment. The microstructure of the Mg-Zn-Dy alloy mainly consisted of ?-Mg and eutectic phase (Mg 8 ZnDy). The melted region of the alloy surface evolved with fine grain microstructure at the near surface region and columnar grains near to the liquid solid substrate. The degree of grain size refinement obtained at the melted zone in the order of 1–2 ?m. The cross sectional microhardness of the modified zone was measured by Vickers microhardness tester. Due to these microstructural refinements and solid solution strengthening the surface hardness of laser treated alloy increased by two-fold. It was found that as the energy density increased the surface roughness along with the surface energy also increased. The wetting behaviour of the surface was estimated through measuring the contact angle by dropping the polar and non-polar liquid. Results showed that the surface energy is also found to change with LSM due to changes in the surface morphology, microstructure and chemical composition of the material. The detailed degradation study was carried out by immersing the samples in hanks balances salt solution (HBSS).The improvement in the degradation behaviour followed by laser surface melting is related to the microstructural refinement as a result of rapid heating and cooling of the melted zone. © 2019 Elsevier B.V.Item Degradation, wettability and surface characteristics of laser surface modified Mg–Zn–Gd–Nd alloy(Springer, 2020) K.r, R.; Bontha, S.; M.r, R.; Das, M.; Balla, V.K.This work evaluates the effects of laser surface modification on Mg–Zn–Gd–Nd alloy which is a potential biodegradable material for temporary bone implant applications. The laser surface melted (LSM) samples were investigated for microstructure, wettability, surface hardness and in vitro degradation. The microstructural study was carried out using scanning and transmission electron microscopes (SEM, TEM) and the phases present were analyzed using X-ray diffraction. The in vitro degradation behaviour was assessed in hank’s balanced salt solution (HBSS) by immersion corrosion technique and the effect of LSM process parameters on the wettability was analyzed through contact angle measurements. The microstructural examination showed remarkable grain refinement as well as uniform redistribution of intermetallic phases throughout the matrix after LSM. These microstructural changes increased the hardness of LSM samples with an increase in energy density. The wetting behaviour of processed samples showed hydrophilic nature when processed at lower (12.5 and 17.5 J/mm2) and intermediate energy density (22.5 and 25 J/mm2), which can potentially improve cell-materials interaction. The corrosion rate of as cast Mg–Zn–Gd–Nd alloy decreased by ~83% due to LSM. [Figure not available: see fulltext.]. © 2020, Springer Science+Business Media, LLC, part of Springer Nature.Item Tailoring surface characteristics of bioabsorbable Mg-Zn-Dy alloy using friction stir processing for improved wettability and degradation behavior(Elsevier Editora Ltda, 2021) Rokkala, U.; Bontha, S.; Ramesh, M.R.; Balla, V.K.; Srinivasan, A.; Kailas, S.V.Magnesium (Mg) and its alloys are currently under consideration for use as temporary implants. However, early degradation and maintaining mechanical integrity is a significant concern. Surface modification techniques are used to improve mechanical and corrosion properties of Mg based alloys. In the present study, friction stir processing (FSP) was used to tailor the surface characteristics of Mg-1Zn-2Dy (wt.%) alloy for temporary implant applications. The FSPed alloy was characterized using EBSD to understand the influence of FSP on crystallographic texture, grain size and grain boundaries and thereby their effect on corrosion, wettability and hardness. Results showed that the grain size of stir zone (SZ) was refined to less than 3 ?m, as a result of dynamic recrystallization (DRX) during FSP and the FSPed alloy exhibited better wettability than as-cast alloy. An increase in the hardness (11.7%) and elastic modulus (6.84%) of FSPed alloy were also observed. Electrochemical corrosion and weight loss methods were conducted in Dulbecco's Modified Eagle's Medium (DMEM) with, 10% Fetal Bovine Serum (FBS) physiological solution. The lower degradation rate (0.72 mm/yr) of FSPed alloy has been attributed to the fine grains and evenly distributed secondary phase particles. Further, the influence of grain boundary characteristics and crystallographic texture on the corrosion behavior have been investigated. © 2021 The Author(s).